• Title/Summary/Keyword: low temperature reduction

Search Result 1,037, Processing Time 0.03 seconds

Austenite Recrystallization and Ferrite Refinement of a Nb Bearing Low Carbon Steel by Heavy Hot Deformation (강가공에 의한 Nb함유 저탄소강의 오스테나이트 재결정과 페라이트 미세화)

  • Lee, Sang Woo
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.18 no.1
    • /
    • pp.3-11
    • /
    • 2005
  • Using various thermo-mechanical schedules characterized by varying reheating temperature, deformation temperature and strain, the austenite recrystallization and ferrite refinement of a Nb bearing low carbon steel(0.15C-0.25Si-1.11Mn-0.04Nb) were investigated. For single pass heavy deformations at $800^{\circ}C$, the 40% deformed austenite was not recrystallized while the 80% deformed one was fully recrystallized. Ferrite grains formed in the 80% deformed specimen was not very small compared with those in the 40% deformed specimen, which implied the recrystallized austenite was not more beneficial to ferrite refinement than the non-recrystallized one. In case of deformation in low temperature austenite region, a multi-pass deformation made finer ferrites than a single-pass deformation, as the total reduction was the same, due to more ferrite nucleation sites in the non-recrystallization of austenite for multi-pass deformation. When specimen was deformed at $775^{\circ}C$ that was $10^{\circ}C$ higher than $Ar_3$, the ferrite of about $1{\mu}m$ was formed through deformation induced ferrite transformation(DIFT), and the amount of ferrite was increased with increasing reduction. Dislocation density was very high and no carbides were observed in DIFT ferrites, presumably due to supersaturated carbon solution. By deformation in two phase(50% austenite+50% ferrite) region the very refined ferrite grains of less than $1{\mu}m$ were formed certainly by recovery and recrystallization of deformed ferrites and, a large portion of ferrites were divided by subgrain boundaries with misorientation angles smaller than 10 degrees.

A study on the reduction of emission by controlled cooling system in a diesel engine (냉각 시스템 제어에 따른 디젤 엔진의 배기가스 저감에 관한 연구)

  • Choi, Kyung-Wook;Cho, Won-Joon;Lee, Ki-Hyung
    • Proceedings of the KSME Conference
    • /
    • 2007.05b
    • /
    • pp.3294-3299
    • /
    • 2007
  • These days the exhaustion of petroleum resources and environmental problems are getting serious. Many researchers are focused on low emission and high performance vehicles. Therefore, we should concern about emission regulation when we design a new car. In this study, we investigated the characteristics of the traditional mechanical engine cooling systems which control the engine temperature using engine speed and wax type thermostat. This experiment used three components which are Radiator fan, water pump and water valve controlled by an electronic system based on the engine status (load, speed). We elucidated how different between traditional mechanical cooling system and electronic cooling system which control coolant temperature and coolant flow rate in a DI diesel engine in this paper. The results revealed a fuel saving and an emission (CO, HC) reduction on NEDC cycle.

  • PDF

Electrochemical Approach in Plasma Display Panel Glass Melts doped with Sulfate and Sulfide II. Square Wave Voltammetry

  • Kim, Ki-Dong
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.7
    • /
    • pp.375-379
    • /
    • 2008
  • Redox behavior was observed in alkali alkaline earth silicate PDP (Plasma Display Panel) glass melts doped with sulfate and sulfide by square wave voltammetry (SWV). According to voltammograms produced at a temperature range of 1100 to $1400^{\circ}C$ and frequency range of 5 to 1000 Hz, both melts showed the same behavior in which there is one reduction peak at low frequency but another peak at an increase of frequency. Based on the frequency dependence of the peak current, self diffusivity of $S^{4+}$ was determined. Based on the temperature dependence of the peak potential, standard enthalpy (${\Delta}H^0$) and standard entropy (${\Delta}S^0$) for the reduction of $S^{4+}$ to $S^0$ were calculated.

Electrochemical extraction of uranium on the gallium and cadmium reactive electrodes in molten salt

  • Valeri Smolenski;Alena Novoselova
    • Nuclear Engineering and Technology
    • /
    • v.56 no.1
    • /
    • pp.42-47
    • /
    • 2024
  • The electrochemical extraction of uranium in ternary low melting LiCl-KCl-CsCl eutectic on inert and reactive electrodes via different electrochemical techniques was investigated. It was established that the electrochemical reduction process of U(III) ions on the inert W electrode was irreversible and proceeded in one stage. On reactive liquid Ga and liquid Cd electrodes the reduction of uranium ions took place with the considerable depolarization with the formation of UGa2, UGa3 and UCd11 intermetallic compounds. Thermodynamic characteristics of uranium compounds and alloys were calculated. The conditions for the extraction of uranium from the electrolyte in the form of alloys on both liquid reactive electrodes via potentiostatic electrolysis were found.

Investigation on the DeNOx Efficiency in Urea-SCR System at Various Operating Conditions and Injection Characteristics for a Passenger Diesel Engine (승용디젤엔진의 운전 조건 및 분사 조건 변경에 따른 Urea-SCR 시스템의 NOx 전환효율에 관한 연구)

  • Hong, Kil-Hwa;Hwang, In-Goo;Myung, Cha-Lee;Park, Sim-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.33 no.12
    • /
    • pp.952-960
    • /
    • 2009
  • Selective Catalytic Reduction (SCR) system is a high-effective NOx reduction technology in diesel engines. As the emission standard of diesel engines is more stringent, vehicle manufactures makes efforts on emission technologies. This paper discusses the performance of Urea-SCR system according to the engine operating conditions in a passenger diesel engine. Engine test results in this paper show that it is important to consider the catalyst temperature and space velocity to obtain high NOx conversion efficiency. In condition of high catalyst temperature, over 90% NOx conversion efficiency is indicated. However, when catalyst temperature is low, NOx conversion efficiency was decreased. Also, it was shown that space velocity mainly effects on the DeNOx performance under 220 degree celsius of SCR catalyst temperature. As the urea injection pressure was decreased, NOx conversion efficiency was declined. It is concerned about urea droplet atomization. This work shown in this paper can lead to improved overall NOx conversion efficiency.

A Estimation of Thermal Fatigue Performance in Three-way Catalyst (삼원 촉매의 열적 내구 성능 평가)

  • Lee, Sung Riong;Cho, Seok-Swoo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.14 no.1
    • /
    • pp.13-19
    • /
    • 2013
  • This study examines thermal safety on three-way catalyst that dominates 70% among whole exhaust gas purification device in 2003. Three-way catalyst maintains high temperature in interior domain but maintains low temperature on outside surface. Therefore this device shows tensile stress on outside surface. Temperature distribution of three-way catalyst was acquired by thermal flow analysis for predicted thermal flow parameter. Thermal stress analysis for three-way catalysis was performed based on this temperature distribution. Thermal safety of three-way catalyst was estimated by strength reduction factor and failure probability.

Field Application of Insulation Curing Method with Double Bubble Sheets Subject to Cold Weather (이중버블시트를 이용한 단열양생공법의 한중콘크리트 현장적용)

  • Hong, Seak-Min;Lee, Il-Sun;Baek, Dae-Hyun;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2009.05b
    • /
    • pp.25-28
    • /
    • 2009
  • This study investigated the results of insulation heat curing method using double layer bubble sheet in slab concrete in cold weather environment. First of all, when double bubble sheets are applied, it was shown that slab concrete was protected from early freezing by remaining between 5 and $l0^{\circ}C$ even in case outside temperature drops $-11^{\circ}C$ below zero until the 4nd day from piling. The insulation heat preservation curing method using the double bubble sheet applied in this field prevented early freezing owing to stable curing temperature management, deterring concrete strength development delay at low temperature, and obtained the needed strength. Also, it was proven that the method is highly effective and economic for cold weather concrete quality maintenance through curing cost reduction like construction period shortening and labor cost reduction, etc by reducing the process of temporary equipment installation and disassembling.

  • PDF

Effects of Process Temperature on the Tribological Properties of Tetrahedral Amorphous Carbon (ta-C) Coating (공정 온도에 따른 사면체 비정질 카본 (ta-C) 코팅의 트라이볼로지적 특성연구)

  • Kang, Yong-Jin;Kim, Do Hyun;Ryu, Hojun;Kim, Jongkuk;Jang, Young-Jun
    • Tribology and Lubricants
    • /
    • v.35 no.6
    • /
    • pp.362-368
    • /
    • 2019
  • In this study, mechanical and tribological properties were investigated by varying the process temperature (50, 100, 125 and 150℃) to reduce internal stress. The internal stress reduction by thermal dissociation ta-C coating film with increasing temperature is confirmed through the curvature radius of the ta-C coating according to the temperature of the SUS plate. As the coating temperature increased, the mechanical properties (hardness, modulus, toughness) deteriorated, which is in agreement with the Raman analysis results. As the temperature increased, the sp2 phase ratio increased owing to the dissociation of the sp3 phase. The friction and wear properties are related to the process temperature during ta-C coating. Low friction and wear properties are observed in high hardness samples manufactured at 50℃, and wear resistance properties decreased with increasing temperature. The contact area is expected to increase owing to the decrease of hardness(72 GPa to 39 GPa) and fracture toughness with increasing temperature which accelerated wear because of the debris generated. It was confirmed that at process temperature of over than 100℃, the bond structure of the carbon film changed, and the effect of excellent internal stress was reduced. However, the wear resistance simultaneously decreased owing to the reduction in fracture toughness. Therefore, in order to increase industrial utilization, optimum temperature conditions that reduce internal stress and retain mechanical properties.

Study on the Flat Zone Expansion and Temperature Deviation Reduction of Low Temperature Furnace for Semiconductor Process (반도체용 저온 열처리로의 Flat Zone 확장 및 온도편차 감소에 관한 연구)

  • Joo, Kang Wo;Shim, Seung Sool;Jang, Hyeok;Lee, You Young;Kim, Kwang Sun
    • Journal of the Semiconductor & Display Technology
    • /
    • v.13 no.4
    • /
    • pp.83-90
    • /
    • 2014
  • This paper is about the yield rate of lower temperature furnace for wafer heat-treatment. The flat-zone that the temperature in furnace has uniform distribution specific area is the significant variable to the yield rate. In this study, we researched about the ways how to widen the flat zone in the furnace using CFD. As a result, we confirmed that the characteristic of the flat-zone was changed when SCU(Super Cooling Unit) was used. We considered temperature control with above.

New Compensation Method for Temperature Sensitivity of Fiber Brags Grating Using Bi-metal

  • Chung, Young-Joo;Song, Jong-Seob;Han, Won-Taek;Paek, Un-Chul
    • Journal of the Optical Society of Korea
    • /
    • v.7 no.2
    • /
    • pp.84-88
    • /
    • 2003
  • A new method for temperature compensation of fiber Bragg grating (FBG) using hi-metal is proposed and experimentally demonstrated. Bi-metal bends toward the metal of low temperature expansion coefficient as the temperature increases, and this property is utilized to cancel the thermo-optic effect of the fiber. The optimum thickness of the high coefficient metal was empirically found by the trial-and-error method. The temperature sensitivities were 8.1 pm/$^{\circ}C$ and -0.018 pm/$^{\circ}C$ for the uncompensated and compensated FBGs, respectively, which indicates a reduction to a mere 0.22 % of the original sensitivity. No appreciable change in the spectral shape was observed. The packaging technique described in this paper is simple and compact, and it can be used for FBGs in WDM and DWDM communication systems that have stringent requirements on the temperature stability of the components.