• Journal of the Korean Electrochemical Society
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• v.7 no.3
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• pp.131-137
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• 2004

Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.

• Journal of Korea Water Resources Association
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• v.40 no.4
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• pp.299-311
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• 2007

Climatic abnormal phenomena involving El Nino and La Nina have been frequently reported in recent decades. The interannual climate variability represented by El Nino-Southern Oscillation (ENSO) is sometimes investigated to account for the climatic abnormal phenomena around the world. Although many hydroclimatologists have studied the impact of ENSO on regional precipitation and streamflow, however, there are still many difficulties in finding the dominant causal relationship between them. This relationship is very useful in making hydrological forecasting models for water resources management. In this study, the seasonal relationships between ENSO and hydrologic variables were investigated in Korea. As an ENSO indicator, Southern Oscillation Index (SOI) was used. Monthly precipitation, monthly mean temperature, and monthly dam inflow data were used after being transformed to the standardized normal index. Seasonal relationships between ENSO and hydrologic variables were investigated based on the exceedance probability and distribution of hydrologic variables conditioned on the ENSO episode. The results from the analysis of this study showed that the warm ENSO episode affects increases in precipitation and temperature, and the cold ENSO episode is related with decreases in precipitation and temperature in Korea. However, in some regions, the local relationships do not correspond with the general seasonal relationship.

• Journal of the Korean Institute of Landscape Architecture
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• v.48 no.5
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• pp.67-79
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• 2020

Plans to mitigate overheating in urban areas requires the identification of the characteristics of the thermal environment of the city. The key information is the distribution of higher and lower temperatures (referred to as "hotspot" or "coldspot", respectively) in the city. This study aims to identify the areas within Jeonju City that are suffering from increasing land surface temperatures (LST) and the factors linked to such this phenomenon. To identify the hot and cold spots, Local Moran's I and Getis-Ord Gi^* were calculated for the LST based on 2017 images taken using the thermal band of the Landsat 8 satellite. Hotspot analysis revealed that hotspot regions, (the areas with a high concentration of Land Surface Temperature) are located in the old town area and in industrial districts. To figure out the factors linked to the hotspots, a correlation analysis, and a regression analysis taking into account environmental covariates including Normalized Difference Vegetation Index (NDVI) and land cover. The values of NDVI showed that it had the strongest effect on the lowering LSTs. The results of this study are expected to provide directions for urban thermal environment designing and policy development to mitigate the urban heat island effect in the future.

• Korean Journal of Agricultural and Forest Meteorology
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• v.13 no.4
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• pp.176-184
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• 2011

Cold air on sloping surfaces flows down to the valley bottom in mountainous terrain at calm and clear nights. Based on the assumption that the cold air flow may be the same as the water flow, current models estimate temperature drop by regarding the cold air accumulation at a given location as the water-like free drainage. At a closed catchment whose outlet is blocked by man-made obstacles such as banks and roads, however, the water-like free drainage assumption is no longer valid because the cold air accumulates from the bottom first. We developed an empirical model to estimate quantitatively the effect of cold pool on nocturnal temperature in a closed catchment. In our model, a closed catchment is treated like a "vessel", and a digital elevation model (DEM) was used to calculate the maximum capacity of the cold pool formed in a closed catchment. We introduce a topographical variable named "shape factor", which is the ratio of the cold air accumulation potential across the whole catchment area to the maximum capacity of the cold pool to describe the relative size of temperature drop at a wider range of catchment shapes. The shape factor is then used to simulate the density profile of cold pool formed in a given catchment based on a hypsometric equation. The cold lake module was incorporated with the existing model (i.e., Chung et al., 2006), generating a new model and predicting distribution of minimum temperature over closed catchments. We applied this model to Akyang valley (i.e., a typical closed catchment of 53 $km^2$ area) in the southern skirt of Mt. Jiri National Park where 12 automated weather stations (AWS) are operational. The performance of the model was evaluated based on the feasibility of delineating the temperature pattern accurately at cold pool forming at night. Overall, the model's ability of simulating the spatial pattern of lower temperature were improved especially at the valley bottom, showing a similar pattern of the estimated temperature with that of thermal images obtained across the valley at dawn (0520 to 0600 local standard time) of 17 May 2011. Error in temperature estimation, calculated with the root mean square error using the 10 low-lying AWSs, was substantially decreased from $1.30^{\circ}C$ with the existing model to $0.71^{\circ}C$ with the new model. These results suggest the feasibility of the new method in predicting the site-specific freeze and frost warning at a closed catchment.

• Journal of the Korean earth science society
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• v.23 no.7
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• pp.552-564
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• 2002

The data of satellite-observed Microwave Sounding Unit (MSU) channel 1 (Ch1) brightness temperature and General Circulation Model (GCM) reanalyses over the globe have been used to investigate low tropospheric hydrometeors and microwave surface emissivity during the period from January 1981 to December 1993. The average of GCM Ch1 temperature has been reconstructed from three kinds of reanalyses, based on the MSU weighting function. Since the GCM temperature mainly corresponds to the thermal state of the lower troposphere without the difference in the emissivity between ocean and land, it is higher in summer than in other seasons over the regions. The MSU temperature over the ocean shows its maximum at the ITCZ and the SPCZ due to hydrometeors. Over high latitude ocean, the temperature is enhanced because of sea ice emissivity, while it is reduced over the land. The seasonal displacement of the ITCZ and the SPCZ systematically appeared in the difference of Ch1 temperature between the GCM and the MSU. The difference values decrease in the regions of the ITCZ, the SPCZ, and the sea ice because of the increase of the MSU temperature. According to the local minima of the values, the ITCZ moves norhward to 9 N in fall, and the SPCZ moves southward to 12 S in boreal fall and winter. The sea ice in the northern hemisphere is extended southward to 53 N in winter, while the ice in the southern hemisphere, northward to 58 S in boreal summer. We also have discussed the separated contribution from hydrometeors and surface emissivity to the MSU Ch1 temperature, utilizing radiative transfer theory. The increase of 4-6K in the temperature over the ITCZ is inferred to result from hydrometeors of 1-1.5mm/day, and furthermore the increase of 10-30K over the high latitude ocean, ice emissivity of 0.6-0.9.

• Computational Structural Engineering
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• v.6 no.4
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• pp.89-98
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• 1993

As the construction of nuclear power plants are increased, nuclear wastes disposal has been faced as a serious problem. If nuclear wastes are to be buried in the underground stratum, thermo-mechanical behavior of stratum must be analyzed, because high temperature distribution has a significant effect on tunnel and surrounding stratum. In this study, in order to analyze the structural behavior of the underground which is subject to concentrated heat sources, a coupling method of nonlinear finite elements and linear boundary elements is proposed. The nonlinear finite elements (NFE) are applied in the vicinity of nuclear depository where thermo-mechanical stress is concentrated. The boundary elements are also used in infinite domain where linear behavior is expected. Using the similar method as for the problem in mechanical field, the coupled nonlinear finite element-boundary element (NFEBE) is developed. It is found that NFEBE method is more efficient than NFE which considers nonlinearity in the whole domain for the nuclear wastes depository that is expected to exhibit local nonlinearity behavior. The effect of coefficients of the rock mass such as Poisson's ratio, elastic modulus, thermal diffusivity and thermal expansion coefficient is investigated through the developed method. As a result, it is revealed that the displacements around tunnel are largely dependent on the thermal expansion coefficients.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.12
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• pp.48-58
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• 2006

The spray and combustion characteristics of liquid jet in cross flow with variation of injection angle are numerically studied. Numerical analysis was carried out using KIVA code, which may be used to generate numerical solutions to spray and chemical reactive fluid problem in three space dimensions and modified to be suitable for simulating liquid jet ejected into the cross flow. Wave model and Kelvin- Helmholtz(KH) /Rayleigh-Taylor(RT) hybrid model were used for the purpose of analyzing liquid column, ligament, and the breakup of droplet. Penetration length increases as flow velocity decreases and injection velocity increases. Numerical error increases as inflow velocity increases. The results of flame propagation contour in combustion chamber and local temperature distribution, combustion emissions were obtained.

• Parasites, Hosts and Diseases
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• v.44 no.4 s.140
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• pp.285-294
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• 2006

Changing patterns of the reemerging Plasmodium vivax malaria in the Republic of Korea (South Korea) during the period 1993 to 2005 are briefly analyzed with emphasis on the control measures used and the effects of meteorological and entomological factors. Data were obtained from the Communicable Diseases Monthly Reports published by the Korea Center for Disease Control and Prevention, and webpages of World Health Organization and United Nations. Meteorological data of Kangwon-do (Province) were obtained from local weather stations. After its first reemergence in 1993, the prevalence of malaria increased exponentially, peaking in 2000, and then decreased. In total, 21,419 cases were reported between 1993 and 2005 in South Korea. In North Korea, a total of 916,225 cases were reported between 1999 and 2004. The occurrence of malaria in high risk areas of South Korea was significantly (P < 0.05) correlated with the mosquito population but not with temperature and rainfall, Control programs, including early case detection and treatment, mass chemoprophylaxis of soldiers, and international financial aids to North Korea for malaria control have been instituted. The situation of the reemerging vivax malaria in the Republic of Korea is remarkably improving during the recent years, at least in part, due to the control activities undertaken in South and North Korea.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.353-356
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• 2009

A pivotal mechanical balance of plant for 75kW class molten carbonate fuel cells comprise of a catalytic burner and an ejector which has been designed and tested in KEPRI(Korea Electric Power Research Institute). The catalytic burner, which oxidizes residual fuel in the anode tail gas, was operated at several conditions. Some problems arose due to local overheating or auto-ignition, which could limit the catalyst life. The catalytic burner was designed by considering both gas mixing and gas velocity. Test results showed that the temperature distribution is very uniform. In addition, an ejector is a fluid machinery to be utilized for mixing fluids, maintaining vacuum, and transporting them. The ejector is placed at mixing point between the anode off gas and the cathode off gas or the fresh air Several ejectors were designed and tested to form a suction on the fuel tail gas and balance the differential pressures between anode and cathode over a range of operating conditions. The tests showed that the design of the nozzle and throat played an important role in balancing the anode tail and cathode inlet gas pressures. The 75kW MCFC system built in our ejector and catalytic burner was successfully operated from Novembe, 2008 to April, 2009. It recorded the voltage of 104V at the current of 754A and reached the maximum generating power of 78.5kW DC. The results for both stand-alone and integration into another balance of plant are discussed.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.5
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• pp.479-490
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• 1998

The concentrations of ten inorganic (sodium, chloride, sulfate, ammonia, etc.) and three organic (acetate, formate, and MSA) ions associated with airborne particulate matter were measured from Cheju Island, Korea during the three field intensive campaigns conducted in (1) Sept./oct. 1997 (fall), (2) Dec. 1997 (winter), and (3) April 1998 (spring). The results of our measurements indicated that the concentration levels of most ionic species were decreasing significantly across the three experimental periods. The patterns of concentration reduction were clear as the sum of all cation and anion species changed dramatically across those periods such as 294> 144 > 65 and 193 >96>74 nequiv/m3, respectively. The changes were best explained in terms of the wind rose patterns of the study site. Since our sampling spot is located on the western-end point of Cheju Island, it is likely to reflect the effects of diverse sources such as natural, marine processes during NW and local non-maritime ones during SE winds. .Hence, the periodical changes in ionic concentrations may be accounted for by the comparable changes in wind direction. To further investigate environmental characteristics of these ionic components, correlation analysis was conducted not only between meteorological and ion data but between different ion-pairs. The results of these analyses confirm that the concentration levels of ionic species are strongly affected by wind speed and temperature and that there are certain patterns between ion species to which such effects apply. In light of the significance of the wind rose patterns in the area, we further extended these analyses into four data groups that were divided on the basis of wind direction. The results of these analyses showed that the strength of correlations between important pairs (e.g.:. between windspeed and most of major inorganic species including sodium and chloride) can be ranked on the distribution of major ions are very diverse, depending on data grouping scheme for such analysis. The results of this study thus suggest that environmental behavior of chemical components be analyzed in various respects, rather than simple standard, especially if measurements are made in complex environmental condition under which both natural and anthropogenic effects are competing each other.