• Korean Journal of Fisheries and Aquatic Sciences
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• 제39권2호
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• pp.106-117
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• 2006

We measured the concentrations of organic matter and metallic elements (Al, Fe, Cr, Mn, Ni, Cu, Zn, As, Cd, Pb and Hg) in the surface sediments of Masan Harbor (in the southern sea, Korea) to evaluate the geochemical characters of sediment and the pollutions by organic matter and metallic elements. The mean grain size of the surface sediments in the study area ranged from $5.6{\phi}$ to $7.8{\phi}$, indicating silt sediment. The water content of the surface sediments exceeded 60% except at some stations. The contents of ignition loss (IL), total organic carbon (TOC) and total nitrogen (TN) ranged from 7.2-14.3%, 1.2-3.2%, and 0.10-0.28%, respectively. Based on the C/N ratios, the organic matter in the surface sediments of Masan Harbor may originate from terrigenous sources including fluvial inputs (mainly sewage in urban areas). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) ranged from $11.3-29.9\;mgO_2/g\;dry$ and 0.20-4.47 mgS/g dry, respectively, and low concentrations were observed near a shipping route. In addition, the concentrations of metallic elements showed large spatial variations in Masan Harbor and the distributions of metallic elements were also comparable to those of organic matter. This implies that the distributions of organic matter and metallic elements in the surface sediments of Masan Harbor are mainly controlled by biogenic matter and artificial action (mainly dredging). In addition, we calculated the enrichment facto. (EF) and geoaccumulation index (Igeo) in order to evaluate pollution by metallic elements. The enrichment of metallic elements relative to Al was three to eighteen times higher at the study sites, compared to levels in the Earth's crust except for Fe, Ni and Mn. In addition, the Igeo class indicated that the surface sediments in the study area were moderately to strongly polluted in terms of metallic elements.

• Korean Journal of Fisheries and Aquatic Sciences
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• 제43권6호
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• pp.723-734
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• 2010

To understand temporal variations in geochemical characteristics of intertidal surface sediments around Byeonsan Peninsula (in the middle of the western coast, Korea) after the construction of Saemanguem dyke, the sedimentation rate and various geochemical parameters, including mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), and acid volatile sulfide (AVS), were measured along four transects (A.D lines) at monthly intervals from February 2008 to March 2009. The average monthly sedimentation rate ranged from -5.3 to 3.8 mm/month (mean $-0.8{\pm}2.7\;mm$/month), which showed an erosion-dominated environment in the lower part of the intertidal zone. In addition, surface sediments were eroded in summer and autumn, but were deposited in spring and winter. The Mz of surface sediments ranged from -0.8 to $3.4{\varnothing}$ (mean $2.8{\pm}0.5{\varnothing}$), indicating that the surface sediments consist of coarser sediments (sand and slightly gravelly sand). The Mz of surface sediments did not show large monthly and/or seasonal variations, although the sedimentation rates of surface sediment showed large seasonal variation. This may be due to lateral shifting and effective dispersion of surface sediments by wind, tide, and longshore current. The concentrations of IL and COD in the surface sediments ranged from 0.2 to 2.9% (mean $1.4{\pm}0.4%$) and from 0.2 to $18.5\;mgO_2$/g-dry (mean $3.9{\pm}3.4\;mgO_2$/g-dry), respectively, which were slightly higher in spring than in the other seasons. This may be related to spring blooms of phytoplankton in seawater and/or benthic microalgae in surface sediments. On the other hand, no AVS concentrations were detected in surface sediments at any of the sampling stations during the study period.

• Journal of Environmental Science International
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• 제22권7호
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• pp.787-799
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• 2013

The aim of this study was to investigate the accumulation of metallic elements and the control effect of marine pollution caused by ocean dumping in the sediments at a waste disposal area in the Yellow Sea. In July 2009, concentrations of organic matter and metallic elements (Al, Fe, As, Cd, Cr, Co, Hg, Ni, Mn, Pb, and Zn) were measured in surface sediments at the site. The ignition loss (IL) in the surface sediments showed a mean value of 15.4%, about 1.5 times higher than the mean value of the sediments in the coastal areas of Korea. The chemical oxygen demand (COD) at some disposal sites exceeded 20 mg $O_2/g{\cdot}dry$, which signifies the initial concentration of marine sediment pollutants in Japan. The disposal sites contain higher concentrations of Cr, Cu and Zn than the sediments of bays and estuaries that might be contaminated. The magnitude of both metal enrichment factors (EF) and adverse biological effects suggest that pollution with Cr and Ni occurred due to the dumping of waste in the study area. In addition, the geoaccumulation index (Igeo) showed that the surface sediments were moderately contaminated. By the mid-2000s, when the amount of waste dumped at this site was the highest, the concentration of metallic elements was higher than ever recorded. On the other hand, in 2008-09, the need for environmental management was relatively low compare with the peak. As a result, the quality of marine sediment has been enhanced, considering the effect of waste reduction and natural dilution in the disposal area.

• Journal of the Korea Concrete Institute
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• 제25권2호
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• pp.209-215
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• 2013

This study is aimed to identify the method to use the CaO-$Al_2O_3$ system of rapidly cooled steel making slag (RCSS) as the environment-friendly inorganic accelerating agent by analyzing its physical and chemical properties. The fraction of rapidly cooled steel making slag is distinguished from its fibrous, and the contents of CaO and $Fe_2O_3$ are inversely proportional across different fractions. In addition, as the content of CaO decreased and the content of $Fe_2O_3$ increased, the loss ignition tended to become negative (-) and the density increased. The pore distribution by mercury intrusion porosimetry is very low as compared to the slowly cooled steel-making slag, which indicates that the internal defect and the microspore rate are remarkably lowered by the rapid cooling. To analyze the major minerals the rapidly cooled steel-making slag, XRD, f-CaO quantification and SEM-EDAX analysis have been performed. The results shows that f-CaO does not exist, and the components are mainly consisted of $C_{12}A_7$ and reactive ${\beta}-C_2S$.

• Journal of Navigation and Port Research
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• 제41권4호
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• pp.195-206
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• 2017

In situ capping technology for marine sediment pollution control has never been applied in South Korea. In this study a pilot project for the capping was carried out in Busan N Harbor. Pipeline and clamshell capping technologies were implemented for the pollution control. Changes of capping shapes, sediment contamination, and the time and costs required for the two constructions were compared. Both the pipeline and clamshell technologies were found to satisfy the target thickness of 50 cm on average. However, the pipeline method did not operate sensitively in terms of change of the sea floor topography, resulting in an uneven shape and a thickness. Organic carbon and ignition loss quite decreased after the pipeline or the clamshell capping while pH showed no significant change. Organic and residual fraction of Cd, Ni, and Zn in the sediments appeared to decrease after all cappings. The pipeline method took a construction time four times as much as the clamshell method. The clamshell method was demonstrated to reduce the construction cost by about 40% compared with the pipeline method. However, a monitoring for all the parameters needs to be conducted at least two years in order to better evaluate an efficiency of the pollution control by these capping constructions.

• Resources Recycling
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• 제8권4호
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• pp.11-19
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• 1999

Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

• Journal of Ecology and Environment
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• 제30권2호
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• pp.151-159
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• 2007

We studied the optimal ranges of water and soil characteristics for wetland plants, particularly Scirpus tabernaemontani (softstem bulrush) and Typha latifolia (broadleaf cattail), which are dominant species with potential for restoration of Korean wetlands. We observed vegetation in S. tabernaemontani and T. latifolia communities from the mid to late June, 2005, and measured characteristics of water environments such as water depth (WD), temperature (WT), conductivity (WC), and concentration of several ions $(NO_3{^-}-N,\;Ca^{2+},\;Na^+,\;Mg^{2+},\;and\;K^+)$, and characteristics of soil environments such as soil texture, organic matter (loss on ignition, LOI), conductivity, and pH. The S. tabernaemontani community was accompanied by Zizania latifolia (Manchurian wildrice), Persicaria thunbergii (Korean persicary), Actinostemma lobatum (lobed actinostemma), and Beckmannia syzigachne (American slough grass), while the T. latifolia community was accompanied by P. thunbergii, T. angustifolia (narrowleaf cattail), and Glycine soja (wild soybean). We defined the optimal range for distribution (ORD) as the range that each plant was crowded. The optimal range of water characteristics for the S. tabernaemontani community was a $WD\;10{\sim}50cm,\;WT\;24.0{\sim}32.0^{\circ}C,\;WC\;100{\sim}500{\mu}S/cm,\;{NO_3}{^-}-N\;0{\sim}60ppb,\;K^+\;0.00{\sim}1.50ppm,\;Ca^{2+}\;7.50{\sim}17.50ppm,\; Na^+\;2.50{\sim}12.50ppm,\;and\;Mg^{2+}\;3.00{\sim}7.00ppm$. In addition, the optimal range of soil characteristics for the S. tabernaemontani community was a soil texture of loam, silty loam, and loamy sand, $LOI\;8.0{\sim}16.0%,\;pH\;5.25{\sim}6.25$, and conductivity $10{\sim}70{\mu}S/cm$. The optimal range of water characteristics for the T. latifolia community was a $WD\;10{\sim}30cm,\;WT\;22.5{\sim}27.5^{\circ}C,\;WC\;100{\sim}400{\mu}S/cm,\;{NO_3}{^-}-N\;0{\sim}60ppb,\;K^+\;0.00{\sim}1.50ppm,\;Ca^{2+}\;0.00{\sim}17.50ppm,\;Na^+\;0.00{\sim}12.50ppm,\;and\;Mg^{2+}\;0.00{\sim}5.00ppm$, and the optimal range of soil characteristics for the T. fatifolia community was a soil texture of loam, sandy loam, and silty loam, LOI $3.0{\sim}9.0%,\;pH\;5.25{\sim}7.25$, and conductivity $0{\sim}70{\mu}S/cm$.

• Korean Journal of Soil Science and Fertilizer
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• 제33권3호
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• pp.175-181
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• 2000

This study was carried out to investigate the change of soil physical properties in long-term fertilized paddy soils with a Fine silty family of Typic Halpaqueps (Pyeongtaeg series). Treatments fertilized consisted of no fertilizer, compost, NPK, NPK+compost for thirty one years and of NPK+silicate for seventeen years. Water stable aggregate and degree of aggregate stability, which were higher in surface-soil than sub-soil, were high in order of NPK + compost > NPK + silicate > compost > NPK > no fertilizer plot. The ratio of aggregate larger than 0.5mm was high at compost and silicate plots but that smaller than 0.5mm was high at no fertilizer and NPK plots. And this aggregate stability showed negative correlation with soil hardness and bulk density ; positive correlation with sedimentation volume of soils in water. Sedimentation volume of soils in water was a little higher in surface-soil than sub-soil and in wet soil than dry soil, respectively. Pore space ratio and water retention capacity of soils were the most increased by the application of compost and not affected by silicate as in cases of liquid limit and plastic limit. Ignition loss of soils was high in order of NPK + compost > compost > NPK + silicate > NPK > no fertilizer plot. And field shattering ratio of soil mass smaller than 25.4mm was relatively high in NPK + compost, compost, and silicate plots.

• Journal of the Korean Wood Science and Technology
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• 제30권2호
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• pp.172-179
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• 2002

In this study, two materials treated with a flame retardant were examined for their fire resistance. The first, MDF (medium density fiberboard) was overlaid by an oak sliced veneer, which was either treated by soaking in a 6wt.% solution of flame retardant chemicals (pentabromine-chlorinated paraffin) or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. The second material, Pinus koraiensis penal was either treated by a spray treatment using a flame retardant solution or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. Pentabromine-chorinated paraffin chemicals were added (6 part of urethane resin) as the flame retardant chemicals in the polyurethane coatings. In the fire resistance test, the th𝜃(℃·min) decreased with the flame retardant treatment or/and the flame retardant coatings, compared to the untreated sample Weight loss (%) decreased with the flame retardant treatment or/and the flame retardant coatings. The ignition time (sec.) increased and the residual flame time (sec.) decreased with the flame retardant treatment or/and flame retardant coatings. Therefore, the flame retardant treatment or/and flame retardant polyurethane coatings have excellent incombustibility.

• Journal of Conservation Science
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• 제32권4호
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• pp.471-490
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• 2016

This study investigated provenance of raw materials and making technique of lime-based materials used in the tomb barriers of the Yesan Mokri tombs from Joseon dynasty on the basis of analysis to material characteristics and physical properties. In the barrier materials, dry density and porosity are the highest value ($1.82g/cm^3$) and the lowest value (25.20%) in the south wall of No. 1 tomb, respectively. Dry density and porosity are inversely proportional in all barrier materials, but unconfined compressive strength, which is the highest value of $182.36kg/cm^2$ in the No. 2 tomb, does not show an interrelation with porosity and density. Mineral components in the lime-soil mixtures of the tomb barrier are mainly quartz, feldspar, mica and calcite about 200 to $600{\mu}m$ size with yellowish brown matrix. Hydrotalcite and portlandite are detected in the lime mixture, and kaolinite in the soils. The lime materials of the tomb barrier occurred in large quantities weight loss and variable endothermic peaks caused by decarbonization reaction of $CaCO_3$ in the range from 600 to $800^{\circ}C$ in thermal analysis. Making temperature of lime for the tomb barrier is presumed approximately about $800^{\circ}C$ based on the occurrences, compositions and thermal analysis. The tomb barriers are revealed to very wide composition ranges of major elements and loss-on-ignition (22.5 to 33.6 wt.%) owing to mixture of the three materials (lime, sand and clay). It is interpreted that low quality construction technique was applied as the limes are very heterogeneous mixture with aggregates, and curing of the lime was poorly processed in the tomb barriers. Possible limestone sources are distributed in many areas around the Mokri site where limestone conformation and quarries for commercial production are found within Yesan and Hongseong areas. Therefore, we estimated that raw materials were possibly supplied from the local mines near the Mokri site.