• Title/Summary/Keyword: low temperature irradiation

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Overhauser dynamic nuclear polarization for benchtop NMR system using a permanent magnet of 1.56 T

  • Lee, Yeon-seong;Lim, Duk-Young;Shim, Jeong Hyun
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.3
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    • pp.81-86
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    • 2019
  • Overhauser dynamic nuclear polarization (O-DNP) has been an efficient method to boost the thermal nuclear polarization in liquids at room temperature. However, O-DNP for a benchtop NMR using a permanent magnet has remained unexplored yet. In this work, we report the development of an O-DNP system adopting a permanent magnet of 1.6 T. Q-band (~43 GHz) high-power amplifier produced 6 W microwave for saturation. Instead of resonator, we used an open-type antenna for the microwave irradiation. For several representative small molecules, we measured the concentration and frequency dependences of the enhancement factor. This work paves the way for the development of a benchtop DNP-NMR system overcoming its disadvantage of low quality signal when using a permanent magnet.

Principles and Applications of Non-Thermal Technologies for Meat Decontamination

  • Yewon Lee;Yohan Yoon
    • Food Science of Animal Resources
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    • v.44 no.1
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    • pp.19-38
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    • 2024
  • Meat contains high-value protein compounds that might degrade as a result of oxidation and microbial contamination. Additionally, various pathogenic and spoilage microorganisms can grow in meat. Moreover, contamination with pathogenic microorganisms above the infectious dose has caused foodborne illness outbreaks. To decrease the microbial population, traditional meat preservation methods such as thermal treatment and chemical disinfectants are used, but it may have limitations for the maintenance of meat quality or the consumers acceptance. Thus, non-thermal technologies (e.g., high-pressure processing, pulsed electric field, non-thermal plasma, pulsed light, supercritical carbon dioxide technology, ozone, irradiation, ultraviolet light, and ultrasound) have emerged to improve the shelf life and meat safety. Non-thermal technologies are becoming increasingly important because of their advantages in maintaining low temperature, meat nutrition, and short processing time. Especially, pulsed light and pulsed electric field treatment induce few sensory and physiological changes in high fat and protein meat products, making them suitable for the application. Many research results showed that these non-thermal technologies may keep meat fresh and maintain heat-sensitive elements in meat products.

Study on Reliability of Vapor Cell by Laser Packaging with Au/Au-Sn Heterojunction (Au/Au-Sn 이종접합 적용 레이저 패키징을 통한 Vapor Cell 신뢰성 연구)

  • Kwon, Jin Gu;Jeon, Yong Min;Kim, Ji Young;Lee, Eun Byeol;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.367-372
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    • 2020
  • As packaging processes for atomic gyroscope vapor cells, the glass tube tip-off process, anodic bonding, and paste sealing have been widely studied. However, there are stability issues in the alkali metal which are caused by impurity elements and leakage during high-temperature processes. In this study, we investigated the applicability of a vapor cell low-temperature packaging process by depositing Au on a Pyrex cell in addition to forming an Au-Sn thin film on a cap to cover the cell, followed by laser irradiation of the Au/Au-Sn interface. The mechanism of the thin film bonding was evaluated by XRD, while the packaging reliability of an Ne gas-filled vapor cell was characterized by variation of plasma discharge behavior with time. Furthermore, we confirmed that the Rb alkaline metal inside the vapor cell showed no color change, indicating no oxidation occurred during the process.

Treatment Cost Comparison and Development of Sustainability Indices for Microwave Soil Remediation of TPHs(Total Petroleum Hydrocarbons)

  • Kim, Dong Uk;Koo, Ja-Kong
    • Journal of Soil and Groundwater Environment
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    • v.20 no.5
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    • pp.11-15
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    • 2015
  • The three processes of 1) high- & low-temperature microwave heatings, 2) the soil washing, and 3) the thermal desorption processes in soil remediation are analysed on the treatment cost data for 2003-2012 years. The cost of microwave heating method with at temperature 500-700℃, for 30 minutes, and at 4-6 kW is approximately 10 $/ton (13,000 ₩) due to the deep through heating of micro-wave, the soil washing with chemicals is about 80 $/ton (85,000 ₩) due to the chemicals & duration, and the thermal desorption process is around 40 $/ton (41,000 ₩) from the less efficiency. Furthermore the sustainability has been assessed, and suggestions are made. 1) Green; the minimal environmental footprint, 2) Growth; the least cost, 3) Shared; the social & environmental justice, 4) Smart; the microwave characteristics of deep through irradiation & heating, and 5) Mutuality; the flexibility of the technology. More additives including water, the government support, and public relation are suggested realizing the microwave in this condition is not harmful to human beings.

Analysis of Performance of Building Integrated PV System of Cold Facade type (Cold facade형 BIPV시스템의 발전성능 분석)

  • Kim, Hyun-II;Kang, Gi-Hwan;Park, Kyung-Eun;Yu, Gwon-Jong;Shu, Seung-Jik
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.275-280
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    • 2008
  • Photovoltaic(PV) permit the on-site production of electricity without concern for fuel supply or environmental adverse effects. The electrical power is produced without noise and little depletion of resources. So BIPV(Building-Integrated Photovoltaic) system have been increased around the world. Hereby the relative installation costs of the system will be relatively low compared to traditional installations of PV in high-rise buildings. This paper examined possibility of BIPV system of cold facade type and analyzed of performance of BIPV system of cold facade type. The system is influenced by conditions such as irradiation, module temperature, shade and architectural component etc. If this BIPV system of 1.1kW is possible the natural ventilation in the summer case, the temperature of PV module decrease and then the efficiency of PV system increase generally. By the results, the annual averaged PR of BIPV system of cold facade type is about 73.1%.

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Electron Spin Resonance of an Irradiated Single Crystal of L-alanine (인체 등가물질에 대한 방사선 조사)

  • 한영환;권수일
    • Progress in Medical Physics
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    • v.4 no.1
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    • pp.41-53
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    • 1993
  • The electron spin resonanec of sigle crystals of L-alanine have been observed at T=300K, 100K and analyzed for different orieantations of the crystal in the magnetic field and at microwave frequency X-band. The stable free radical profuced by the irradiation is proved to be of the form CH$_3$CHR, where R is a group which has no nuclei with detectable coupling A notable dependence on temperature of the absorption was observed in the range from 1100K to 2l0K. It was concluded that the reorietation of the methy group of the radical H$_3$CCHR is quenched at low temperature.

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Effect of columnar defects on the irreversibility line in pristine and iodine-intercalated Bi$_2$Sr$_2$CaCu$_2$O$_{8+{\delta}} single crystals

  • Kim, Ki-Joon;Kim, Mun-Seog;Choi, Jae-Hyuk;Kang, W.N.;Lee, Sung-Ik;Ha, Dong-Han;Kim, Dong-Ho
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.45-50
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    • 2000
  • We have investigated the influence of columnar defects (CD) on the vortex dynamics in pristine and iodine-intercalated Bi$_2$Sr$_2$CaCu$_2$O$_{8+{\delta}} single crystals from do SQUID magnetization measurements. Especially, the temperature dependence of the irreversibility fields, H$_{irr}$(T), were studied. Anisotropy ratio ${\gamma}$, estimated from the fitting to the 2-dimensional melting model (A. Schilling et al., Phys. Rev. Lett. 71 1899 (1993)) in higher fields than the matching field B$_{\phi}$ at low temperature region, turns out to be decreased by the iodine-intercalation and additionally by the heavy-ion irradiation.

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An ESR Study of Amino Acid and Protein Free Radicals in Solution. Part IV. An ESR study of Gamma-Irradiated Amino Acids in Frozen Aqueous Solutions.

  • Sun-Joo Hong;D. E. Holmes;L. H. Piette.
    • Journal of the Korean Chemical Society
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    • v.15 no.5
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    • pp.256-265
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    • 1971
  • An ESR study has been made on free radicals produced in frozen aqueous solutions (ices) of glycine, DL-${\alpha}$-alanine, DL-serine, L-cysteine, DL-leucine and DL-isoleucine by gamma-irradiation at dry ice temperature. All free radicals induced were decayed concomitant to the successive annealing but the radical species which is believed to be dominant seems to be stable even near the melting point of the ice. These dominant species were found to be identical to those resulted from direct action of radiation in the solid at room temperature. Small but significant changes in the spectra of glycine and DL-${\alpha}$-alanine were observed by varying the microwave power. These results seem to support the view that the spectra obtained were composite consisting of more than two different resonances having different power saturation characteristics. The relative contribution of unidentified resonances to the composite spectra was greater for solutions of low concentration. These resonances are assumed to be induced by indirect effects, mainly hydrogen abstraction by radiation produced hydroxyl radicals and also C-N bond cleavage by hydrated electrons.

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Evaluation of Radiation Degradation or Crosslinked Polyethylene using TGA (TGA를 이용한 가교폴리에틸렌의 방사선 열화 평가)

  • Lee, Chung;Kim, Ki-Yup;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Journal of the Korean Society of Safety
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    • v.18 no.2
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    • pp.50-55
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    • 2003
  • Radiation degradation of crosslinked polyethylene(XLPE) was investigated using thermogravimetric analysis(TGA), The results of TGA were compared with FT-IR, melting temperature, oxidation induction time, and elongation at break on the XLPE exposed by $\gamma$-ray. 5% decomposition temperature of $\gamma$-ray irradiated XLPE showed similar tendencies with the case of elongation at break. Both properties agreed below 1000 KGy, however, did not show any remarkable characteristics above 1000 kGy, these properties can be useful to evaluate the radiation degradation of XLPE for only low irradiated region. Above 1000 kGy, the thermal decomposition activation energy showed decreased, on the contrary, increasing below 1000 kGy. Compared with FT-IR spectrum of irradiated XLPE, it was confirmed that the oxidation reaction was still occurring below 1000 kGy. Radiation degradation of XLPE was dependent upon the irradiation doses, TGA can be a useful tool to evaluate the degradation.

A Research Trend on Space Charge Analysis in Polymer Irradiated by Electron Beam (온도 상승시에 전자빔 조사된 폴리머내의 전하 분포의 축퇴 현상 연구 동향)

  • Ko, Sung-Min;Kim, Nam-Yong;Kim, Dae-Yeol;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1992-1993
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    • 2007
  • Decay processes of accumulated charge in e-beam irradiated polymers during elevating temperature are observed using pulsed electro-acoustic measurement system. Since the polymeric materials have many superior properties such as light-weight, good mechanical strength, high flexibility and low cost, they are inevitable materials for spacecrafts. In space environment, however, the polymers sometimes have serious damage by irradiation of high energy charged particles. When the polymers of the spacecraft are irradiated by high energy charged particles, some of injected charges accumulate and remain for long time in the bulk of the polymers. Since the bulk charges sometimes cause the degradation or breakdown of the materials, the investigation of the charging and the decay processes in polymeric materials under change of temperature is important to decide an adequate material for the spacecrafts. By measuring the charge behavior in e-beam irradiated polymer, such as polyimide or polystyrene, it is found that the various accumulation and decay patterns are observed in each material. The results seem to be useful and be helpful to progress in the reliability of the polymers for the spacecraft.

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