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Feasibility Study on the Vitrification of Concentrated Boric Acid Waste (붕산농축폐액 유리화 타당성 연구)

  • Cho, Hyun-Je;Kim, Deuk-Man;Park, Jong-Kil
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.2
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    • pp.143-150
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    • 2010
  • Vitrification technology has been gradually recognized as one of effective solidification methods for concentrated boric acid wastes generated in PWR. Vitrification for low- and intermediate-level radioactive wastes has a large volume reduction and good durability for the final products. A feasibility study for the vitrification of concentrated boric acid wastes has been performed with developing the pre-treatment methods of powdered wastes, glass compositions using glass formulation and demonstration test. The pre-treatment method is pelletizing the powder type for stable feeding within cold crucible melter. The glass compositions should be developed considering molten glass are related with wastes reduction. High contents of sodium and boron within borate wastes give influence to waste loading. A variety of factors obtained from the demonstration test are reviewed, which is wastes feeding rate, off-gas characteristics on stack and glass characteristics of final products such as durability for implementing the wastes disposal requirement. The aim of this paper is to present the feasibility of vitrification and review the solidification method for concentrated boric acid wastes and obtain the physicochemical characteristics of solidified glass.

Radiological Impact Assessment for the Domestic On-road Transportation of Radioactive Isotope Wastes (방사성동위원소 폐기물의 국내육상운반에 관한 방사선영향 평가)

  • Seo, Myunghwan;Hong, Sung-Wook;Park, Jin Beak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.279-287
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    • 2016
  • Korea Radioactive Waste Agency (KORAD) began to operate the low and intermediate level radioactive waste disposal facility in Gyeongju and to transport the radioactive waste containing radioactive isotopes from Daejeon to the disposal facility for the first time at 2015. For this radioactive waste transportation, in this study, radiological impact assessment is carried out for workers and public. The dose rate to workers and public during the transportation is estimated with consideration of the transportation scenarios and is compared with the Korean regulatory limit. The sensitivity analysis is carried out by considering both the variation of release ratios of the radioactive isotopes from the waste and the variation of the distances between the radioactive waste drum and worker during loading and unloading of radioactive waste. As for all the transportation scenarios, radiological impacts for workers and public have met the regulatory limits.

Development of Thin Film Electrode by Thermal CVD and Its Anode Characteristics for Lithium Battery (Thermal CVD법을 이용한 박막전극의 개발 및 리튬이차전지의 음극특성)

  • Lee, Young-Ho;Kim, Seong-Il;Doh, Chil-Hoon;Jin, Bong-Soo;Min, Bok-Ki;Kim, Hyun-Soo;Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.378-379
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    • 2006
  • The carbon thin film was developed by the CVD method using the carbon source of toluene with the stream of argon gas at $800{\sim}1100^{\circ}C$ for 1 hour. Developed carbon thin films have the material loading of 0.27 mg($800^{\circ}C$), 0.80 mg($900^{\circ}C$), 2.3 mg($1000^{\circ}C$), and 2.9 mg($1100^{\circ}C$) for the disk of 15 mm diameter on single side. The characteristics of carbon thin film as the anode of thin film battery were evaluated using Li|C coin cell. Li|C($1100^{\circ}C$) coin cell has the first specific discharge and charge capacity of 953 mAh/g and 374 mAh/g, respectively, resulting the first Ah efficiency of 39.3 %. Capacity retention of the 5th cycle was 93.2 % indicating good cycleability. The carbon thin film prepared by CVD shows good specific capacity and cycleability, but low Ah efficiency.

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Flexural Behaviour of Encased Composite Beam with Precast Hollow Core Slabs and Channels (속빈 PC 슬래브와 채널을 사용한 매입형 합성보의 휨 거동)

  • Heo, Byung Wook;Kwak, Myong Keun;Bae, Kyu Woong
    • Journal of Korean Society of Steel Construction
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    • v.20 no.4
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    • pp.493-504
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    • 2008
  • This paper deals with the experimental analysis of the flexural behaviour of encased composite beams with hollow core slabs and channels. The shear force between steel beams and hollow core slabs are transferred by channels. Three full-scale specimens were constructed and tested with different steel beam heights, which were compared with those of previous studies. Based on observation of the experiments, the encased composite beams exhibited full shear connection behaviour without any other shear connectors due to their inherent mechanical and chemical bond stress. Experimental results show a behaviour similar to steel-concrete composite beams with classical connectors: elastic and yield domains, great ductility, flexural failure mode (plastic hinge), low relative movement at steel-concrete interface and all specimens failed in a very ductile manner. Consequently, this study enables the validation of the proposed connection device under static loading and shows that it meets modern structural requirements.

Effects of Zr-hydride distribution of irradiated Zircaloy-2 cladding in RIA-simulating pellet-clad mechanical interaction testing

  • Magnusson, Per;Alvarez-Holston, Anna-Maria;Ammon, Katja;Ledergerber, Guido;Nilsson, Marcus;Schrire, David;Nissen, Klaus;Wright, Jonathan
    • Nuclear Engineering and Technology
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    • v.50 no.2
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    • pp.246-252
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    • 2018
  • A series of simulated reactivity-initiated accident (RIA) tests on irradiated fully recrystallized boiling water reactor Zircaloy-2 cladding has been performed by means of the expansion-due-to-compression (EDC) test method. The EDC method reproduces fuel pellet-clad mechanical interaction (PCMI) conditions for the cladding during RIA transients with respect to temperature and loading rates by out-of-pile mechanical testing. The tested materials had a large variation in burnup and hydrogen content (up to 907 wppm). The results of the EDC tests showed variation in the PCMI resistance of claddings with similar burnup and hydrogen content, making it difficult to clearly identify ductile-to-brittle transition temperatures. The EDC-tested samples of the present and previous work were investigated by light optical and scanning electron microscopy to study the influence of factors such as azimuthal variation of the Zr-hydrides and the presence of hydride rims and radially oriented hydrides. Two main characteristics were identified in samples with low ductility with respect to hydrogen content and test temperature: hydride rims and radial hydrides at the cladding outer surface. Crack propagation and failure modes were also studied, showing two general modes of crack propagation depending on distribution and amount of radially oriented hydrides. It was concluded that the PCMI resistance of irradiated cladding under normal conditions with homogenously distributed circumferential hydrides is high, with good margin to the RIA failure limits. To further improve safety, focus should be on conditions causing nonfavorable hydride distribution, such as hydride reorientation and formation of hydride blisters at the cladding outer surface.

Radiological Safety Assessment of Transporting Radioactive Wastes to the Gyeongju Disposal Facility in Korea

  • Jeong, Jongtae;Baik, Min Hoon;Kang, Mun Ja;Ahn, Hong-Joo;Hwang, Doo-Seong;Hong, Dae Seok;Jeong, Yong-Hwan;Kim, Kyungsu
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1368-1375
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    • 2016
  • A radiological safety assessment study was performed for the transportation of low level radioactive wastes which are temporarily stored in Korea Atomic Energy Research Institute (KAERI), Daejeon, Korea. We considered two kinds of wastes: (1) operation wastes generated from the routine operation of facilities; and (2) decommissioning wastes generated from the decommissioning of a research reactor in KAERI. The important part of the radiological safety assessment is related to the exposure dose assessment for the incidentfree (normal) transportation of wastes, i.e., the radiation exposure of transport personnel, radiation workers for loading and unloading of radioactive waste drums, and the general public. The effective doses were estimated based on the detailed information on the transportation plan and on the radiological characteristics of waste packages. We also estimated radiological risks and the effective doses for the general public resulting from accidents such as an impact and a fire caused by the impact during the transportation. According to the results, the effective doses for transport personnel, radiation workers, and the general public are far below the regulatory limits. Therefore, we can secure safety from the viewpoint of radiological safety for all situations during the transportation of radioactive wastes which have been stored temporarily in KAERI.

Study on the Fabrication of Ceramic Core using a Gel-casting Process in Aqueous medium(I) : Gelation Behavior of Polydispered Ceramic Slip (수용액 매체에서 젤-케스팅 공정을 이용한 세라믹 코어 제조에 관한 연구(I) : 다성분계 분산 세라믹 슬립의 젤화 거동)

  • Kim, Jae-Won;Kim, Du-Hyeon;Kim, In-Su;Yu, Yeong-Su;Kim, Jae-Cheol;Jo, Chang-Yong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.137-145
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    • 2001
  • A new process, gelcasting in aqueous medium, to fabricate complex-shaped ceramic core has investigated. The ceramic slurry, mixture of fused silica powder and additives such as zircon and cordierite, was electrosterically stabilizes. The slip was prepared by ball milling of polydispered ceramic suspension with monomer, dimer and dispersant. The rheological behavior of slip was evaluated by viscosity measurement. It was found that the high solid loading of polydispersed ceramic slip, which has low viscosity of 50vol%, is possible to obtained. The viscosity of the slip was significantly dependent upon the amount of polymer dispersant and the formulation of monomer and dimer. The green bodies were fabricated through casting and gelation at room temperature followed by drying at $25^{\circ}C$ for 48hrs under relative humidity of 80~85%. Crack-free green body was successfully fabricated through the above process.

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High Cyclic Fatigue Life and Fracture Behaviors of Shot-Peened Bearing Steel (쇼트피닝 처리를 한 베어링강의 고사이클 피로수명 및 파괴거동)

  • Yoon, Sang-Jae;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.9
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    • pp.1119-1129
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    • 2011
  • Shot-peening effects on the fatigue behavior of bearing steel were investigated under the high cyclic loading. Hourglass shape specimens were made of bearing steel(JIS-SUJ2) for rotary bending fatigue tests. Two kinds of treatments were performed : a heat treatment and a shot-peened surface treatment after the heat treatment. The fracture surfaces of specimens were classified into two types of fracture mode : the surface fracture mode induced by a surface defect and the internal fracture mode induced by a nonmetallic inclusion. Inclusion depth and shape affected considerably the fatigue life. Shot-peening treatment improved much the fatigue life of the bearing steel under low and high levels of cyclic loads. Probabilistic-stress-life (P-S-N) curves were suggested for the reliable fatigue life estimation of the improved bearing steel.

Clinical Findings and Gene Analysis of BH4 Responsive PKU Patients in Korea (BH4 responsive PKU 환자들의 임상적 특성과 유전자분석)

  • Rhee, Minhee;Kim, Jiwon;Lee, Jeongho;Lee, Dong Hwan
    • Journal of The Korean Society of Inherited Metabolic disease
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    • v.13 no.2
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    • pp.104-110
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    • 2013
  • Purpose: Phenylketonuria (PKU) is the first inherited metabolic disease of which treatment is known. We performed this study to find out clinical symptoms and prognosis of tetrahydrobiopterin (BH4) responsive PKU patients and genetic relation. Methods: Clinical, biochemical, genetic analysis were done retrospectively in 23 patients diagnosed BH4 responsive PKU in Soonchunhyang University Hospital from March 2000 to September 2012. Results: Patients were classified to mild hyperphenylalaninemia and mild phenylketonuria with initial plasma phenylalanine level below 20 mg/dL. After BH4 loading, blood phenylalanine decrease level ranged between 37% and 99%. Initial treatment with low phenylalanine formula or BH4 was started before 2 month after birth except 2 patients. And one of them resulted in developmental delay in language and social activity. The others showed satisfactory progress without developmental delay. In genetic analysis, of 46 allele, R241C allele mutation was identified most commonly (41%). R241C/A259T, R241C/R243Q, R241C/V388M, R241C/T278I was detected in 5 (21.7%), 3 (13%), 2 (8%), 2 (8%) patients, respectively. Conclusion: R241C mutation was detected most frequently in this study group and R243Q mutation which is known to be prevalent in Korean PKU patients was found in 4 patients (8.6%). Early diagnosis and treatment is important in PKU patients.

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An Improvement in Loading Speed Using RAM-based Java Card Installer (RAM기반 자바카드 인스톨러를 이용한 로딩속도 개선)

  • Jin, Min-Sik;Choi, Won-Ho;Lee, Dong-Wook;Kim, Han-Na;Jung, Min-Soo;Park, Kyoo-Seok
    • Journal of Korea Multimedia Society
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    • v.10 no.5
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    • pp.604-611
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    • 2007
  • Java Card has gained genera1 acceptance with standard for smart card and (U)SIM technology, and it is in distinction from native card by its post-issuance of an application and independence from hardware platforms. However, a main weak point of Java Card is its low execution speed caused by the hardware limitation and Java programming language itself. In this paper, we propose a new Java Card Installer to improve the download speed during the post-issuance of an application by resolving symbolic references to physical references in HAM. Our Resolution_In_RAM is based on the improved new RAM writing is 100,000 times faster than EEPROM writing and PageBuffer that is operated as block mode, rather than cell mode is used to write to EEPROM. Consequently, the total number of EEPROM writing are reduced 37%, and the times of downloading are reduced over 30% by using the Resolution_In_RAM-based Java Card Installer.

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