• 한국연소학회지
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• 제13권2호
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• pp.33-41
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• 2008

The high permeability of the gas in the molten iron of the dripping zone of the blast furnace is a major factor in achieving the stable operation of a furnace with high productivity. Basic studies of the liquid flow behavior in a packed bed are necessary to grasp the effect of various operational changes on conditions in the dropping zone. Molten iron and slag together playa critical role in the lower zone, transporting mass and energy, while impairing and redistributing the gas flow. In turn, molten iron and slag undergo physical and chemical changes, and are redistributed radially as they descend to the hearth. In this research, mathematical formulations are derived for the gas and the liquid. The solid phase is fixed with constant porosity. The information for the molten iron and slag includes the hold-up, velocity, pressure, and information related to the areas of interaction between the gas and the liquid, and the solid and the liquid. Predictable results include the velocity, pressure and temperature distribution. Additional parameters include the packed particle size and the air blast rate.

• 한국물환경학회지
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• 제21권6호
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• pp.549-563
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• 2005

The study was carried out to develop and standardize the analytical method of 1,4-dioxane in water. The National Institute of Environmental Research in Korea has monitored for 1,4-dioxane in water since 1998 and it has been detected in environmental water occasionally. But the environmental pollution and analytical method in water is not well known over the world. The trace analytical method at low-${\mu}/L$ level is prerequisite in order to evaluate the residue of 1,4-dioxane in water. Evaluation of the method was demonstrated by comparing and analyzing with liquid-liquid extraction, solid-phase extraction and purge & trap technique. As a result of experiment by standard solutions and raw samples, the precision and accuracy for three methods were obtained within error rate of about 10%. Therefore, three methods were standardized as official monitoring method in Korea. Also, a convenient and simple liquid-liquid extraction method for the analysis of 1,4-dioxane in water was developed by combined with gas chromatography/mass spectrometry and applied to the water samples in Korea

• Membrane and Water Treatment
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• 제2권4호
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• pp.207-223
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• 2011

Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.

• 오토저널
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• 제14권6호
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• pp.81-90
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• 1992

This paper deals with an experimental study on the initial condition of liquid film surface waves disintegration and investigation on the behavior of liquid film surface waves formed by the high speed air flow on the solid plane surface. The authors conducted the qualitative and quantitative study to in vestigate the liquid film flow phenomena, the liquid film disintegration mechanism, and droplet formation process with breaking the liquid film surface wave. The newly devised transparent rectangular test section which has semi-two-dimensional flow at the center of the bottom was introduced to perform the experimental study, and it can generate the uniform thickness liquid film at the bottom. The strobo streak camera was used to obtain the instantaneously transformed photographs. The electronic measuring device was also used to measure the liquid film thickness variation in order to perform the easy and effective analysis of complex flow phenomena in the air-water cocurrent flow.

• Journal of Welding and Joining
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• 제13권2호
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• pp.132-138
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• 1995

Rene80 superalloy was liquid phase diffusion bonded by using boron(B) as an insert material, where B has high diffusivity and higher melting point as an insert material. Bonding procedure and bonding mechanism of Rene80/B/Rene80 joint were investigated. As results, liquid metal was produced by solid state reaction between base metal and insert material on bonding zone. The liquid metal was produced preferentially at the grain boundary. Except for production of liquid metal, other bonding procedure was nearly same as TLP(Transient Liquid Phase) bonding. Bonding time, however, was reduced compared to prior result of TLP bonding. By bonding S.4ks at l453K, Ren80/B/Rene80 joint was isothermally solidified and homogenized where thickness of insert material was 7.5.mu.m.

• 한국환경과학회지
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• 제3권4호
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• pp.403-408
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• 1994

Catalytic slurry reactors, in which a solid maintained in the rom of fine particles suspended in a liquid, are frequently used in chemical and biochemical and industries. In these processes the particle loading is normally low so that the effects of particles on the liquid-film mass transfer coefacent and the gas-liquid interface area are assumed to be negligible. But it is known from the works, amongst others, that the finely powdered activated carbon can increase the gas-liquid mass transfer significantly in surface-aerated reactors. The stirred cell (13.2cm inside diameter) contained four baffles and at the stirring speeds range of 80 ∼ 300ppm, the gas-liquid interfacial area could be considered as that of the cross section of the vessel (that is, 130.1cm2). When the stirrer speeds were increased, the effective interfacial area was slightly higher than the geometric area and was obtained experimentally from the Danckwerts plots. Key Words : gas-liquid interfacial area, Duckwert's Plot stirred dell. mass transfer coefficient.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.279-279
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• 2006

We report a fabrication of carbon nanotube (CNT) monolayer thin film using liquid-liquid interface. The multiwalled carbon nanotube (MWCNT), which were synthesized by the alumina template method formed a monolayer at the liquid-liquid interface after sonicating the MWCNT water-oil dispersion. Moreover, with the addition of ethanol, the MWCNT monlayer was also formed at the liquid-liquid interface. The monolayer is transferable onto solid substrates and the transferred film was observed using atomic force microscopy (AFM)

• 소성∙가공
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• 제18권1호
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• pp.26-38
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• 2009

It was reported that the semi-solid forming process has many advantages over the conventional forming process, such as a long die life, good mechanical properties and energy savings. It is very important, however, to control liquid segregation to gain mechanical property improvement of materials. During forming process, rheology material has complex characteristics, thixotropic behavior. Also, difference of velocity between solid and liquid in the semi-solid state material makes a liquid segregation and specific stress variation. Therefore, it is difficult for a numerical simulation of the rheology process to be performed. General plastic or fluid dynamic analysis is not suitable for the behavior of rheology material. The behavior and stress of solid particle in the rheology material during forging process is affected by viscosity, temperature and solid fraction. In this study, compression experiments of aluminum alloy were performed under each other tool shape which is rectangle shape(square array), rectangle shape(hexagonal array), and free shape tool. In addition, the dynamics behavior compare with Okano equation to power law model which is viscosity equation.

• Asian-Australasian Journal of Animal Sciences
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• 제31권5호
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• pp.763-772
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• 2018

Objective: Swine manure in Korea is separated into solid and liquid phases which are composted separately and then applied on land. The nutrient accumulation in soil has been a big issue in Korea but the basic investigation about nutrient input on arable land has not been achieved in detail. Within the nutrient production from livestock at the national level, most values are calculated by multiplication of the number of animals with the excreta unit per animal. However, the actual amount of nutrients from swine manure may be totally different with the nutrients applied to soil since livestock breeding systems are not the same with each country. Methods: This study investigated 15 farms producing solid compost and 14 farms producing liquid compost. Composting for solid phase used the Turning+Aeration (TA) or Turning (T) only methods, while liquid phase aeration composting was achieved by continuous (CA), intermittent (IA), or no aeration (NA). Three scenarios were constructed for investigating solid compost: i) farm investigation, ii) reference study, and iii) theoretical P changes (${\Delta}P=0$), whereas an experiment for water evaporation was conducted for analyzing liquid compost. Results: In farm investigation, weight loss rates of 62% and 63% were obtained for TA and T, respectively, while evaporation rates for liquid compost were 8.75, 7.27, and $5.14L/m^2{\cdot}d$ for CA, IA, and NA, respectively. Farm investigation provided with the combined nutrient load (solid+liquid) of VS, N, and P of 117.6, 7.2, and $2.7kg/head{\cdot}yr$. Nutrient load calculated from farm investigation is about two times higher than the calculated with reference documents. Conclusion: The nutrient loading coefficients from one swine (solid+liquid) were (volatile solids, 0.79; nitrogen, 0.53; phosphorus, 0.71) with nutrient loss of 21%, 47%, and 29%, respectively. The nutrient count from livestock manure using the excretion unit has probably been overestimated without consideration of the nutrient loss.

• The Korean Journal of Ceramics
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• 제5권3호
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• pp.205-210
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• 1999

The thermodynamic properties and phase diagram of the$ PbO-ZrO_2$ system have been critically assessed using the Thermo-Calc program. Excess Gibbs energies were expressed by Redlich-Kister polynomials for the solid phases, by the two-sublattice ionic liquid model for the liquid phase and by the compound energy model for the solid solution phase. All solid phases were treated as stoichimetric compounds.