• The Korean Journal of Pesticide Science
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• v.2 no.1
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• pp.70-78
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• 1998

This study was conducted to investigate the adsorption-desorption characteristics of herbicide paraquat on clay minerals, humic materials, and soils under the laboratory conditions. Adsorption time of paraquat on clay minerals was faster than organic materials and soils. Adsorption amount on montmorillonite, 2:1 expanding-lattice clay mineral, was largest among the adsorbents tested. The adsorption capacity of paraquat was approximately 21 % of cation exchange capacity in soils, 45.1 % in kaolinite, and 80.6% in montmorillonite. Humic materials, humic acid and fulvic acid isolated from soil II, adsorbed larger amount of paraquat than kaolinite and soils. Distribution of tightly bound type of paraquat was larger in clay mineral and soils but loosely bound type was larger in humic acid and fulvic acid. In oxidized soil, the adsorption amount of paraquat was decreased to 85.1-95.5% of original soils. Distribution of unbound and loosely bound type of paraquat was decreased in oxidized soil but tightly bound type was increased. The competition cations decreased paraquat adsorption on humic materials and soils but not affected on montmorillonite. No difference was observed as the kinds of cations. In cation-saturated adsorbents, the adsorption amount was decreased largely in humic materials and soils but decreased a little in montmorillonite. The tightly bound type of paraquat in all adsorbents was not desorbed by pH variation, sonication, and cation application but loosely bound type was desorbed. However, the desorption amount was different as a kinds of adsorbents and desorption methods.

• Journal of the Mineralogical Society of Korea
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• v.10 no.2
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• pp.82-96
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• 1997

Buserties are known to have layer structures with variable C dimension which depended on the nature interlayer catious and contents of water molecular between edge-sharing [MnO6] octabedral layers. Na-, Ca-, Mg-, and Zn-buserties were synthesized in the laboratory and studied for to know the structural states of water molecules and the role of catious in the buserite structures. With lowering the relative humidity(RH), Ca-buserite begins to dehydrate at 27% RH and proceeds further very slowly. Mg- and Zn- buserite also slow dehydration above 2% RH. With gradual ineveasing temperature Ca- and Zn-buserite show abrupt shifting of 10$\AA$ peak (10$\AA$-phare) toward 7$\AA$ peak. All of 7$\AA$-phare are further dehydrated to 5$\AA$-phare by further increasing temperature. It suggests that interlayer catious play a crucial role in the dehydration behavious of buserites. Simulation of one-dimensional X-ray diffraction patterns of buserties show that buserites have three layers of water molecules of different types: the very loosely bound and tightly bend waters, instead of two layers that was regarded by previous authers. The very loosely bound water is sited I open space of the interlayer, the loosely bound water is bound on the tightly bound water by hydrogen bond, and the tightly bond water in coodinately bound on the interlayer catious.

• Journal of the korean academy of Pediatric Dentistry
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• v.24 no.1
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• pp.148-172
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• 1997

Sixty human premolar teeth were used for this in vitro study. After each tooth was sectioned mesiodistally, one half was used for the experimental group and the other half for the control. Three groups were made for each fluoride applying method and twenthy teeth were assigned to each group. Ten teeth were used for evaluating total fluoride amount and the other ten were used for firmly-bound fluoride. Fluorshield was used for fluoride-releasing sealant and 1.23% APF, 0.05% NaF were used for topical application fluorides. Each tooth was cleaned with a tooth brush using nonfluoride containing pumice before the experiment. In the sealant group, fluoroshield was applied to the enamel surface without etching procedure and stored in $37^{\circ}C$ saline for 30 days. After 30 days, sealant was removed with explorer without scratching the enamel surface and washed with distilled water and dried. In the APF group, each tooth was immersed in 1.23% APF for 30 min then washed and dried in the same manner. In the NaF group, each tooth was immersed in 0.05% NaF for 24 hours then washed and dried as described above. After each fluoride regimen was applied, ten teeth were randomly selected from each group and immersed in 1M KOH solution for 24 hours to remove loosely-bound fluoride possibly deposited by the three different fluorides applied. In each group, total fluoride amount deposited and the amount of enamel removed by acid biopsy were calculated. After loosely-bound fluoride was removed, firmly-bound fluoride deposited and the amount of enamel removed by acid biopsy were also calculated. Total fluoride amount deposition was significantly increased in the APF and NaF groups, but not in the sealant group. Amount of enamel removed by acid-biopsy was also significantly diminished in the APF and NaF groups, but not in the sealant groups. After loosely-bound fluoride was removed from each groups, no statistical difference was found in the amount of firmly-bound fluoride in any groups. Also no effect of firmly-bound fluoride on enamel dissolution was shown in any groups after loosely-bound fluoride was removed from each group. In conclusion, topical application method of APF or NaF is more effective than fluoride-releasing sealant application to make $CaF_2$ coating on enamel surface and $CaF_2$ coating is the main source for anticariogenic effect of fluoride. However, longterm anticariogenic effect of fluoride-releasing sealant should be further evaluated.

• Korean Journal of Environmental Agriculture
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• v.16 no.3
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• pp.239-244
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• 1997

To develope more effective extraction methods for paraquat in soil, some modification methods were accomplished in two different types of soil. For extraction of tightly bound-paraquat, conc. HCl 70ml were added with different shaking times, and then $H_2SO_4$ reflux were performed for an hour. In this case, 60 minutes shaking were optimum and recovery were increased more $1.09{\sim}1.50$ folds(84.0% in high clay contents soil, but 96.7% in low clay contents soil) and the long-time consuming step, filtration were easily done, with decreasing filtration time were shorter 4.6 folds(ca. $11{\sim}14min.$). than general paraquat analytical method(ca. $55{\sim}65min.$). And only $H_2O_2$ digestion with different volume and refluxing time resulted in recovery increasing. Nevertheless, considering analyst's safety, 30ml of $H_2O_2$ addition and 30 minutes reflux were regarded as optimum condition. Although, Kjeldahl digestion with $H_2O_2$ showed relatively high recovery, it is not significant statistically. For extraction of loosely bound-paraquat, 0.01, 0.1, 1.0, 10.0M of $NH_4Cl$ and of $CaCl_2$ compared with $1.5{\sim}24hr$ of different shaking time. There were no loosely bound residues of paraquat.

• Macromolecular Research
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• v.9 no.1
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• pp.45-50
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• 2001

Formation of bound rubber depends on the filler-polymer interactions including physical adsorption, chemisorption, and mechanical interaction. Bound rubbers consist of tightly and loosely bound ones. Styrene-butadiene rubber (SBR) is composed of styrene, 1,2-, cis-1,4-, and trans-1,4-units. Filler-polymer interactions of each components of SBR with fillers, carbon black and silica, were studied by analysis of microstructure of the bound rubber. Filler-polymer interaction of the 1,2-unit with the fillers was found to be stronger than those of the other components and this phenomenon was shown more clearly in the tightly bound rubber.

• Korean Journal of Ecology and Environment
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• v.48 no.3
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• pp.168-175
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• 2015

This study was conducted in autumn to determine phosphorus (P) fraction in sediments of Daechung Lake, to elucidate controlling factors for sedimentary P, and to compare with the other areas. For this study, sediment samples were collected at 6 sites only once on November 2014 using ponar grab and analyzed for solid-phase P (Loosely adsorbed, Fe-bound, Al-bound, detrital apatite, and refractory organic P) by sequential extraction. Total phosphorus (TP) was relatively high in front of Daechung Dam and Hoinam where fish farm was run until 1997. The dominant sedimentary P form was Al-bound P, followed by Fe-bound P, which could be released from sediment to water column during suboxic state. Based on principal component analysis, Al-bound P, Fe-bound, and TP were controlled by grain size of sediments. Loosely adsorbed, detrital apatite, and refractory organic P were relatively highly accumulated at the mouth of major tributaries where suspended sediments were delivered. Sedimentary P concentrations in Daechung Lake sediments were not higher than in other lake sediments. Therefore, based on these results, major controlling factors were grain size and input of suspended sediments from tributaries.

• Geomechanics and Engineering
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• v.27 no.6
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• pp.573-582
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• 2021

From the effect of bound water, this study aims to seek the potential reasons for difference of mechanical experiment results of subgrades soils. To attain the comparatively test condition of bound water, dry forming (DF) and wet forming (WF) were used in the specimen forming process before testing, series of laboratory tests, i.e., CBR tests, direct shear tests and compaction tests. The measured optimal moisture contents, maximum dry densities, CBR, cohesion c, and internal friction angle 𝜑 were given contrastive analysis. Then to detect the adsorptive bound water in the subgrade soils, the thermal gravimetric and differential scanning calorimetry (TG-DSC) test were employed under different heating rates. The free water, loosely bound water and tightly bound water in soils were qualitatively and quantitatively analyzed. It was found that due to the different dehydration mechanics, the lost bound water in DF and WF process show their own characteristics. This may lead to the different mechanical properties of tested soils. The clayey particles have a great influence on the bound water adsorbed ability of subgrade soils. The more the clay content, the greater the difference of mechanical properties tested between the two forming methods. Moreover, in highway construction of southern China, the wet forming method is recommended for its higher authenticity in simulating the subgrade filed humidity.

• Korean Journal of Microbiology
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• v.24 no.4
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• pp.335-340
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• 1986

Two kind of ${\beta}-glucosidase$, tightly-bound enzyme(TBE) and loosely-bound enzyme(LBE), were obtained from the conidia of Aspergillus nidulans. The existence of enzymes in conidia was conformed by the fact that these enzyme activities were proportional to the number of conidia. The levels of enzyme activities were independent of aging of the conidia. Enzymes were characterized partially. In spite of the physical and chemical treatments of conidia, there was no significant change in TBE activity. The optimum pH and temperature was 6.0 and $55^{\circ}C$, respectively. Thermostability of the TBE was remarkably higher than that of mycelial ${\beta}-glucosidase$. The electrophoretic pattern of LBE was identical to that of mycelial ${\beta}-glucosidase$. These results suggest that conidial ${\beta}-glucosidase$ are involved in adaptation process of the conidia to variable environments.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.4
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• pp.43-49
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• 2019

In order to investigate the relation between sewage sludge solubilization and extracellular polymeric substances(EPS) during alkaline-ultrasonic pretreatment, SCOD/TCOD ratio, solubilization rate, VSS/TS ratio, VSS reduction rate, LB-EPS(Loosely-Bound EPS) and TB-EPS(Tightly-Bound EPS) were measured. At the condition of TS 1.0% and pH 12, solubilization rate increased by 27.7%, LB-EPS as Carbohydrate and Protein increased by 14.6 and 13.3 mg/L/g TS, respectively. Withal, VSS decreased by 26.7% and TB-EPS as Carbohydrate and Protein were extracted by 15.7 and 21.9 mg/L/g TS, respectively. Consequently, the concentrations of organic matter and LB-EPS increased and the trends appeared similarly. In addition, the concentrations trend of decreasing solid matter and extracted TB-EPS also appeared similarly.

• Ocean and Polar Research
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• v.32 no.3
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• pp.177-186
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• 2010

A sequential extraction technique was used to study sediment phosphorus speciation and its relative importance in the intertidal flat of Keunso Bay during summer and winter for a better understanding of the phosphorus cycle and bioavailability in intertidal sediments. Loosely sorbed P contents were the lowest among the five P-pools and showed little seasonal or spatial variation. Although Fe-bound P contents were almost constant in winter, they decreased rapidly with sediment depth in summer. The dissolution of Fe oxides, used as an oxidant for the anaerobic respiration, ascribed the rapid decrease of Fe-bound P in summer. Al-bound P contents displayed little seasonal variation, but showed a large spatial variation, with higher values in the upper intertidal flat. Comprising about 50% of total P, Ca-bound P contents were the highest among the five P-pools. Ca-bound P contents were higher in winter than summer, but did not exhibit a clear spatial variation. Organic P contents were higher in summer than winter, which was associated with higher primary production and clam biomass in summer. Organic P contents were higher in the lower intertidal flat than the upper intertidal flat. In Keunso Bay, bioavailable P contents of the intertidal flat comprising about one third of total P ranged from 2.41 to 5.09 ${\mu}molg^{-1}$ in summer and 3.82 to 5.29 ${\mu}molg^{-1}$ in winter. The bioavailability of P contents was higher in the lower intertidal flat than the upper intertidal flat, which was attributed to the large clam production in the lower intertidal flat.