• Journal of Korean Society for Atmospheric Environment
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• v.32 no.3
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• pp.272-279
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• 2016

Understanding sources and contributions of $PM_{2.5}$ mass and particulate PAHs from traffic-related pollution can provide valuable information for alleviating air contamination from car emissions in urban areas. Two sampling sites at the Gwangju Institute of Science and Technology (GIST, $35.228^{\circ}N$, $126.843^{\circ}E$) and National institute of environmental research NamBu Supersite (NNBS, $35.226^{\circ}N$, $126.848^{\circ}E$) were selected for comprehensive road-oriented-PM investigations. Continuous measurements from optical particle sizer (OPS) and optical particle counter (OPC) with 24 hr integrated filter based samplers for organic carbon, water soluble organic carbon, and Poly Aromatic Hydrocarbons (PAHs) were conducted during Nov. 3 through 22 in 2014. As a result, $PM_{2.5}$ mass concentrations using OPC and OPS in NNBS presented about twice higher than in GIST due to road dust impacts based on wind direction analysis. In addition, ratios of elemental carbon (EC) to organic carbon (OC) and water insoluble organic carbon (WIOC) to organic carbon (OC) supported an additional evidence of the primary pollutant contributions oriented from road dust. PAHs related to 5 rings such as benzo(e&a)pyrene indicates higher associations.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.2
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• pp.215-224
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• 2004

We report the high concentration episodes for PM$_{10}$, SO$_2$, NO$_2$, and $O_3$ in many urban areas Korea during 2002. The high concentration episodes are identified based on the National Ambient Air Quality Standards and the observations obtained from the Regional Air Monitoring Network composed of approximately 160 air pollution monitoring stations located in a number of major or big cities in South Korea including Seoul, Pusan, Daegu, and Incheon cities. The results show that the twenty cases of high concentration episodes in 2002 consists of both ozone warning episodes (6 cases) and high PM$_{10}$ concentration cases (14 cases), and one half of the latter are found to occur in association with the Yellow Sand (Asian Dust) phenomena. The most outstanding characteristics of the reported episodes are the excessively high levels of maximum PM$_{10}$ concentrations during the Yellow Sand period (i.e., exceeding 3,000$\mu\textrm{g}$/㎥ in April, 2002) and their variable occurrence frequencies across seasons. The high ozone concentration episode days are mainly resulting from both the high photochemical reactions and poor ventilations. The high PM$_{10}$ concentration days during non Yellow Sand periods, however, mostly occurred under the influence of synoptic meteorological conditions such as stagnant or slowly passing high pressure centers, and consequently prevailing weak wind speeds over the Korean peninsula. The overall results of our study thus suggest the importance of both synoptic and local meteorological factors for high concentration levels in the major and/or big cities in Korea.n Korea.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.4
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• pp.372-383
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• 2016

This study aimed at analyzing the sensitivity of ozone simulation in accordance with the meteorological nudging for a high nocturnal ozone episode. To demonstrate the effectiveness of nudging methods (e.g., nudging techniques and application domains), the following six experiments were designed: (1) control without nudging, (2) experiment with application of observation nudging to all domains (domain 1~4), and (3)~(6) experiments with application of grid nudging to domain 1, domain 1~2, domain 1~3 and all domains, respectively. As a result, the meteorological nudging had a direct (improvement of input data) and indirect (estimate natural emission) effect on ozone simulation. Nudging effects during the daytime were greater than those during the nighttime due to low accuracy of wind direction during the nighttime. On comparison of the nudging techniques, the experiments in which grid nudging was applied showed more improved results than the experiments in which observation nudging was applied. At this time point, the simulated concentrations were generally similar to the observed concentrations due to the increase in the nudging effect when grid nudging was applied up to the sub-domain. However, for high nocturnal ozone uptakes, the experiment in which grid nudging was applied do domain 1~3 showed better results than the other experiments. This is because, when grid nudging was applied to the high resolution domain (e.g., domain 4 with 1 km), the local characteristics were removed due to the smoothing effects of meteorological conditions.

• Asian Journal of Atmospheric Environment
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• v.9 no.4
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• pp.259-271
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• 2015

This study conducted analyses on biogenic volatile organic compounds (BVOC) emission sources contributing to urban ozone ($O_3$) concentration in Osaka Prefecture, Japan in summer 2010 by using the Weather Research and Forecasting model (WRF) version 3.5.1 and the Community Multiscale Air Quality model (CMAQ) version 5.0.1. This prefecture is characterized by highly urbanized area with small forest area. The contributions of source regions surrounding Osaka were estimated by comparing the baseline case and zero-out cases for BVOC emissions from each source region. The zero-out emission runs showed that the BVOC emissions substantially contributed to urban $O_3$ concentration in Osaka (10.3 ppb: 15.9% of mean daily maximum 1-h $O_3$ concentration) with day-by-day variations of contributing source regions, which were qualitatively explained by backward trajectory analyses. Although $O_3$ concentrations were especially high on 23 July and 2 August 2010, the contribution of BVOC on 23 July (35.4 ppb: 25.6% of daily maximum $O_3$) was much larger than that on 2 August (20.9 ppb: 14.2% of daily maximum $O_3$). To investigate this difference, additional zero-out cases for anthropogenic VOC (AVOC) emissions from Osaka and for VOC emissions on the target days were performed. On 23 July, the urban $O_3$ concentration in Osaka was dominantly increased by the transport from the northwestern region outside Osaka with large contribution of $O_3$ that was produced through BVOC reactions by the day before and was retained over the nocturnal boundary layer. On 2 August, the concentration was dominantly increased by the local photochemical production inside Osaka under weak wind condition with the particularly large contribution of AVOC emitted from Osaka on the day.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.2
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• pp.162-175
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• 2008

Gyeongju, which was the central city of the ancient civilization at Silla Kingdom, has various kinds of stone cultural properties. It is significantly important to preserve historical sources of Korea. However, recent air quality data measured in Gyeongju did not show good air quality level. In order to investigate variation of the concentration of the air pollutants with meteorological condition, an air quality monitoring and an aerosol sampling were conducted during the intensive monitoring period in Gyeongju. Impacts of the meteorological factors on the air pollutants were also analyzed based on the air mass pathway categories using HYSPLIT model and the local wind patterns using MM5 model. The prevailing air mass pathways were classified into four categories as following; category I affected by easterly marine aerosols, category II affected by northwesterly continental aerosols, category III affected by southwesterly continental aerosols, and category IV affected by northerly continental aerosols. The concentrations of the air quality standards were relatively lower during the fall intensive monitoring period. At that time, the easterly marine air mass pattern was dominated. The seasonal average mass concentration of $PM_{10,Opt}$, which optically measured at the monitoring site, was the highest value of $77.6{\pm}28.3\;{\mu}g\;m^{-3}$ during the spring intensive monitoring period but the lowest value of $20.1{\pm}5.3\;{\mu}g\;m^{-3}$ during the fall intensive monitoring period. The concentrations of $SO_2$ and CO were relatively higher when the air mass came from the northwestern continent or the northern continent. The concentrations of ${SO_4}^{2-}$ and ${NO_3}^-$ increased under the northwesterly continental condition. It was estimated that the acidic aerosols were dominated in the atmosphere of Gyeongju when the air mass came from the continental regions.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.2
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• pp.142-158
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• 2012

This paper investigates the physical and chemical characteristics of long-range transport (LRT) process of air pollutants by employing the MM5-CMAQ and its comparison with local emission dominant (LED) case over northeast Asia. We first classified high air pollution days into LRT and LED cases based on the synoptic meteorological variables of vorticity and geostrophic wind speed/direction at a geopotential level of over 850hPa. LRT cases are further categorized into three types of transport patterns (LRT-I-III) according to the air mass pathways from source regions. LRT-I-III are originated from northern, central, and southern China, respectively, identified by back trajectory analysis. Three LRT-I-III groups have different and unique locations of high pressure and transport pathways. The chemical characteristics showed that the simulated spatial distributions varied in terms of locations of maximum concentrations and the temporal variation of surface concentrations. The primary air pollutants such as $NO_x$, $PM_{10}$ and $SO_2$ of all of three LRT cases are well transported into Korea peninsula with different concentration levels. Of LRT cases, LRT-II has the greatest effect on air quality of Korea peninsula, followed by LRT-I and LRT-III. In comparison with LRT, the LED case shows relatively higher air pollution concentrations in general, but showed a variety of different air quality levels following the emission strength pattern. These widely varying patterns are impling the case dependent multi-directional approach for the development of indicators of long-range transport process over northeast Asia.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.1
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• pp.38-55
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• 2013

This study has been performed to select several indicators of long-range transport process that can be applied to the Northeast Asia. We first classified high air pollution days into long-range transport (LRT) dominant cases and the local emission dominant (LED) cases based on the synoptic meteorological variables including vorticity and geostrophic wind speed/direction at a geopotential level of 850 hPa. LRT cases were further categorized into two types: LRT-I type with air mass pathways from northern China and/or Mongolia, and LRT-II type from central and southern China. In each categorized case, we examined the difference of both measured aerosol optical properties of AERONET at two sites in western Korea, and the simulated characteristics of LRT process by MM5-CMAQ model. We contrasted LRT case with LED case, and then generated the LRT indicators applicable to Northeast Asia. The results showed that fine and coarse modes of LRT-II were relatively smaller than LED and LRT-I cases, respectively. Aerosol size distribution showed significantly higher concentration of fine-mode particle (mainly smoke or urban aerosols) in LED case in comparison with that of LRT groups (LRT-I, II), suggesting the amplitudes fine modes of LRT relative to LED as a possible LRT indicator. From the results of MM5-CMAQ modeling, we concluded that the conversion ratios for sulfur ($F_s$) were the most effective indicators of LRT cases, and the ratio of VOC to NOx and NOx to CO were found to be the second most effective indicators of LED case.

• Atmosphere
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• v.30 no.3
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• pp.257-276
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• 2020

Faithful evaluation of the meteorological input is a prerequisite for a better understanding of air quality model performance. Despite the importance, the preliminary meteorological assessment has rarely been concerned. In this study, we aim to evaluate the performance of the Weather Research and Forecasting (WRF) model conducting a year-long high-resolution meteorological simulation in 2016 over the Seoul metropolitan area. The WRF model was configured based on a series of sensitivity simulations of initial/boundary meteorological conditions, land use mapping data, reanalysis grid nudging method, domain nesting method, and urban canopy model. The simulated results of winds, air temperature, and specific humidity in the atmospheric boundary layer (ABL) were evaluated following statistical evaluation guidance using the surface and upper meteorological measurements. The statistical evaluation results are presented. The model performance was interpreted acceptable for air quality modeling within the statistical criteria of complex conditions, showing consistent overestimation in wind speeds. Further statistical analysis showed that the meteorological model biases were highly systematic with systematic bias fractions (f_SB) of 20~50%. This study suggests that both the momentum exchange process of the surface layer and the ABL entrainment process should be investigated for further improvement of the model performance.

• Journal of the Korean Society of Marine Environment & Safety
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• v.3 no.1
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• pp.33-49
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• 1997

One of the most important missons that are imposed on merchant ship at sea is to accomplish the safe transportation of cargo loaded. Recently, a study on the seakeeping performance has been carried out on the development of evaluation system related to the synthetic safety of a ship at sea. The seakeeping performance is the ship's ability sailing at, and executing its misson against adverse environmental factors successfully and safely. Until now, however, there has not been any method of quantitative evaluation on the dynamic safety of the ship's cargo loaded. In this regards, this paper has introduced the evaluation method of dynamic safety of the ship's cargo. In order to evaluate the dynamic safety of cargo, the vertical and lateral acceleration which causes the collapse, racking and local structure failure of cargo was adopted as the evaluation factors in the ship's motions. The response amplitude of ship's motions in regular waves is manipulated by NSM (New Strip Method) on a given 2,700 TEU full container vessel under the wind forces of 7, 8 and 9 Beaufort scale. Each response of ship's motions induced by NSM was applied to short-crested irregular waves for stochastic process on evaluation factors and then vertical and lateral acceleration of each cargo was compared with significant amplitude of each acceleration. A representative dangerous factor was determined by comparing permissible values of stacking and racking forces occurred typically to the vertical and transverse directions with the container strength required on ISO 1496 at the positions of forecastle, poop and ship's midship respectively. Through the occurrence probability of the determined factor by Rayleigh's probability density function, the dangerousness which limits loads on container's side wall as an evaluation was applied in judging of the danger of the ship's cargo loaded.

• Environmental Engineering Research
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• v.24 no.1
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• pp.159-172
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• 2019

To investigate the influence of pollution events on the chemical composition and formation processes of aerosol particles, 24-h integrated size-segregated particulate matter (PM) was collected during the fall season at an urban site of Gwangju, Korea and was used to determine the concentrations of mass, water-soluble organic carbon (WSOC) and ionic species. Furthermore, black carbon (BC) concentrations were observed with an aethalometer. The entire sampling period was classified into four periods, i.e., typical, pollution event I, pollution event II, and an Asian dust event. Stable meteorological conditions (e.g., low wind speed, high surface pressure, and high relative humidity) observed during the two pollution events led to accumulation of aerosol particles and increased formation of secondary organic and inorganic aerosol species, thus causing $PM_{2.5}$ increase. Furthermore, these stable conditions resulted in the predominant condensation or droplet mode size distributions of PM, WSOC, $NO_3{^-}$, and $SO{_4}^{2-}$. However, difference in the accumulation mode size distributions of secondary water-soluble species between pollution events I and II could be attributed to the difference in transport pathways of air masses from high-pollution regions and the formation processes for the secondary chemical species. The average absorption ${\AA}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950}$) for 370-950 nm wavelengths > 1.0 indicates that the BC particles from traffic emissions were likely mixed with light absorbing brown carbon (BrC) from biomass burning (BB) emissions. It was found that light absorption by BrC in the near UV range was affected by both secondary organic aerosol and BB emissions. Overall, the pollution events observed during fall at the study site can be due to the synergy of unfavorable meteorological conditions, enhanced secondary formation, local emissions, and long-range transportation of air masses from upwind polluted areas.