• 제목/요약/키워드: low temperature irradiation

검색결과 275건 처리시간 0.027초

Effect of Heat-Treated Temperature on Surface Crystal Structure and Catalytic Activity of ACF/ZnO Composite under Ultraviolet Irradiation and Ultrasonication

  • Zhang, Kan;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제47권2호
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    • pp.136-141
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    • 2010
  • ACF/ZnO photocatalyst was synthesized by a sol-gel method using activated carbon fiber (ACF) and Zn $(NO_3)_2$ as precursors. Samples were characterized by Brunauer-Emmett-Teller measurements (BET), scanning electron microscope (SEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX). The XRD results showed that ACF/ZnO composites only included a hexagonal phase by heat-treated temperature at $400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, and $700^{\circ}C$. The SEM analysis revealed that the ACF/ZnO composites did not exhibit any morphological changes of the catalyst surface according to the different heat-treated temperatures. The photocatalytic activity of the samples was tested for degradation of methylene blue (MB) solutions under ultraviolet (UV) light and ultrasonication respectively. The results showed that the photocatalytic activity of ACF/ZnO composites heat-treated at $500^{\circ}C$ was higher than other samples, which is ascribed to the fine distribution of ZnO particles on the surface of the ACF. In addition, an ultrasound of low power (50 W) was used as an irradiation source to successfully induce ACF/ZnO composites to perform sonocatalytic degradation of MB. Results indicated that the sonocatalytic method in the presence of ACF/ZnO composites is an advisable choice for the treatments of organic dyes.

전자선 조사된 폴리프로필렌 부직포의 그라프트에 있어 보관조건이 미치는 영향 (Effect of Storage Conditions on Graft of Polypropylene Non-woven Fabric Induced by Electron Beam)

  • 이진영;전준표;강필현
    • 방사선산업학회지
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    • 제9권2호
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    • pp.57-62
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    • 2015
  • In this study, we fabricated effect of storage conditions on graft of polypropylene (PP) non-woven fabric induced by electron beam. The electron beam irradiations on PP non-woven fabric were carried out over a range of irradiation doses from 25 to 100 kGy to make free radicals on fabric surface. The radical measurement was established by electron spin resonance (ESR) for confirming the changes of the alkyl radical and peroxy radical according to effect of storage time, storage temperature and atmosphere. It was observed that the free radicals were increased with irradiation dose and decreased with storage time due to the continuous oxidation. However, the radical extinction was significantly delayed due to reduced mobility of radicals at extremely low temperature. The degree of graft based on the analysis of ESR was investigated. The conditions of graft reaction were set at a temperature: $60^{\circ}C$, reaction time: 6 hours and styrene monomer concentration: 20 wt%.

저장 중 발광다이오드 광 조사가 타이로시네이스 활성에 미치는 영향 (Effect of Light Emitting Diode Irradiation on Tyrosinase Activity during Storage)

  • 정효연;김정선;노봉수
    • 한국식품과학회지
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    • 제47권6호
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    • pp.785-788
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    • 2015
  • 식품 저장 중 효소적 갈변을 일으키는 타이로시네이스의 활성을 저해시킬 수 있는 LED의 파장을 구명하기 위하여 파란색, 초록색, 빨간색 LED와 형광등을 이용하여 타이로시네이스에 7일동안 조사하였다. 또한 강도에 따른 타이로시네이스의 활성을 조사하기 위하여 파란색, 초록색, 빨간색 LED를 선택하여 빛의 강도를 3단계로 구분하여 사용하였다. 파장에 따른 타이로시네이스의 활성 저해율은 형광등에서 가장 컸으며 그 다음으로 파란색 LED에서 높은 저해율을 보였다. 빨간색 LED에서는 대조구와 유사한 저해율을 보였으며 초록색 LED에서 저해율이 가장 낮았다. 상대적 빛의 강도에 따른 타이로시네이스 활성은 초록색과 빨간색 LED 조사 시 효소활성의 변화가 크지 않았고, 반면 파란색 LED에서 강도가 증가할수록 큰 저해효과를 보였다. 이러한 결과를 토대로 볼 때 여러 가지 파장의 LED 중 고강도의 파란색 LED에서 타이로시네이스에 의한 식품의 갈변을 최소화 할 수 있을 것으로 판단되며 이는 갈변 억제를 유도함으로써 과일 및 채소의 저장 중 품질을 향상시킬 수 있을 것이다.

Properties of Pulsed Photostimulated Luminescence and Thermoluminescence for Detection of Gamma-Irradiated Teas during Storage

  • Kausar, Tusneem;Kim, Byeong-Keun;Yang, Jae-Seung;Byun, Myung-Woo;Kwon, Joong-Ho
    • Preventive Nutrition and Food Science
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    • 제9권3호
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    • pp.227-231
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    • 2004
  • Green, black and oolong teas were irradiated by $^{60}$ Co-gamma rays (0~10 kGy) and were investigated for detection of irradiation treatment using pulsed photostimulated luminescence (PPSL) and thermoluminescence (TL) during storage. Teas irradiated at 2.5 kGy or more showed a photon count of greater than 5000 counts/60 sec while the non-irradiated yielded only 650~1000 count/60 sec. Correlation coefficients between irradiation dose and photon counts/60 sec were 0.8951, 0.7934 and 0.9007 for green, black and oolong teas, respectively. The TL glow curves for minerals isolated from the non-irradiated teas were situated at about 30$0^{\circ}C$ with a low intensity, but for irradiated samples were approximately 15$0^{\circ}C$ with a high intensity. The TL ratios (TL$_1$/TL$_2$), calculated from values after initial radiation and then after re-irradiation of the teas, were below 0.1 for the non-irradiated samples and higher than 1.44 for all irradiated samples, enhanced the reliability of the identification results for TL. The signal intensity of PPSL and TL for irradiated teas decreased with the lapse of post-irradiation storage time at room temperature but was still distinguishable from that of the non-irradiated samples even after one year.

전자빔 조사가 ZnO 박막의 전기적 특성 변화에 미치는 영향 (Influence of Electron Beam Irradiation on the Electrical Properties of ZnO Thin Film Transistor)

  • 최준혁;조인환;김찬중;전병혁
    • 한국전기전자재료학회논문지
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    • 제30권1호
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    • pp.54-58
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    • 2017
  • The effect of low temperature ($250^{\circ}C$) heat treatment after electron irradiation (irradiation time = 30, 180, 300s) on the chemical bonding and electrical properties of ZnO thin films prepared using a sol-gel process were examined. XPS (X-ray photoelectron spectroscopy) analysis showed that the electron beam irradiation decreased the concentration of M-O bonding and increased the OH bonding. As a result of the electron beam irradiation, the carrier concentration of ZnO films increased. The on/off ratio was maintained at ${\sim}10^5$ and the $V_{TH}$ values shifted negatively from 11 to 1 V. As the irradiation time increased from 0 to 300s, the calculated S. S. (subthreshold swing) of ZnO TFTs increased from 1.03 to 3.69 V/decade. These values are superior when compared the sample heat-treated at $400^{\circ}C$ representing on/off ratio of ${\sim}10^2$ and S. S. value of 10.40 V/decade.

방사선조사(放射線照射)와 자연저온(自然低溫)에 의한 발아식품(發芽食品)의 Batch Scale저장(貯藏)에 관(關)한 연구(硏究) -제4보(第四報) : 밤의 저장(貯藏)- (Batch Scale Storage of Sprouting Foods by Irradiation Combined with Natural Low Temperature -Ⅳ. Storage of Chestnuts-)

  • 조한옥;양호숙;변명우;권중호;김종군
    • 한국식품과학회지
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    • 제15권3호
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    • pp.231-237
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    • 1983
  • 감마선(線) 조사(照射)와 자연저온(自然低溫)에 의한 밤의 상업적(商業的) 저장법(貯藏法) 개발(開發)을 목표(目標)로 $15{\sim}30Krad$ 범위의 감마선(線)을 조사(照射)하고 자연저온(自然低溫) 저장고(貯藏庫)에 batch scale로 저장(貯藏)하면서 이화학적(理化學的) 변화(變化)를 조사(調査)하여 다음과 같은 결과(結果)를 얻었다. 1. 밤의 발아율(發芽率)은 저장(貯藏) 7 개월(個月)에 비조사구(非照射區)는 100% 발아(發芽)하였으나 적정선량(適正線量)이라 생각되는 $20{\sim}25Krad$ 조사구(照射區)는 $5{\sim}14%$만 발아(發芽)하였고, 부패(腐敗) 및 중량변화(重量變化)에서도 방사선(放射線) 조사구(照射區)가 비조사구(非照射區) 보다 양호(良好)하였으며, 육질(肉質)및 조직(組織)도 25 Krad 범위(範圍)의 조사구(照射區)가 우수하였다. 2. 화학성분(化學成分) 변화(變化)에 있어서 9 개월간(個月間) 저장중(貯藏中)에 수분(水分) 및 환원당은 저장기간(貯藏期間)이 경과(經過)함에 따라 전당(全糖)의 감소(減少)와 비례적(比例的)으로 증가(增加)하였는데 이러한 변화(變化)는 비조사구(非照射區)가 조사구(照射區)보다 심하였다. Ascorbic acid 는 저장기간(貯藏間)이 경과(經過)함에따라 각구(各區) 모두 감소현상(減少現象)을 보였으며 비조사구(非照射區) 보다 조사구(照射區)의 함량(含量)이 높았다.

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방사선(放射線) 조사(照射)와 자연저온(自然低溫)에 의한 발아식품(發芽食品)의 Batch Scale 저장(貯藏)에 관(關)한 연구(硏究) - 제2보(第二報) : 조사(照射)감자의 장기간(長期間) 저장후(貯藏後) Potato Chip 가공적성(加工適性)에 대하여 - (Batch Scale Storage of Sprouting Foods by Irradiation Combined with Natural Low Temperature - II. Suitability for Potato Chip Processing of Irradiated Potatoes after Storage -)

  • 변명우;이철호;조한옥;권중호;양호숙
    • 한국식품과학회지
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    • 제14권4호
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    • pp.364-369
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    • 1982
  • 감마선 조사(照射)와 자연저온(自然低溫)에 의한 감자의 상업적(商業的) 저장법(貯藏法) 개발(開發)을 목표(目標)로 제일보(第一報)와 같은 방법으로 Irish cobbler와 Shimabara 품종(品種)을 7개월(個月) 및 9개월간(個月間) 각각(各各) 저장(貯藏)하면서 potato chip 제조적성(製造適性)에 대한 실험(實驗)을 한 결과(結果)는 다음과 같다. 1. 9개월간(個月間) 저장(貯藏)한 Irish cobbler로 제조(製造)된 potato chip은 기계적(機械的) 및 관능검사결과(官能檢査結果) 대조구(對照區)가 무처리구(無處理區)보다 우수하였다. 2. Potato chip 수율(收率)에 영향이 큰 제피율(除皮率)에 따른 손실은 무처리구(無處理區)가 조사구(照射區)보다 $20{\sim}25%$ 높았다. 3. 단경기(端境期)에 있어서 potato chip 가공원료(加工原料)로써 방사선(放射線)과 자연저온(自然低溫)에 의하여 저장(貯藏)된 감자가 적당하였다.

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The effects of LED light quality on ecophysiological and growth responses of Epilobium hirsutum L., a Korean endangered plant, in a smart farm facility

  • Park, Jae-Hoon;Lee, Jung-Min;Kim, Eui-Joo;You, Young-Han
    • Journal of Ecology and Environment
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    • 제46권3호
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    • pp.161-171
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    • 2022
  • Background: Epilobium hirsutum L. is designated as an endangered plant in South Korea located in Asia, due to the destruction of its habitats through the development of wetlands. Therefore, in this study, in order to find a light condition suitable for the growth and ecophysiological responses of Epilobium hirsutum L., those of this plant under treatment with various light qualities in a smart farm were measured. Results: In order to examine the changes in the physiological and growth responses of Epilobium hirsutum L. according to the light qualities, the treatment with light qualities of the smart farm was carried out using the red light: blue light irradiation time ratios of 1:1, 1:1/2, and 1:1/5 and a red light: blue light: white light irradiation time ratio of 1:1:1. As a result, the ecophysiological responses (difference between leaf temperature and atmospheric temperature, transpiration rate, net photosynthetic rate, intercellular CO2 partial pressure, photosynthetic quantum efficiency) to light qualities appeared differently according to the treatments with light qualities. The increase in the blue light ratio increased the difference between the leaf temperature and the atmospheric temperature and the photosynthetic quantum efficiency and decreased the transpiration rate and the intercellular CO2 partial pressure. On the other hand, the white light treatment increased the transpiration rate and intercellular CO2 partial pressure and decreased the temperature difference between the leaf temperature and the ambient temperature and photosynthetic quantum efficiency. Conclusions: The light condition suitable for the propagation by the stolons, which are the propagules of Epilobium hirsutum L., in the smart farm, is red, blue and white mixed light with high net photosynthetic rates and low difference between leaf temperature and atmospheric temperature.

이온빔 조사된 저온 소성 인듐 아연 산화막을 이용한 액정의 고속 스위칭 특성 연구 (Fast liquid crystal switching performance on indium zinc oxide films with low curing temperature via ion-beam irradiation)

  • 오병윤
    • 전기전자학회논문지
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    • 제23권3호
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    • pp.904-909
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    • 2019
  • $100^{\circ}C$에 소성한 인듐 아연 산화막 (IZO)을 이온빔 처리하여, 균일할 수평 액정 배향을 구현하였다. 유리 기판 위에 코팅된 IZO 박막을 $100^{\circ}C$에 소성하고 액정 배향 기술로 이온빔을 사용하였다. 이것을 이용하여 얻어진 액정 배향의 특성을 분석하기 위해서, 편광 현미경과 결정 회전법을 사용하였다. 또한 이온빔 처리된 IZO 박막을 이용하여 만든 액정 셀이 높은 품질의 액정 소자에 충분한 열적 안정성을 가진다는 것을 확인할 수 있었다. 그리고 전계방출 주사 전자 현미경을 이용하여 이온빔의 IZO 박막의 표면에 미치는 영향을 분석하였다. 이것을 통하여 이온빔이 IZO 박막 표면의 거칠기를 변화시키고, 액정 배향에 영향을 준다는 것을 확인할 수 있었다. 마지막으로 IZO 박막으로 제작한 액정 셀의 전기-광학 특성을 측정하였다. 그리고 이것이 기존에 사용되는 러빙법 처리된 폴리이미드 박막으로 제작한 액정 셀보다 뛰어난 특성을 가진다는 것을 확인하였다. 또한 액정 고정 에너지를 측정하여 이것이 균일한 액정 배향을 구현하기 위한 적합한 특성을 가진다는 것을 확인하였다.

아르곤 레이저를 이용한 광중합 수복재의 물리적 성질에 관한 연구 (A STUDY ON THE PHYSICAL PROPERTIES OF RESTORATIVE MATERIALS FOR PHOTO-POLYMERIZATION OF ARGON LASER)

  • 주상호;최형준;김성오;이종갑
    • 대한소아치과학회지
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    • 제25권2호
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    • pp.368-382
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    • 1998
  • The purpose of this study is to evaluate and compare the results of argon laser for 5 seconds, argon laser for 10 seconds, and visible light for 40 seconds photo-polymerization in compressive strength, microhardness, curing depth, temperature rising during polymerization, and polymerization shrinkage. Hybrid type composite resin(Z-100) and compomer(Dyract) were used to be compared. The compressive strength was measured by an Instron(1mm/min cross head speed) in 60 specimens and the microhardness of the surface was expressed by Vickers Hardness Number(VHN) in 30 specimens. The curing depth was evaluated comparing the different values of upper and lower VHN according to irradiation time and thickness for the light source polymerization in 60 specimens. The temperature rising during photopolymerization was observed by the temperature change with thermocouple sensitizer beneath 40 specimens at the argon laser for 10 seconds and visible light 40 seconds irradiation. The polymerization shinkage was evaluated by calculating the decrease of % volume by using a dilatometer in 30 specimens. The results were as follows ; 1. In the case of compressive strength, the argon laser polymerization groups were higher than visible light group in Z-100 (p<0.05). In Dyract, the argon laser 5 seconds group did not show a significant difference with the visible light 40 seconds group. The argon laser 10 seconds group showed the markedly low value when compared with other groups (p<0.05) 2. In microhardness, Z-100 was better than Dyract when comparing by VHNs (p<0.05); however, there was not a significant difference between two materials in the visible light 40 seconds group and the argon laser 10 seconds group. 3. In the study of curing depth, Z-100 showed the consistent polymerization in argon laser irradiation because there was no difference in the VHN decrease according to the thickness change. Over the thickness control, the results did not show a significant difference between visible light and argon laser group in Z-100; however, in the case of Dyract, the visible light 40 seconds group was better than the argon laser groups(p<0.05). 4. There was a significant difference between the two materials in temperature rising during polymerization (p<0.05), but not a significant difference between irradiation times, 5. There was not a significant difference between the two materials in polymerization shrink age. The argon laser 5 seconds group was smaller than the other groups (p<0.05). It could be concluded that Z-100 polymerization was recommended to use the argon laser for reduction of the irradiation time while Dyract was recommended to use the visible light polymerization.

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