• Title/Summary/Keyword: loading rate effect

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The effect of the modification methods on the catalytic performance of activated carbon supported CuO-ZnO catalysts

  • Duan, Huamei;Yang, Yunxia;Patel, Jim;Burke, Nick;Zhai, Yuchun;Webley, Paul A.;Chen, Dengfu;Long, Mujun
    • Carbon letters
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    • v.25
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    • pp.33-42
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    • 2018
  • Activated carbon (AC) was modified by ammonium persulphate or nitric acid, respectively. AC and the modified materials were used as catalyst supports. The oxygen groups were introduced in the supports during the modifications. All the supports were characterized by $N_2$-physisorption, Raman, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and thermogravimetric analysis. Methanol synthesis catalysts were prepared through wet impregnation of copper nitrate and zinc nitrate on the supports followed by thermal decomposition. These catalysts were measured by the means of $N_2$-physisorption, X-ray diffraction, XPS, temperature programmed reduction and TEM tests. The catalytic performances of the prepared catalysts were compared with a commercial catalyst (CZA) in this work. The results showed that the methanol production rate of AC-CZ ($23mmol-CH_3OH/(g-Cu{\cdot}h)$) was higher, on Cu loading basis, than that of CZA ($9mmol-CH_3OH/(g-Cu{\cdot}h)$). We also found that the modification methods produced strong metal-support interactions leading to poor catalytic performance. AC without any modification can prompt the catalytic performance of the resulted catalyst.

Spherical Indentation Testing to Evaluate Mechanical Properties In 1Cr-1Mo-0.25V Steel (Spherical Indentation Testing에 의한 1Cr-1Mo-0.25V 강의 기계적 물성 평가)

  • Lee, J.M.;Nam, Y.H.;Nham, S.H.;Lee, S.S.;Lee, O.S.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.266-271
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    • 2001
  • Spherical indentation technique was developed to evaluate the flow properties of metallic materials in carbon steel, stainless steel and alloys, etc. Through the spherical indentation test, differently degraded 1Cr-1Mo-0.25V steel's mechanical properties were observed and compared with conventional standard test data. The flow properties of 1Cr-1Mo-0.25V steels were estimated by analyzing the indentation load-depth curve. To characterize the flow property, we used material yield slope and constraint factor index rather than strain-hardening exponent because the variation of strain-hardening exponent was very little and the data showed irregularly. And the constraint factor's effect was small when the material yield slope was taken into account.

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Fatigue Crack Propagation Behaviors under the Controlloed Stress Amplitude (하중진폭제어에 따르는 피로균열전파거동)

  • Kim, Sang-Chul;Ham, Kyoung-Chun;Kang, Dong-Myeong
    • Journal of the Korean Society for Precision Engineering
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    • v.9 no.3
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    • pp.140-148
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    • 1992
  • The effect of mechanical, properties in the plastic zone near the crack-tip was investigated, under various controlled loading conditions, i.e., ${\Delta}K$ increasing, ${\Delta}K$ decreasing, and single overload test. For both ${\Delta}K$ decreasing test and ${\Delta}K$ increasing test with constant stress ratio, it is found that the ratio of material constant m'( ${\Delta}K$ decreasing test) to material constant m( ${\Delta}K$ increasing test) is larger than 1 for n<0.1, and it is equal to 1 for 0.10.2. A modified crack growth rate equation based on Forman's equation which applied stable region of fatigue crack propagation in ${\Delta}K$ decreasing test is proposed. Within the limit of this single overload test, an empirical relation between among the retardation ratio (Nd/ $N^{*}$), the strain hardening exponent (n) and the percent peak load (%PL) has been established.established.

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Clinical Observations of Abnormal Glucose Tolerance in Hyperthyroidism (갑상선(甲狀腺) 기능항진증(機能亢進症)에서의 당부하(糖負荷)에 대(對)한 임상적(臨床的) 관찰(觀察))

  • Lee, Kyung-Ja;Lee, Hong-Kyu
    • The Korean Journal of Nuclear Medicine
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    • v.3 no.2
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    • pp.23-27
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    • 1969
  • Plasma glucose levels before and after oral glucose administration have been compared in a group of 76 thyrotoxic subjects and a group of 8 normal control subjects in order to study the effect of glucose loading in thyrotoxicosis. Following were the results: 1. The mean fasting plasma glucose level was elevated in the thyrotoxic group(95.5mg%) compared to normal control group (88mg%). 2. The peak of glucose tolerance curve is at 30 minutes after glucose administration in both groups, but its mean value was 44mg% higher in thyrotoxic group than in control group. 3. The plasma glucose levels returned towards the fasting level in the later stage of the test more rapidly in thyrotoxic group than in control group. 4. 69.6% of oral glucose tolerance tests were impaired in the thyrotoxic group, and the occurance of abnormal glucose tolerance could be related to the degree of thyrotoxicity, sex and age. 5. The mechanisms of the impaired glucose tolerance in thyrotoxicosis are thought to be related to an increased rate of glucose absorption from gastrointestinal tract, abnormal liver function with decreased hepatic glycogenesis, increased glucose oxidation, decreased pancreatic release of insulin, and genetic relationship between diabetes and thyrotoxicosis.

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Microwave-Assisted Acid-Hydolysis of Laminaria Japonica and its Ethanol Productivity: Comparison with Conventional Heating (마이크로파를 이용한 다시마의 산 가수분해와 에탄올 생산성: 재래식 가열과 비교)

  • Song, Myoung-Ki;Na, Choon-Ki
    • New & Renewable Energy
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    • v.9 no.2
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    • pp.5-14
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    • 2013
  • The efficiency of microwave-assisted acid hydrolysis of seaweeds for the production of ethanol was investigated and its effect on hydrolysis into reducing sugar and fermentation into ethanol evaluated as compared with those by conventional heating. A brown seaweed, Laminaria japonica (10-100g/L) was hydrolysed under dilute acidic condition (0.5N $H_2SO_4$, $100^{\circ}C$) with two sorts of heating: microwave irradiation for ${\leq}10min$ and conventional heating for 10-60min. Microwave-assisted hydrolysis was shown to be more efficient. A similar range of reducing sugar and ethanol yields as with the conventional autoclave heating procedure(${\geq}30min$) was observed, but it was obvious that production of ethanol from microwave-assisted hydrolysis had a 3 times faster reaction rate leading to very short production times, lower energy consumption/loss than from the conventional heating mode, and higher biomass loading without significant reducing ethanol yield, thus microwave-assisted acid hydrolysis is a potential alternative method for more effective hydrolysis of Laminaria japonica.

Effects of Dopamine on Intracellular pH in Opossum Kidney Cells

  • Kang, Kyung-Woo;Kim, Yung-Kyu
    • The Korean Journal of Physiology and Pharmacology
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    • v.7 no.3
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    • pp.187-191
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    • 2003
  • $Na^+/H^+$ exchanger (NHE) has a critical role in regulation of intracellular pH (pHi) in the renal proximal tubular cells. It has recently been shown that dopamine inhibits NHE in the renal proximal tubules. Nevertheless, there is a dearth of information on the effects of long-term (chronic) dopamine treatment on NHE activities. This study was performed to elucidate the pHi regulatory mechanisms during the chronic dopamine treatments in renal proximal tubular OK cells. The resting pHi was greatly decreased by chronic dopamine treatments. The initial rate and the amplitude of intracellular acidification by isosmotical $Na^+$ removal from the bath medium in chronically dopamine-treated cells were much smaller than those in control. Although it seemed to be attenuated in $Na^+$-dependent pH regulation system, $Na^+$-dependent pHi recovery by NHE after intracelluar acid loading in the dopamine-treated groups was not significantly different from the control. The result is interpreted to be due to the balance between the stimulation effects of lower pHi on the NHE activity and counterbalance by dopamine. Our data strongly suggested that chronic dopamine treatment increased intrinsic intracellular buffer capacity, since higher buffer capacity was induced by lower resting pHi and this effect could attenuate pHi changes under extracellular $Na^+$-free conditions in chronically dopamine-treated cells. Our study also demonstrated that intracellular acidification induced by chronic dopamine treatments was not mediated by changes in NHE activity.

A Study on the Time-Dependent Deformation Behaviors of PMMA in Nanoindentation Process for Hyperfine Pit Structure Fabrication (극미세 점 구조체 제작을 위한 나노압입 공정에서 PMMA의 시간의존적 변형거동에 관한 연구)

  • Kim Hyun-Il;Kang Chung-Gil;Youn Sung-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.7 s.172
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    • pp.62-70
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    • 2005
  • The nanoindenter and AFM have been used for nanofabrication, such as nanolithography, nanowriting, and nanopatterning, as well as measurement of mechanical properties and surface topology. Nanoscale indents can be used as cells for molecular electronics and drug delivery, slots for integration into nanodevices, and defects for tailoring the structure and properties. Therefore, it is very important to make indents of desired morphology (shape, size and depth). Indents of different shapes can be obtained by using indenters of different geometries such as a cube comer and conical and spherical tips. The depth and size of indents can be controlled by making indentations at different indentation loads. However, in case of viscoplastic viscoelastic materials such as polymethylmethacrylate (PMMA) the time dependent deformation (TDD) should also be considered. In this study, the effect of process parameters such as loading rate and hold-time at peak load on the indent morphology (maximum penetration depth, elastic recovery, transient creep recovery, residual depth pile-up height) of PMMA were studied for hyperfine pattern fabrication.

Temperature Effect of the UASB Process for Treatment of Organic Waste (상향류식 혐기성 입상슬러지 공법의 유기폐수 처리 효율에 미치는 온도의 영향)

  • Park, Chul Hwi;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.45-54
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    • 1996
  • Effects of temperature on the efficiency of the Upflow Anaerobic Sludge Blanket(UASB) process for treatment of wastewater from a starch and related products manufacturing industry were investigated using laboratory scale reactors equipped with two types of Gas-Solid Separator(GSS). Both fresh digested sludge and granular sludge stored nearly for one year at room temperature were good as a seeding material. The reactors seeded with aged granular sludge showed slow start-up, however, lowered activity at the initial period was recovered gradually. The GSS with an inner cylinder was proved to be effective in liquid-solid separation compared to the conventional type. Although the rate of organic removal and gas production per unit volatile suspended solids in the reactor reduced significantly as the temperature varied from 35 to $20^{\circ}C$, possibility of operation at low temperatures was shown as a result of gradual buildup of volatile suspended solids in the bed. Stable operation with a reduced efficiency was possible at a COD loading of $5-8kg/m^3/day$ at a temperature as low as $20^{\circ}C$.

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Effect of Proximate Composition Ratios for Biogas Production

  • Kim, Min-Jee;Kim, Soo-Ah;Kim, Sang-Hun
    • Journal of Biosystems Engineering
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    • v.42 no.3
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    • pp.155-162
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    • 2017
  • Purpose: The objective of this study was to evaluate the biogas productivity of agricultural by-products (ABPs) based on their proximate composition. Specifically, the effects of proximate composition were investigated, and a new mixing method was developed using various ABPs that are difficult to digest for biogas production. Methods: Experiments were conducted to compare the biogas productivity between a single ABP and a mixture of ABPs that had the same proximate composition as the single ABP. To match the proximate compositions of radish waste and corn distiller's dried grains with solubles (DDGS), mixed ABPs were made from various ABPs. Biogas potential tests (BMP tests) were performed at an organic loading rate (OLR) of 2.5 g VS/L and a feed to microorganism ratio (F/M) of 0.5 under the mesophilic condition. Results: The individual ABPs (radish and corn DDGS) and the mixed ABPs (cabbage waste with skim milk waste, bean-curd waste with skim milk waste, and some others) produced similar amounts of biogas. Conclusions: The new mixing method based on proximate composition can be applied to other ABPs and organic wastes from factories and municipal waste treatment plants to develop renewable energy and effective waste treatment methods.

A Study on the Bounding Value of Valve Performance Parameters for Motor Operated Flexible Wedge Gate Valve (모터구동 Flexible Wedge형 게이트밸브의 밸브 성능인자 Bounding Value에 대한 연구)

  • Kim, Dae-Woong;Yoo, Seong-Yeon;Park, Sung-Keun;Lee, Do-Hwan
    • The KSFM Journal of Fluid Machinery
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    • v.10 no.5
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    • pp.46-53
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    • 2007
  • Stem friction coefficient and valve factor are very important parameters for the evaluation of valve performance. In this study, the characteristics of stem friction coefficient and valve factor are analyzed, and thor bounding value is determined. The hydraulic testing is performed for many flexible wedge gate valves in the plant and statistical method is applied to the determination of bounding value. According to the results of this study, stem friction coefficient does not change much with differential pressure, and the bounding value of closing stroke is higher than that of opening stroke. The valve factor of valves with high differential pressure is higher than that of valves with medium differential pressure. It means valve factor is more sensitive to the differential pressure than the stem friction coefficient. Valve factor of the closing stroke is higher than that of opening stroke due to piston effect.