• Title/Summary/Keyword: lithium bromide

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Development of Absorption fluid with Water-Lithium bromide-Lithium nitrate system (Water-Lithium bromide-Lithium nitrate계 흡수용액 개발)

  • 오영삼;주우성;박달령;조원일;백영순;방효선
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1996.10b
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    • pp.190-192
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    • 1996
  • 본 연구는 기존의 Water-Lithium Bromide(H2O/LiBr) 용액에 비해 부식성이 낮은 Water-Lithium bromide-Lithium Nitrate계(H2O/LiBr-LiNO3)용액의 용해도, 증기압, 점도, 표면장력 등의 물리적 성질을 조사하였다. 또한 용해도가 가장 큰 최적의 혼합 몰비를 구하여 증기압 및 점도, 표면장력등의 물성을 구함으로써 흡수식 냉온수기용 홉수제 개발의 기본 자료를 확보하였다. 이러한 연구 결과로부터 다성분 Lithium 염 혼합물계로 이루어진 흡수용액 개발의 기초자료로 이용하고자 한다.

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Effect of Lithium Bromide on Chitosan/Fibroin Blend (키토산/피브로인 블렌드에 있어서 브롬화 리튬의 효과)

  • Kim, Hong-Sung;Park, Sang-Min;Yoon, Sang-Jun;Hwang, Dae-Youn;Jung, Young-Jin
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.509-513
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    • 2009
  • For examining an effect of lithium bromide on structure and property of chitosan/fibroin blend, we investigated the structural characteristic of chitosan/fibroin blend films using solution with lithium bromide which was removed during a casting. The chitosan/fibroin blend formed a complex with the dissolved bromine/lithium ions. The crystalline phase of the complex was found in the blend film at LiBr concentration of 0.6 mol/L. The degree of crystallization was decreased with increasing the concentration of LiBr. The hydrated crystalline phase of chitosan was formed in the blend film that lithium bromide was removed in the process of casting by neutralization and osmotic action. The crystallinity of this film was increased largely as compared with that of the film without lithium bromide. The complexed blend film formed hydrogel absorbing plenty of water.

The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.125-131
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    • 2002
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the fresh water and 62 % lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze was carried out. And polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: (1) As the experimental temperature increase, the change of corrosion rate of Al-Ni bronze become duller than SS 400 and Cu in 62% lithium bromide solution. (2) According as corrosion environment is changed from fresh water to 62% lithium bromide solution, potential change of Cu and Al-Ni bronze become less noble than SS 400. (3) The corrosion sensitivity of Al-Ni bronze was duller than that of Cu and SS 400 in 62% LiBr solution.

Experimental investigation of enhanced heat and mass transfer toy LiBr/$H_2O$ absorber (LiBr/$H_2O$계 흉수기의 흡수촉진에 관한 실험적 연구)

  • 설원실;권오경;윤정인
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.5
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    • pp.581-588
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    • 1998
  • An experimental study of the absorption process of water vapor into Lithium Bromide solution was performed. For the purpose of development of high performance absorption chiller-heater utilizing Lithium Bromide solution as working fluid, the absorber is the most effective to improve the performance of an absorber because it requires the largest heat transfer area in an absorption chiller-heater system. This paper introduces bare tube and floral tube for the absorber of absorption chiller-heaters. floral tube has higher heat and mass transfer performance than bare tube conventionally used in absorbers and the it is expected to perform high heat and mass transfer. This paper will provide important information on the selection of absorber tubes in commercial absorption chiller -heaters.

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Characteristic of Heat and Mass Transfer on Inner Ribbed Notched Fin Tube Absorber (내면가공 핀튜브 흡수기의 열 및 물질전달특성)

  • 설원실;권오경;문춘근;정용옥;윤정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.4
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    • pp.478-485
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    • 2000
  • An experimental study of the absorption process of water vapor into lithium bromide solution was performed. For the purpose of development of high performance absorption chiller-heater utilizing Lithium Bromide solution as working fluid, the absorber is the most effective to improve the performance of an absorber because it requires the largest heat transfer area in an absorption chiller-heater system. This paper introduces bare tube and inner ribbed notched fin tube for the absorber of absorption chiller-heaters. Inner ribbed notched fin tube has about 10∼20% higher heat and mass transfer performance than bare tube conventionally used in absorbers and the it is expected to perform high heat and mass transfer. This paper will provide important information on the selection of absorber tubes in commercial absorption chill-heaters.

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Synthesis of Acyclic Nucleosides of 2-Thio-Pyrimidines and -Purines Using a New Coupling Agent of Lithium Bromide

  • Kim, Joong-Young;Kim, Yong-Hae
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.295-298
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    • 1988
  • Acyclic nucleosides, 1-[[1,3-bis(benzyloxy)-2-propoxy]methyl]-2-thiopyrimidine, 9-[[1,3-bis(benzyloxy)-2-propoxy]methyl]-6-amino -2-thiopurine, 1-(2-acetoxyethoxymethyl)-2-thiopyrimidine, and 9-[[1,3-bis(benzyloxy)-2-propoxy]methyl]-6-amino -2-thiopurine have been synthesized by coupling pyrimidine and purine bases with acyclic acetates using a new coupling reagent of lithium bromide in the presence of trifluoro acetic acid in acetonitrile.

The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using LiBr-$H_2O$ Working Fluids (LiBr-$H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철;윤병두;강성수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.11a
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    • pp.92-97
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    • 2001
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using LiBr-$H_2O$ working fluids. In the fresh water and 62 %lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(Cl220T-OL) and Ni-Al bronze was carried out. And Polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: As the experimental temperature increase, the change of corrosion rate of Ni-Al bronze become duller than SS 400 and Cu in 62 % lithium bromide solution. Open circuit potential of SS 400 is less noble than that of Cu and Ni-Al bronze in fresh water, but that becomes noble than Cu and Ni-Al bronze in 62 % lithium bromide solution. The corrosion sensitivity of Ni-Al bronze was controlled than that of Cu and SS 400 in 62% LiBr solution.

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Characteristics of Heat and Mass Transfer for a Falling Film Type Absorber with Insert Spring Tubes (스프링삽입형 유하액막식 흡수기의 열 및 물질전달 특성)

  • 윤정인;오후규;백목효부
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.6
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    • pp.1501-1509
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    • 1995
  • It is known that the heat and mass transfer characteristics in the absorber are most sensitive of the temperature boost of all the heat exchangers and the development of a more efficient absorber should be highly important. This paper describes absorption experiments made with different inside tube diameters, tube length and tube shapes. The purpose of this study is to acquire basic knowledge about heat and mass transfer in a falling film type absorber with vertical inner tubes. Heat and mass transfer were measured for water vapor absorption into a Lithium Bromide-water solution flowing down an absorber of vertical inner tubes. As a result, insert spring tube compares bare tube and heat transfer improved by order of insert spring tube P2(pitch 20 mm) and P1(pitch 10 mm).

Evaporation of Water in an Aqueous Lithium Bromide Solution flowing over a Horizontal Tube

  • Kim, Dong-Kwan;Kim, Moo-Hwan
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.3
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    • pp.57-62
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    • 2001
  • Falling film heat transfer analyses with aqueous lithium bromide solution were performed to investigate the transfer characteristics of the copper tubes. Finned (knurled) tube and a smooth tube were selected as test specimens. Averaged generation fluxes of water and the heat flux were obtained. As the film flow rate of the solution increased, the generation fluxes of water decreased for both tubes due to the fact that the heat transfer resistance increased with the film thickness. The effect of the enlarged surface area at the knurled tube was supposed to be dominant at a small flow rate. The generation fluxes of water increased with the increasing degree of tube wall superheat. Nucleate boiling is supposed to occur at a wall superheat of 20K for a smooth tube, and at 10K for a knurled tube. The increased performance of the knurled tube was supposed to mainly come from the effect of the increased heating surface area.

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Simulation of a two-stage absorption heat pump cycle using treated sewage (하수처리수 이용 흡수식 열펌프 사이클의 시뮬레이션)

  • 이용화;신현준;최국광
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.422-430
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    • 1999
  • This paper concerns the study of a two-stage absorption heat pump cycle to utilize treated sewage. This two-stage cycle consists of coupling double-effect with parallel or series flow type and single effect cycle so that the first stage absorber and condenser produces hot water to evaporate refrigerant in the evaporator of the second stage. The effects of operating variables such as absorber temperature on the coefficient of performance have been studied for two-stage absorption heat pump cycle. The working fluid is lithium bromide and water solution. The efficiency of the two-stage absorption heat pump cycle has been studied and simulation results show that higher coefficient of performance could be obtained for the first stage with parallel flow type. The optimum ratio of solution distribution can be shown by considering the COP, the crystallization of solution and the generator temperature.

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