• Title/Summary/Keyword: low permeability

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Percolation Approach to the Morphology of Rigid-Flexible Block Copolymer on Gas Permeability

  • 박호범;하성룡;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.69-70
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    • 1997
  • Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

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The Variation of Permeability and$Q_{max}$ Frequency with Processing Parameters in NiCuZn Ferrites (제조 공정 Parameter에 따른 NiCuZn Ferrite의 투자율과 $Q_{max}$ 주파수 변화)

  • 신재영;박지호;박진채;한종수;송병무
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.19-24
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    • 1997
  • Composition and process conditions for low temperature sintered NiCuZn ferrites were investigated, so as to fabricate multilayered chip inductor. The$Fe_2O_3$ deficiency for low temperature sintering was decreased with NiO contents of NiCuZn ferrites. The permeability of NiCuZn ferrites can be controlled in the range of 12~562 with the variation of NiO and $Co_3O_4$ contents. The $Q_{max} $ frequency of NiCuZn ferrites was decreased from 50 MHz to 3 MHz linearly with permeability increase from 60 to 560. The relation between the $Q_{max}$ frequency(Y) and permeability(X) of NiCuZn ferrites was expressed with the following empirical equation, logY=4.2-1.4logX.

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Preparation and Electrochemical Applications of Pore-filled Ion-exchange Membranes with Well-adjusted Cross-linking Degrees: Part I. All Vanadium Redox Flow Battery (가교도가 조절된 세공충진 이온교환막의 제조 및 전기화학적 응용: Part I. 전 바나듐 레독스 흐름전지)

  • Lee, Ji-Eun;Park, Ye-Rin;Kim, Do-Hyeong;Kang, Moon-Sung
    • Membrane Journal
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    • v.27 no.5
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    • pp.406-414
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    • 2017
  • In this study, we have developed pore-filled ion-exchange membranes (PFIEMs) filled with ionomer in a thin polyethylene porous film (thickness = $25{\mu}m$) and investigated the charge-discharge characteristics of the all vanadium redox flow battery (VRFB) employing them. Especially, the degree of crosslinking and free volume of the PFIEMs were appropriately controlled to produce ion-exchange membranes exhibiting both the low membrane resistance and low vanadium permeability by mixing crosslinking agents having different molecular size. As a result, the prepared PFIEMs exhibited excellent electrochemical properties which are comparable to those of the commercial membranes. Also, it was confirmed through the experiments of vanadium ion permeability and VRFB performance evaluation that the PFIEMs showed low vanadium ion permeability and high charge-discharge efficiency in comparison with the commercial membrane despite their thin film thickness.

Centrifuge Modeling of Soft Clay with Vertical Drains Considering the Centrifuge Similarity (상사성을 고려한 배수재 설치 연약점토 지반의 원심모델링)

  • Yoo, Nam-Jae;Hong, Young-Kil;Jeong, Gil-Soo;Cho, Han-Ki
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.111-120
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    • 2007
  • This paper is results of experimental research on the effect of application of similarity related to permeability of soil on the consolidation behavior as centrifuge modeling of consolidation is performed with the centrifuge model facility. In this research, the permeability of soil was controlled by changing the viscosity of porewater as the mixed water with glycerin was used during the centrifuge model experiments. The effect of drainage path on consolidation was investigated by installing the vertical drains. A serise of centrifuge model tests with conditions of single vertical and radial horizontal drainage were carried out. Kaolinite and Jumunjin standard sand were used as soft clay and surcharges respectively during tests. For testing condition of single vertical drainage considering similarity of permeability, it was found that consolidation with mixed porewater with glycerin was delayed in comparisons sons with test results with water only. For conditions of horizontal drainage with vertical drains, a low permeability by changing the viscosity of pore water resulted in delayed degree of consolidation at an initial stage of consolidation. But, it predicted not much differences in settlement as long as the consolidation time was sufficiently long enough to finish consolidation. Consequently, it was found that similarity in permeability should be considered to be critical for the case of centrifuge model experiments related to consolidation with long drainage path.

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Creep-permeability behavior of sandstone considering thermal-damage

  • Hu, Bo;Yang, Sheng-Qi;Tian, Wen-Ling
    • Geomechanics and Engineering
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    • v.18 no.1
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    • pp.71-83
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    • 2019
  • This investigation presented conventional triaxial and creep-permeability tests on sandstones considering thermally-induced damage (TID). The TID had no visible effects on rock surface color, effective porosity and permeability below $300^{\circ}C$ TID level. The permeability enlarged approximately two orders of magnitude as TID increased to $1000^{\circ}C$ level. TID of $700^{\circ}C$ level was a threshold where the influence of TID on the normalized mass and volume of the specimen can be divided into two linear phases. Moreover, no prominent variations in the deformation moduli and peak strength and strain appeared as TID< $500^{\circ}C$ level. It is interesting that the peak strength increased by 24.3% at $700^{\circ}C$ level but decreased by 11.5% at $1000^{\circ}C$ level. The time-related deformation and steady-state creep rate had positive correlations with creep loading and the TID level, whereas the instantaneous modulus showed the opposite. The strain rates under creep failure stresses raised 1-4 orders of magnitude than those at low-stress levels. The permeability was not only dependent on the TID level but also dependent on creep deformation. The TID resulted in large deformation and complexity of failure pattern for the sandstone.

Surface Image Analysis for Evaluating Porosity and Permeability Coefficient of Permeable Concrete Block (투수 콘크리트 블록 공극률 및 투수계수 평가를 위한 표면 이미지 분석 기법 개발)

  • Jo, Sangbeom;Son, Younghwan;Kim, Donggeun;Jeon, Jihun;Kim, Taejin
    • Journal of The Korean Society of Agricultural Engineers
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    • v.65 no.2
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    • pp.47-57
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    • 2023
  • The increase of impermeable area ratio is causing hydrologic cycle problems in urban areas and groundwater depletion in rural areas, permeable pavements are getting attention to expand permeable areas. The performance of the permeable concrete block pavement, which is part of the permeable pavement, is greatly affected by the porosity. In addition, the permeability coefficient is a major factor when designing permeable concrete block pavement. Existing porosity and permeability test methods have problems such as uneconomical or poor field applicability. The object of this study was to develop a methodology for evaluating porosity and permeability coefficient using a surface image of a permeable concrete block. Specimens are manufactured with various porosity ranges and porosity and permeability tests are performed. After surface image preprocessing, normalization and binarization methods were compared. Through this, the method with the highest correlation with the lab test result was determined. From the results, the PDR (pore determined ratio) was obtained. Simple linear regression analysis is performed with PDR and lab test results. The results showed a high correlation of R2 more than 0.8, and the errors were also low.

Dynamic evolution characteristics of water inrush during tunneling through fault fracture zone

  • Jian-hua Wang;Xing Wan;Cong Mou;Jian-wen Ding
    • Geomechanics and Engineering
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    • v.37 no.2
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    • pp.179-187
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    • 2024
  • In this paper, a unified time-dependent constitutive model of Darcy flow and non-Darcy flow is proposed. The influencing factors of flow velocity are discussed, which demonstrates that permeability coefficient is the most significant factor. Based on this, the dynamic evolution characteristics of water inrush during tunneling through fault fracture zone is analyzed under the constant permeability coefficient condition (CPCC). It indicates that the curves of flow velocity and hydrostatic pressure can be divided into typical three stages: approximate high-velocity zone inside the fault fracture zone, velocity-rising zone near the tunnel excavation face and attenuation-low velocity zone in the tunnel. Furthermore, given the variation of permeability coefficient of the fault fracture zone with depth and time, the dynamic evolution of water flow in the fault fracture zone under the variable permeability coefficient condition (VPCC) is also studied. The results show that the time-related factor (α) affects the dynamic evolution distribution of flow velocity with time, the depth-related factor (A) is the key factor to the dynamic evolution of hydrostatic pressure.

Properties of Low Density Foamed Concrete for Building Construction Using Anionic Surfactants of Synthetic and Natural Materials

  • Jeong, Ji-Yong;Kim, Jin-Man
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.557-566
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    • 2011
  • The surfactants facilitate the formation of foam bubbles under a proper condition and provide stability of foam bubbles by decreasing the surface tension of solutions and increasing the viscosity of foam surface. However, there have been almost no practical data of foam concrete in this regard so far. This study aims to understand the effects of foaming agents such as anionic synthetic surfactant and anionic natural material surfactant on the low density foamed concrete. From the experiment, the vegetable soap of anionic natural material surfactants showed a higher foaming rate, more open pores, slightly lower compressive strength, and a higher permeability coefficient compared to the vegetable soap of anionic synthetic surfactants. It is believed that the natural material surfactants make not only the surface tension of the solution low but also the viscosity of slurry high.

A Study on the Properties of EMI filter for the Ni/Zn ratio of Ni-Zn Ferrite (Ni-Zn ferrite의 Ni/Zn비 변화에 따른 EMI 비드 필터 특성 연구)

  • 이재영;김왕섭;손용배;김경용
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.6
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    • pp.848-853
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    • 1993
  • The properties of ferrite bead, a low-pass filter, are determined by the frequency dispersion of the complex permeability. In this study, frequency dispersion of complex permeability of the Ni-Zn ferrites with different Ni/Zn ratio were investigated. Relationship between the behavior of filter and dispersion of complex permeability of a ferrite was studied. As a result, it was concluded that the compositions for Ni/Zn ratio of $0.41{\sim}0.47$, having high initial permeability and good sensitivity, were favorable as a ferrite bead filter.

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A Case Study on the Leakage in Concrete Face Rockfill Dam (콘크리트 표면차수벽형 석괴댐(CFRD)의 누수특성에 관한 사례연구)

  • 방돈석;신창건;이강용;안상로
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.197-202
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    • 2003
  • The leakage quantity through concrete facing of Concrete Face Rockfill Dam(CFRD) is very small due to its low permeability of intact concrete. Even though the concrete facing is well designed and constructed, fine cracks can be generated due to effects of thermal and drying shrinkage. Therefore, it can be said that the leakage from the CFRD is subjected to not permeability of intact concrete but poor joints, cracks and foundation rocks. The Safety of a dam on leakage was evaluated based on the comparison between apparent permeability estimated and leakage quantity measured. The above method can be concluded to give a good direction for the evaluation of safety on CFRD in maintenance aspects as design and construction technology is improved with the accumulation of leakage data.

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