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Applications of Micro-Droplet Cell to Study of Localized Corrosion Resistance of Stainless Steels (스테인리스강의 국부부식 저항성 연구에 미세방울셀의 응용)

  • Kim Sung-Yu;Kim Hee-San
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.70-76
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    • 2006
  • Micro-droplet cell with free droplet as a micro-electrochemical technique has been limited to apply to electrochemical systems with high wetting properties such as an acidic solution and low grade stainless steels(Type 316L). By loading negative pressure to a droplet, control of droplet size, and use of hydrophobic gasket, the cell is modified to be allowed to use for electrochemical systems with high wetting properties. For giving the reliability of new cell, studies on local corrosion were conducted for three different systems-an acidic chloride solution and high chromium ferritic stainless steel, the other acidic chloride solution and type 316, and a neutral chloride solution and type 316. stainless steel. Firstly, the modified micro-droplet cell allows the anodic polarization curves in an acidic chloride solution to show the fact that the local corrosion of high chromium stainless steel near the $\alpha/\sigma$ interface is due to the Cr depleted zone. Secondly, the local anodic polarization test of type 316 L in the other acidic chloride solution can be successfully conducted in the cell. Furthermore, the local polarization curves help elucidating the corrosion of type 316 with $\delta-ferrite$ phase. Finally, the polarization curves of type 316 L in a neutral chloride solution indicates that the factor affecting the pitting corrosion resistance was inclusions rather than $\delta-ferrite$.

Estimation of Water Quality Environment in Youngsan and Seumjin River Basins (영산강과 섬진강 유역의 하천 수질환경 평가)

  • 양해근;최희철
    • Journal of the Korean Geographical Society
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    • v.38 no.1
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    • pp.16-31
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    • 2003
  • The water quality environment in Youngsan and Seumjin river basins was investigated based on the concept of the comprehensive Water Quality Index (WQI) and a spacial pollution source. Artificial factors influencing to river water quality have been analyzed. The specific delivery load of Youngsan river basin was found to be 8.34~97.25 kg/day/$\textrm{km}^2$, Gomagwon stream and Gwangju stream showed the relatively high rates as 97.25 kg/day/$\textrm{km}^2$ and 86.06 kg/day/$\textrm{km}^2$, respectively. The specific delivery load in Seumjin river basin was estimated to be 10.98∼19.51 kg/day/$\textrm{km}^2$, Suggesting no Significant Contribution of pollution. WQI of Youngsan watershed revealed 1.36~3.45, whereas Seumjin watershed showed a relatively low value of 0.5~1.47 And it is concluded that the specific delivery load suggested in this study provides the essential core data of the upper limit of pollutants receptor in the watershed area studied. From this study, it is suggested that the integrated environmental management of river basin requires the analysis of pollutants generation rate of the basin and the receptor capability for the self-purification.

Horizontal Bearing Behavior of Group Suction Piles by Numerical Analysis (수치해석을 이용한 그룹형 석션파일의 수평방향 지지거동 분석)

  • Lee, Ju-Hyung;Lee, Si-Hoon;Kim, Sung-Ryul
    • Journal of the Korean Geotechnical Society
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    • v.29 no.11
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    • pp.119-127
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    • 2013
  • Recently, several researches on the development of new economical foundation types have been performed to support floating structures as many offshore structures have been constructed. This study focused on the evaluation of bearing capacity of group suction piles, which are connected by a concrete pile cap. The offshore floating structures are mainly subjected to horizontal loading, so the horizontal bearing capacities of the group suction piles were analyzed by performing 3-dimensional finite element analyses. The group suction piles are expected to behave as a rigid pile due to its shallow embedded depth. Therefore, the detailed soil modeling was necessary to simulate the bearing behavior of soils under low confining pressure. The modulus and the strength of soils were modelled to increase with effective confining pressure in soils. For the parametric study, the center-to-center spacing between piles was varied and two soil types of clay and sands were applied. The analyses results showed that the yielding load of the group pile increased with the increase of the pile spacing and the yielding load of the group piles with 5D spacing was about 3 times larger than that of the single pile with free rotation.

Porous Structures with Negative Poisson's Ratio using Pattern Transformation Triggered by Deformation (변형에 의한 패턴변화를 활용한 음의 포아송비 다공성 구조)

  • Oh, Myung-Hoon;Choi, Myung-Jin;Byun, Tauk;Cho, Seonho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.4
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    • pp.275-282
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    • 2017
  • In this paper, using a pattern transformation triggered by deformation, we propose a porous structure that exhibits the characteristic of negative Poisson's ratio in both tension and compression. Due to the lack of torque for rotational motion of ligaments, the existing porous structure of circular holes shows positive Poisson's ratio under tension loading. Also, the porous structure of elliptic holes has a drawback of low durability due to stress concentration. Thus, we design curved ligaments to increase the rotational torque under tension and to alleviate the stress concentration such that strain energy is uniformly distributed in the whole structure. The developed structure possesses better stiffness and durability than the existing structures. It also exhibits the negative Poisson ratio in both compression and tension of 10% nominal strain. Through nonlinear finite element analysis, the performance of developed structure is compared with the existing structure of elliptic holes. The developed structure turns out to be significantly improved in terms of stiffness and durability.

Seismic Curvature Ductility of RC Bridge Piers with 2.5 Aspect Ratio (형상비 2.5의 RC 교각의 내진 곡률연성도)

  • Chung, Young-Soo;Park, Chang-Kyu;Lee, Eun-Hee
    • Journal of the Earthquake Engineering Society of Korea
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    • v.8 no.3
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    • pp.1-12
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    • 2004
  • Due to the 1989 Loma Prieta, 1995 Hyogoken Nambu earthquakes, etc, a number of bridge columns  were collapsed in flexure-shear failures as a consequence of the premature termination of the column longitudinal reinforcement. Nevertheless, previous researches for the performance of bridge columns were concentrated on the flexural failure mode. It is well understood that the seismic behaviour of RC bridge piers was dependent on the performance of the plastic hinge of RC bridge piers, the ductility of which was desirable to be computed on the basis of the curvature. Experimental investigation was made to evaluate the variation of the curvature of the plastic hinge  region for the seismic performance of earthquake-damaged RC columns in flexure-shear failure mode. Seven test specimens in the aspect ratio of 2.5 were made with test parameters: confinement ratios, lap splices, and retrofitting FRP materials. They were damaged under series of artificial earthquakes that could be compatible in Korean peninsula. Directly after the pseudo-dynamic test, damaged columns were retested under inelastic reversal cyclic loading under a constant axial load, $P=0.1f_{ck}A_g$. Residual seismic capacity of damaged specimens was evaluated by analzying the moment-curvature hysteresis and the curvature ductility. Test results show that the biggest curvature was developed around 15cm above the footing, which induced the column failure. It was observed that RC bridge specimens with lap-spliced longitudinal steels appeared to fail at low curvature ductility but significant improvement was made in the curvature ductility of RC specimens with FRP straps wrapped around the plastic hinge region. Based on the experimental variation of the curvature of RC specimens, new equivalent length of the plastic hinge region was proposed by considering the lateral confinement in this study. The analytical and experimental relationship between the displacement and the curvature ductility were compared based on this proposal, which gave excellent result.

The Effects of Ethanol on Nano-emulsions Containing Quercetin Prepared by Emulsion Inversion Point Method (에멀젼 반전법으로 제조된 쿼세틴을 함유하는 나노에멀젼에 대한 에탄올의 영향)

  • Park, Soo-Nam;Won, Bo-Ryoung;Kang, Myung-Kyu;Ahn, You-Jin
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.35 no.2
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    • pp.79-89
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    • 2009
  • The objective of this study was to find out the stable formulation of nano-emulsion containing high concentration of quercetin and to investigate the effect of an ethanol on the nano-emulsion prepared by POE (30) hydrogenated castor oil (HCO-30)/oil/quercetin/ethanol/water system. Nano-emulsion was prepared using emulsion inversion point (EIP) method as low-energy method plus homogenizer as high-energy method. To evaluate effect of ethanol and other components on the nano-emulsion, physical properties such as droplet size, morphology, and size distribution were determined. The optimal quercetin concentration was 0.2 % on the nano-emulsion. The droplet diameter was below 300 nm at the HCO-30 concentration below 2.00 %. Nano-emmulsion containing 4.75 % HCO-30 was the most stable and its mean droplet size was 172.40 nm. Finally, the size of nano-emulsion containing 4.00 % ethanol was 128.15 nm and size distribution was also narrow. The results showed that the breakdown process of this nano-emulsion could be attributed to Ostwald ripening. This study about effect of ethanol on the nano-emulsion showed that loading capacity of drug could be increased by using a small amount of ethanol. As prepared stable nano-emulsion, this study showed that these results could be applied to pharmaceutics, cosmetic including skin-care products, perfume and etc.

Facile Synthesis of In2S3 Modified Ag3PO4 Nanocomposites with Improved Photoelectrochemical Properties and Stabilities

  • Zeng, Yi-Kai;Bo, Shenyu;Wang, Jun-hui;Cui, Bin;Gu, Hao;Zhu, Lei;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.601-608
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    • 2020
  • In this work, Ag3PO4/In2S3 nanocomposites with low loading of In2S3 (5-15 wt %) are fabricated by two step chemical precipitation approach. The microstructure, composition and improved photoelectrochemical properties of the as-prepared composites are studied by X-ray diffraction pattern (XRD), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), photocurrent density, EIS and amperometric i-t curve analysis. It is found that most of In2S3 nanoparticles are deposited on the surfaces of Ag3PO4. The as-prepared Ag3PO4/In2S3 composite (10 wt%) is selected and investigated by SEM and TEM, which exhibits special morphology consisting of lager size substrate (Ag3PO4), particles and some nanosheets (In2S3). The introduction of In2S3 is effective at improving the charge separation and transfer efficiency of Ag3PO4/In2S3, resulting in an enhancement of photoelectric behavior. The origin of the enhanced photoelectrochemical activity of the In2S3-modified Ag3PO4 may be due to the improved charge separation, photocurrent stability and oriented electrons transport pathways in environment and energy applications.

Dynamic Deformation Characteristics of Joomunjin Standard Sand Using Cyclic Triaxial Test (반복삼축압축시험을 이용한 주문진 표준사의 동적변형특성 분석)

  • Kim, You-Seong;Ko, Hyoung-Woo;Kim, Jae-Hong;Lee, Jin-Gwang
    • Journal of the Korean Geotechnical Society
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    • v.28 no.12
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    • pp.53-64
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    • 2012
  • In this study, the modified cyclic triaxial tests with Joomunjin standard sand are performed for dynamic deformation characteristics, such as Young's moduli and damping ratio. The cyclic triaxial test is equipped with Local Displacement Transducer (LDT) on the outside of a cell which has a range from $10^{-4}$ to $10^{-1}$ of shear strains, ${\gamma}$ (%), instead of conventional cyclic triaxial test which has linear variable displacement transducer (LVDT) with low precision. With the small strain control, tests were carried out at various loading rates, void ratios, and effective confining pressures. Based on the test results, such as dynamic deformation characteristics, shear modulus, and damping ratio, it is found that the test can measure more range of medium strains (0.02-0.2%) than results obtained from conventional test (resonant column test). For the medium strain range, dynamic deformation characteristics investigated by the cyclic triaxial test are also different from those predicted by nonlinear model in conventional test.

Evaluation of Accuracy of Modified Equivalent Linear Method (수정된 등가선형해석기법의 정확성 평가)

  • Jeong, Chang-Gyun;Kwak, Dong-Yeop;Park, Duhee;Kim, Kwangkyun
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.6
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    • pp.5-20
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    • 2010
  • One-dimensional equivalent linear site response analysis is widely used in practice due to its simplicity, requiring only few input parameters, and low computational cost. The main limitation of the procedure is that it is essentially a linear method, in which the time dependent change in the soil properties cannot be modeled and constant values of shear modulus and damping is used throughout the duration of the analysis. Various forms of modified equivalent linear analyses have been developed to enhance the accuracy of the equivalent linear method by incorporating the dependence of the shear strain with the loading frequency. The methods are identical in that it uses the shear strain Fourier spectrum as the backbone of the analysis, but differ in the method in which the strain Fourier spectrum is smoothed. This study used two domestically measured soil profiles to perform a series of nonlinear, equivalent linear, and modified equivalent linear site response analyses to verify the accuracy of two modified procedures. The results of the analyses indicate that the modified equivalent linear analysis can highly overestimate the amplification of the high frequency components of the ground motion. The degree of overestimation is dependent on the characteristics of the input ground motion. Use of a motion rich in high frequency contents can result in unrealistic response.

Failure Analysis of Corroded Coating Materials by Acoustic Emission (음향방출법에 의한 용사코팅 피막부식재의 파손 해석)

  • KIM GUI-SHIK;HYUN CHANG-HAE;HONG YONG-UI;SHON CHANG-HWAN
    • Journal of Ocean Engineering and Technology
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    • v.19 no.5 s.66
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    • pp.43-49
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    • 2005
  • This paper is to investigate the effect of corrosion by acoustic emission method in tensile loading and the adhesiveness between substrate and coating layer. The powders used are Zn and Amdry625, respectively. They are coated on brass alloy substrate. AE signals of Zn and Amdry625 coating layer increase drastically in strain $2\%$. However, those of Zn specimen have more than those of Amdry625 specimen. When the specimens executed the corrosion test under $3.5\%$ NaCl solution for 500, 1000 hours, the salt solution penetrated into the surface of the substrate through the pores of the coating layer. As a result, corrosion production formed on the surface of the substrate. The adhesiveness between coating layers is weakened by the polarization and corrosion itself. The AE event, count, and energy of corroded coating specimens decrease, compared to specimens without corrosion. The results are summarized as follows : 1. In the tensile tests, the time that it took to start and develop the cracks and exfoliations between the surface of the substrates and the plasma spray coatings were different according to the type of plasma sprayed material, which are Zn and Amdry625. These phenomena were obvious at the strain rate 1 to $5\%$, and few available data were found after that stage. 2. The specimens with Zn coating showed the characteristics of crack, according to the changes of the tensile strength applied on the substrates while those with Amdry625 showed exfoliation as a result of low adaptation to the tensile strength. 3. The anti-corrosion specimens showed that the adhesive properties between the substrate and the plasma spray coating were strong in the order of Zn, Amdry. It showed that Corroded specimens cracked or exfoliated easily, even with the small energy, because those had a comparatively weakened adhesive property, due to corrosion. 4. Zn specimen showed no corrosion phenomena on the surface of the substrates, because they had the function of sacrifice anode however, Amdry625 specimen showed the corrosion, because it did not have that function.