• Title/Summary/Keyword: low dimensional materials

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Enhanced Environmental Stability of Graphene Field-Effect Transistors through Interface Control (계면 제어를 통한 그래핀 기반 전계효과 트랜지스터의 환경 안정성 향상)

  • Seong, Jun Ho;Lee, Dong Hwa;Lee, Eunho
    • Journal of Adhesion and Interface
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    • v.23 no.3
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    • pp.75-79
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    • 2022
  • Graphene is a two-dimensional carbon allotrope composed of honeycomb sp2 hybrid orbital bonds. It shows excellent electrical and mechanical properties and has been spotlighted as a core material for next-generation electronic devices. However, it exhibits low environmental stability due to the easy penetration or adsorption of external impurities from the formation of an unstable interface between the materials in the electronic devices. Therefore, this work aims to improve and investigate the low environmental stability of graphene-based field-effect transistors through direct growth using solid hydrocarbons as a precursor of graphene. Graphene synthesized from direct growth shows high electrical stability through reduction of change in charge mobility and Dirac voltage. Through this, a new approach to utilize graphene as a core material for next-generation electronic devices is presented.

Experimental Investigation on the Hydraulic Performance of the Regenerative Pump According to the Blade Angle (재생 펌프의 날개 각도에 따른 성능 변화에 관한 실험적 연구)

  • Yoo, Il Su;Choi, Won Chul;Park, Mu Ryong;Lee, Gong Hoon
    • The KSFM Journal of Fluid Machinery
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    • v.16 no.5
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    • pp.5-10
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    • 2013
  • The regenerative pump is a kind of turbomachine which is capable of developing high pressure rise at relatively lower flow rates compared to the centrifugal and axial pumps. Although the efficiency of regenerative pumps is much lower than other turbomachines, still they have been widely used in many industrial applications for working at low specific speeds. There are some theoretical models to analysis the pump performance, however, the effect of the blade angle on the pump performance has not been covered in any model to date. In the present study, experimental study on the regenerative pump performance according to the impeller blade angle and its shape has been carried out. The straight radial blades with forward, backward and chevron blades which have inclined angles of $15^{\circ}$, $30^{\circ}$ and $45^{\circ}$ were tested. The pump performance characteristics as the pressure head, efficiency were obtained depending on the flow rate for every impeller, and their results, expressed in appropriate non-dimensional coefficients, were compared and analysed in detail. From the experimental results, it was found that the pressure head and the efficiency depend strongly on the blade angles as well as the blade type. These experimental data has made it possible to better understand the effects of the blade angle on the pump performance, and widen the applicability of the current performance analysis and design models with including the effect of blade angles.

Optical Probing of Electronic Interaction between Graphene and Hexagonal Boron Nitride (hBN)

  • Ahn, Gwanghyun;Kim, Hye Ri;Ko, Taeg Yeoung;Choi, Kyoungjun;Watanabe, Kenji;Taniguchi, Takashi;Hong, Byung Hee;Ryu, Sunmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.213-213
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    • 2013
  • Even weak van der Waals (vdW) adhesion between two-dimensional solids may perturbtheir various materials properties owing to their low dimensionality. Although the electronic structure of graphene has been predicted to be modified by the vdW interaction with other materials, its optical characterization has not been successful. In this report, we demonstrate that Raman spectroscopy can be utilized to detect a few % decrease in the Fermi velocity ($v_F$) of graphene caused by the vdW interaction with underlying hexagonal boron nitride (hBN). Our study also establishes Raman spectroscopic analysis which enables separation of the effects by the vdW interaction from those by mechanical strain or extra charge carriers. The analysis reveals that spectral features of graphene on hBN are mainly affected by change in vF and mechanical strain, but not by charge doping unlike graphene supported on $SiO_2$ substrates. Graphene on hBN was also found to be less susceptible to thermally induced hole doping.

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Fabrication and Characterization of 3D Woven Textile Reinforced Thermoplastic Composites (3차원 직조형 열가소성수지 복합재료 제조 및 특성화)

  • 홍순곤;변준형;이상관
    • Composites Research
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    • v.16 no.2
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    • pp.33-40
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    • 2003
  • In order to overcome one of the most pronounced shortcomings of conventional laminated composites, such as the low damage tolerance due to delamination, the thermoplastic materials and 3D (three-dimensional) preforms have been utilized in the manufacture of composite materials. From the newly developed process termed as the co-braiding, hybrid yarns of the thermoplastic fibers (PEEK) and reinforcing fibers (carbon) have been fabricated. In order to further enhance the delamination suppression, through thickness fibers have been introduced by way of 3D weaving technique in the fabrication of textile preforms. The preforms have been thermoformed to make composite materials. Complete impregnation of the PEEK into the carbon fiber bundles has been confirmed. For the comparison of mechanical performance of 3D woven composites, quasi-isotropic laminates using APC-2/AS4 tapes have been fabricated. Tensile and compressive properties of both the composites have been determined. Furthermore. the open hole, impact and CAI(Compression After Impact) tests were also carried out to assess the applicability of 3D woven textile reinforced thermoplastic composites in aerospace structures.

Gravity, Magnetic and VLF explorations in the ubong industrial waste landfill, Pohang (포항 유봉산업 폐기물 매립지에서의 중력, 자력, VLF 탐사)

  • 권병두
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.177-187
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    • 1999
  • Gravity, magnetic and VLF surveys were conducted to investigat the structural stability and hazards associated with the Ubong landfill in Pohang City, which has been built to dump industrial wastes. In 1994, the collapse of a bank happened in the 6th landfill site due to sudden heavy rain, and a large quantity of waste materials flowed out to the nearby landfill sites, factories and roads. We used $10{\times}10m$ resolution DEM data for gravity reductions. The maximum variation of the terrain effect in the survey area is about 0.5 mgal and the terrain effect is large in the vicinity of bank boundary. The Bouguer gravity anomaly map shows the effect due to the variatino of thickness and type of waste materials. The small negative gravity anomaly increases from the 9th site to the 6th site. The small negative gravity anomaly of the 9th site reflects the relatively shallow dumping depth of average 14.5 m in this site and increased density of waste materials by the repeated stabilization process of soil overlaying. The 6th site is located at the center of the former valley and rainfall and groundwater are expected to flow from south-east to north-west. Therefore, considering the previous accident of mixing waste and bank materials at the north-west boundary of the landfill, there may be some environmental problems of leakage of contaminated water and bank stability. The complex inversion technique using Simulated annealing and Marquardt-Levenberg methods was applied to calculate three-dimensional density distribution from gravity data. In the case of 6th site, it is apparent that the landfill had been dumped in four sectors. However, most part of the 9th site and showed that high magnetic industrial wastes were concentrated in the 6th site. The result of magnetic survey showing low magnetic anomalies along the boundaries of two sites is similar to that of gravity data. The VLF data also reveals four divided sectors in the 6th site, and overall anomaly trend indicates the directio of former valley.

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The Solidification Microstructure of X%C-5%Cr-5%V-5%Mo-5%W-5%Co Multi-Component White Cast Iron (X%C-5%Cr-5%V -5%Mo-5%W-5%Co 다합금계백주철의 응고조직에 관한 연구)

  • Yu, Sung-Kon;Yasuhiro Matsubara
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.472-476
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    • 2001
  • Type and three-dimensional morphology of carbides precipitated in the X(X= 1.70, 1.92, 2.21, 2.50, 2.86)%C-5%Cr-5%V-5%Mo-5%W-5%Co multi-component white cast iron were investigated using an optical microscope and SEM. The types of carbides precipitated were MC, M$_2$C and M$_{7}$C$_{3}$. Morphology of the MC carbide took three forms, that it petal-like, nodular and coral-like. MC carbide seemed to change its morphology from petal-like through nodular, and finally to coral-like with an increase in carbon content. M7C carbide was classified into lamellar and plate-like type. The lamellar M$_2$C arbide precipitated in the iron with low molybdenum and tungsten contents, and higher contents of both elements in the iron were needed to form the plate-like M$_2$C carbide. The morphology of M$_{7}$C$_{3}$ was rod-like similar to that observed in high chromium white cast iron. However, cobalt does not affect the type and morphology of precipitated carbides.des.

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Active Materials for Energy Conversion and Storage Applications of ALD

  • Sin, Hyeon-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.75.2-75.2
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    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

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Growth Behavior of InGaN/GaN Quantum Dots Structure Via Metal-organic Chemical Vapor Deposition (유기금속기상증착법에 의한 InGaN/GaN 양자점 구조의 성장거동)

  • Jung, Woo-Gwang;Jang, Jae-Min;Choi, Seung-Kyu;Kim, Jin-Yeol
    • Korean Journal of Materials Research
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    • v.18 no.10
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    • pp.535-541
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    • 2008
  • Growth behavior of InGaN/GaN self-assembled quantum dots (QDs) was investigated with respect to different growth parameters in low pressure metalorganic chemical vapor deposition. Locally formed examples of three dimensional InGaN islands were confirmed from the surface observation image with increasing indium source ratio and growth time. The InGaN/GaN QDs were formed in Stranski-Krastanow (SK) growth mode by the continuous supply of metalorganic (MO) sources, whereas they were formed in the Volmer-Weber (V-W) growth mode by the periodic interruption of the MO sources. High density InGaN QDs with $1{\sim}2nm$ height and $40{\sim}50nm$ diameter were formed by the S-K growth mode. Dome shape InGaN dots with $200{\sim}400nm$ diameter were formed by the V-W growth mode. InN content in InGaN QDs was estimated to be reduced with the increase of growth temperature. A strong peak between 420-460 nm (2.96-2.70 eV) was observed for the InGaN QDs grown by S-K growth mode in photoluminescence spectrum together with the GaN buffer layer peak at 362.2 nm (3.41 eV).

Evaluation of 3D concrete printing performance from a rheological perspective

  • Lee, Keon-Woo;Lee, Ho-Jae;Choi, Myoung-Sung
    • Advances in concrete construction
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    • v.8 no.2
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    • pp.155-163
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    • 2019
  • The objective of this study was to derive a cementitious material for three-dimensional (3D) concrete printing that fulfills key performance functions, extrudability, buildability and bondability for 3D concrete printing. For this purpose, the rheological properties shown by different compositions of cement paste, the most fundamental component of concrete, were assessed, and the correlation between the rheological properties and key performance functions was analyzed. The results of the experiments indicated that the overall properties of a binder have a greater influence on the yield stress than the plastic viscosity. When the performance of a cementitious material for 3D printing was considered in relation with the properties of a binder, a mixture with FA or SF was thought to be more appropriate; however, a mixture containing GGBS was found to be inappropriate as it failed to meet the required function especially, buildability and extrudability. For a simple quantitative evaluation, the correlation between the rheological parameters of cementitious materials and simplified flow performance test results-time taken to reach T-150 and the number of hits required to reach T-150-in consideration of the flow of cementitious materials was compared. The result of the analysis showed a high reliability for the correlation between the rheological parameters and the time taken to reach T-150, but a low reliability for the number of hits needed for the fluid to reach T-150. In conclusion, among several performance functions, extrudability and buildability were mainly assessed based on the results obtained from various formulations from a rheological perspective, and the suitable formulations of composite materials for 3D printing was derived.

Bayesian Survival Analysis of High-Dimensional Microarray Data for Mantle Cell Lymphoma Patients

  • Moslemi, Azam;Mahjub, Hossein;Saidijam, Massoud;Poorolajal, Jalal;Soltanian, Ali Reza
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.1
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    • pp.95-100
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    • 2016
  • Background: Survival time of lymphoma patients can be estimated with the help of microarray technology. In this study, with the use of iterative Bayesian Model Averaging (BMA) method, survival time of Mantle Cell Lymphoma patients (MCL) was estimated and in reference to the findings, patients were divided into two high-risk and low-risk groups. Materials and Methods: In this study, gene expression data of MCL patients were used in order to select a subset of genes for survival analysis with microarray data, using the iterative BMA method. To evaluate the performance of the method, patients were divided into high-risk and low-risk based on their scores. Performance prediction was investigated using the log-rank test. The bioconductor package "iterativeBMAsurv" was applied with R statistical software for classification and survival analysis. Results: In this study, 25 genes associated with survival for MCL patients were identified across 132 selected models. The maximum likelihood estimate coefficients of the selected genes and the posterior probabilities of the selected models were obtained from training data. Using this method, patients could be separated into high-risk and low-risk groups with high significance (p<0.001). Conclusions: The iterative BMA algorithm has high precision and ability for survival analysis. This method is capable of identifying a few predictive variables associated with survival, among many variables in a set of microarray data. Therefore, it can be used as a low-cost diagnostic tool in clinical research.