• Title/Summary/Keyword: low pressure of oxygen

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Electrical Conduction in $SrZr_{0.95}Y_{0.05}O_{2.975}$ Ceramics

  • Baek, Hyun-Deok;Noh, Jin-Hyo
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.288-295
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    • 1999
  • Partial conductivities contributed by electron holes, oxygen ions, and protons were caluclated in $SrZr_{0.95}Y_{0.05}O_{2.975}$, using the reported formulae derived from the defect chemistry of HTPCs. Required parameters were obtained from the graphical analysis of total conductivity variation against partial pressure of water vapor and oxygen. Predicted overall conductivities showed a reasonable agreement with experimental measurements. The conductivity of the material showed a linear increase with square root of the water vapor pressure. This increase was due to proton conduction in an almost pure ionic conductivity. The calculation of partial conductivities at $800^{\circ}C$ resulted in an almost pure ionic conductivity at $P_{02}=10^{-10}$ atm and a predominant hole conductivity at $P_{02}=10^{-10}$ atm. Pure proton conduction was not expected at this temperature, contrary to the earlier reports. Discussions were made in relation with reported thermodynamic data and defect structure of the material. It was shown that from the total conductivity dependence on water vapor pressure, the pure ionic conductivity at low oxygen partial pressures could be separated into protonic and oxygen ionic conductivity in $ZrO_2$-based HTPCs.

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Development of low power type sensor for the DO concentration measurement by clark electrode (Clark전극에 의한 DO 농도측정을 위한 절전형 센서개발에 관한 연구)

  • 이동희
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.254-260
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    • 1995
  • A method is described for the design and fabrication of the sensor interface circuits on the Clark electrodes for the dissolved oxygen(DO). The discussion includes a method for the +5 V single-supply driving for the sensor circuits, which has low power comsumption for the front-end electronics. DO probe under test is composed of the Clark electrode with silver anode, gold cathode and the electrolyte of half saturated KCI solution and the FEP teflon memtrance for the oxygen penetration. Typical polarograms for the DO probes by using this sensor circuit reveals high accuracy over 99% of the I to V conversion. Partial pressure of oxygen obtained from the polarograms are well suited to the results calculated. It is expected that the proposed sensor circuits can be utilized into the customized IC for the battery-driven small-size DO meters.

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Reduction Characteristics of Oxygen Carriers in a Pressurized Bubbling Fluidized Bed (가압 기포유동층에서 산소전달입자들의 환원반응특성)

  • YOON, JOO-YOUNG;BAE, DAL-HEE;BAEK, JEOM-IN;RYU, HO-JUNG
    • Journal of Hydrogen and New Energy
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    • v.27 no.5
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    • pp.589-596
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    • 2016
  • Effects of pressure, temperature, gas velocity, and fuel flow rate on reduction of three oxygen carriers, SDN70, OC-1, OC-2, were measured and investigated in a pressurized bubbling fluidized bed reactor. Among three oxygen carriers OC-2 was selected as the best oxygen carrier in view of fuel conversion and $CO_2$ selectivity. However, all oxygen carriers showed good reactivity even at high pressure conditions. SDN70 particle showed maximum reactivity at $900^{\circ}C$ and low reactivity at $950^{\circ}C$. However, reactivity decay of OC-1 and OC-2 particles at high temperature condition was negligible. The fuel conversion and the $CO_2$ selectivity slightly decreased as the gas velocity increased, whereas they are slightly increased as the fuel concentration increased.

superconducting properties of Bi-2223 tapes with various heat treatment condition (열처리 온도 및 분위기 변화에 따른 Bi-2223 초전도 선재에서의 특성변화)

  • 하동우;이동훈;하홍수;오상수;김홍대;양주생;윤진국;최정규;권영길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.527-530
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    • 2002
  • A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. In this paper, initial annealing of Bi-2223/Ag wire to transform Bi-2212 orthorhombic from Bi-2212 tetragonal Precursor was investigated. This initial annealing step at low oxygen partial pressure were to transform Bi-2212 orthorhombic structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 Phases were appeared at higher annealing temperature. Critical currents(Je) of Bi-2223/Ag tapes were sintered at low oxygen Partial pressure were higher than that of the wires sintered at atmosphere condition. In order to investigate the effect of rolling reduction ratio, Bi-2223/Ag HTS tapes were rolled with different reduction ratio. There were no clear difference of Je and filaments shape with various rolling reduction ratio.

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Fabrication of Cu-Sheathed Bi-Sr-Cu-O High Temperature Superconductor Thick Films (동피복재법을 이용한 Bi-Sr-Ca-Cu-O 고온초전도 후막 제조)

  • 한상철;성태현;한영희;이준성;정상진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 1999.02a
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    • pp.22-25
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    • 1999
  • A well oriented Bi-2212 superconductor thick films were fabricated by screen printing with a Cu-free Bi-Sr-Ca-Cu-O powder on a copper plate and heat-treating at 820- $880^{\circ}C$for several minute in low oxygen pressure or are. At minute in low oxygen pressure of air. At , the printing layer partially melted by reaction between the Cu-free precursor by reaction between the Cu-free$870^{\circ}C$ precursor and CuO of the oxidizing copper plate. It is believed that the solid phase is Bi : Sr : Ca : Cu = 2 : 2 : 0 : 1. It is likely that the Bi-2212 superconducting phase is formed at Bi-2212 superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows.

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Characteristics of Low Temperature Combustion in Single Cylinder Engine by High EGR Rate (단기통 엔진에서 대유량 EGR을 통한 저온 연소 특성)

  • Cho, Sang-Hyun;Oh, Kwang-Chul;Lee, Chun-Beom
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.4
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    • pp.79-85
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    • 2009
  • Low temperature combustion regime for the simultaneous reduction of nitrogen oxides ($NO_x$) and paticulate matter (PM) is demonstrated in single cylinder engine at various operating parameters, such as EGR rate, injection timing, EGR temperature, amount of fuel and swirl rate. Low temperature combustion is accomplished by high exhaust gas recirculation (EGR) rate in this study. Generally, the emission of $NO_x$ almost completely disappears and PM significantly increases in the first decreasing regime of oxygen concentration but after peaking about 10~12% oxygen concentration, PM then decreases regardless of fuel injection quantity. Low temperature combustion regime was extended by low EGR temperature, high injection pressure and low amount of fuel.

PSP Pressure Field Visualization of an Oblique Impinging Jet (경사충돌제트의 PSP 압력장 가시화)

  • Kang Jong Hoon;Lee Sang Joon
    • 한국가시화정보학회:학술대회논문집
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    • 2004.11a
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    • pp.10-13
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    • 2004
  • The PSP(pressure sensitive paint) technique has recently received a large attention as a new revolutionary optical method to measure absolute pressure distribution on a model surface. The PSP technique can be applied to quantitatively investigate flow structure using a CCD camera and image processing technique. In the static calibration, the luminescent intensity of PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. In this study, the low-pressure PSP technique was applied to an oblique impinging jet to measure pressure field variations on the impingement plate with varying angle of an oblique jet. The flow structure over the impingement plate was visualized using a surface tracing method. As a result, the detail pressure field distributions of the oblique low-speed impinging jet were visualized effectively using the PSP technique.

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Effects of Pressure and Dissolved Oxygen Concentration on the Activated Sludge (압력 및 용존산소 농도가 활성슬러지에 미치는 영향)

  • Yang, Byeong-Su;Sin, Hyeon-Mu;Jeong, Hyeong-Suk;Ryu, Dong-Chun;Yun, Jong-Ho;Jeong, Byeong-Gon
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.107-107
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    • 1995
  • This study was conducted to evaluate the effects of pressure and dissolved oxygen concentration on the activated slut비e and to determine the optimum depth of deep shaft process. Some results from this study were summarized as follows. 1. It is considered that low sludge product in the activated sludge system maintaining high dissolved oxygen concentration is attributed to the increase of endogeneous respiration rate caused by the increase of aerobic zone in the sludge floe. 2. The increase of dissolved oxygen concentration does not affect to the increase of organic removal efficiency greatly and therefore the limiting factor is the substrate transfer into the inner part of floe. 3. The yield coefficient, Y is decreased in proportion to the increase of oxygen concentration. In this study, Y values arre ranged from 0.70 to 0.41 according to the variation of dissolved oxygen concentration from 18.0mg/$\ell$ to 258 mg/$\ell$. 4. The optimum depth of deep shaft process should be determined within the limits of non-toxicity to the microorganism and it is about loom in this study.

The Structural and Electrical Properties of Vanadium Oxide Thin Films as $O_2/(Ar+O_{2})$ ratio ($O_2/(Ar+O_{2})$비에 따른 바나듐 산화막의 구조적, 전기적 특성)

  • 최용남;최복길;최창규;김성진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.729-732
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    • 2001
  • In this study, the effect of oxygen partial pressure on the electrical properties of vanadium oxide(VO$_{x}$) thin films were investigated. The thin films were prepared by r.f. magnetron sputtering from V$_2$O$_{5}$ target in a gas mixture of argon and oxygen. The oxygen partial pressure ratio is changed from 0% to 8%. I-V characteristics were distinguished between linear and nonlinear region. In the low field region the conduction is due to Schottky emission, while at high fields it changes to Fowler-Nordheim tunneling type conduction. The conductivity measurements have shown an Arrhenius dependence of the conductivity on the temperature.ure.

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