• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.492-497
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• 2008

The solubility of carbon dioxide in ionic liquids and amine solvents has been investigated in gas-liquid absorption equilibrium reactor. Absorption capacity and kinetics of $CO_2$ with $CO_2$ pressure and absorption time in 9 different ionic liquids and 2 kinds of amine solvents were evaluated. In order to understand the effect of ionic type, we changed the cation or anion of ionic liquids. $CO_2$ absorption capacity and absorption rate of amine solvents were higher than those of ionic liquids. $CO_2$ absorption capacity of [emim][$Tf_2N$], $0.14molCO_2/mol\;IL$ at 1 bar, was the highest among the ionic liquids. $CO_2$ absorption capacity of ionic liquid steeply decreased with increasing temperature. Anion of ionic liquid dominates interaction with $CO_2$ and cation plays secondary role.

• Clean Technology
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• v.18 no.3
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• pp.229-249
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• 2012

At present, global warming and depletion of fossil fuels have been one of the big issues which should be solved for sustainable development in the future. CCS (carbon capture and sequestration) technology as the post $CO_2$ reduction technology has been considered as a promising solution for global warming due to increased carbon emission. However, the environmental and ecological effects of CCS have drawn concerns. There are needs for noble post reduction technology. More recently, CCU (carbon capture and utilization) Technology, which emphasizes transforming carbon dioxide into value-added chemicals rather than storing it, has been attracted attentions in terms of preventing global warming and recycling the renewable carbon source. In this paper, various technologies developed for carbon dioxide conversion both in gas and liquid phase have been reviewed. For the thermochemical catalysis in gas phase, the development of the catalytic system which can be performed at mild condition and the separation and purification technology with low energy supply is required. For the photochemical conversion in liquid phase, efficient photosensitizers and photocatalysts should be developed, and the photoelectrochemical systems which can utilize solar and electric energy simultaneously are also in development for more efficient carbon dioxide conversion. The energy needed in CCU must be renewable or unutilized one. CCU will be a key connection technology between renewable energy and bio industry development.

• Journal of Environmental Science International
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• v.13 no.3
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• pp.319-325
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• 2004

An experimental study on the preparation of monolithic porous polymers by environmentally friend process in supercritical carbon dioxide has been carried out. Polymerization mixture composed of a cross-linking monomer, initiator and functional co-polymer was charged in the reactor with sapphire window. After the system was purged with a flow of $CO_2$ for 15 min, the reactor was pressurized with liquid $CO_2$ up to 100 bars. The reactor was isolated from and placed back to the system via quick connector for shaking until the mixture had become fully homogeneous. The reactor was then heated and pressurized to the required reaction conditions and left overnight. After cooling and $CO_2$ evacuation, the polymer was removed from the reactor as dry, white, continuous monoliths. The effect of experimental conditions on the physical properties of porous polymer was systematically examined, and it was found that monomer content had a major effect on the physical properties of the polymers.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4635-4642
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• 2013

The advanced absorbent that used amine mixture with different order were developed to separate carbon dioxide emitted from fossil fuel power plant. The carbon dioxide absorption capacity for mixtures with different amine(primary, secondary and tertiary) were investigated according to $CO_2$ partial pressure. The carbon dioxide absorption capacity at the same pressure is ordered as 3DMA1P 30wt%>3DMA1P 27wt%+MEA 3wt%>3DMA1P 27wt%+DEA 3wt%. The result indicates that mixing tertiary amine with primary amine yields more efficient carbon dioxide absorbent than mixing tertiary with secondary amine does. Finally, the predicted semi-empirical gas-liquid equilibrium model fitted with experimental results.

• Atmosphere
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• v.28 no.4
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• pp.393-402
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• 2018

This study investigated future changes in the Arctic permafrost features and related biogeochemical alterations under global warming. The Community Land Model (CLM) with biogeochemistry (BGC) was run for the period 2005 to 2099 with projected future climate based on the Special Report on Emissions Scenarios (SRES) A2 scenario. Under global warming, over the Arctic land except for the permafrost region, the rise in soil temperature led to an increase in soil liquid and decrease in soil ice. Also, the Arctic ground obtained carbon dioxide from the atmosphere due to the increase in photosynthesis of vegetation. On the other hand, over the permafrost region, the microbial respiration was increased due to thawing permafrost, resulting in increased carbon dioxide emissions. Methane emissions associated with total water storage have increased over most of Arctic land, especially in the permafrost region. Methane releases were predicted to be greatly increased especially near the rivers and lakes associated with an increased chance of flooding. In conclusion, at the end of $21^{st}$ century, except for permafrost region, the Arctic ground is projected to be the sink of carbon dioxide, and only permafrost region the source of carbon dioxide. This study suggests that thawing permafrost can further to accelerate global warming significantly.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.35-40
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• 2012

In this study, 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate ionic liquid has been synthesized, characterized and tested with respect to carbon dioxide absorption with the aim to use it as advanced absorbent materials in fossil fuel processing. The ionic liquid was synthesized by a one step method, low cost. The thermal and chemical stability of selected ionic liquid has been investigated by DSC, TGA and the structure was verified by $^1H$-NMR spectroscopy. The solubility of carbon dioxide in the methanesulfonate-based ionic liquids were measured using a high-pressure equilibrium apparatus equipped with a variable-volume view cell at 30, 50 and $70^{\circ}C$ and pressure up to 195 bar. The results show that carbon dioxide solubilities of 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate increased with pressure increasing and temperature decreasing, and the carbon dioxide absorption capacity showed 27.6 $CO_2/IL$(g/kg) at $30^{\circ}C$, 13 bar.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.66-69
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• 2006

The idea of $CO_2$ sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect Therefore, in the present study, calculations of the dissolution behavior of $CO_2$ hydrate when liquid carbon dioxide is released at 1,000m and 1,500m in depth are performed. The results show the liquid $CO_2$ injected in the ocean becomes $CO_2$ bubble at between 350m and 500m in depth, and the injection from a moving ship is a more effective method of dissolution than through a fixed pipeline. It so also noted that the ultimate plume generated from $CO_2$ bubbles repeats expansion and shrinking due to the peel ins from a fixed pipeline.

• Transactions of the Korean Society of Mechanical Engineers
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• v.6 no.3
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• pp.261-270
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• 1982

In the previously reported Part I and Part II, the experimental results in the frictional machining under liquid atmospheres to obtain the best surface roughness were showed. In the present study the frictional machining was carried out in gas atmospheres such as air, oxygen, dioxide carbon and argon, and in solid lubricant atmosphere of graphite powder. The results were compared with those of Part I and Part II. The material to be tested and machining conditions were made identical with Part I and Part II. The best surface roughness obtained in the above gas and solid lubricant atmospheres was worse than the liquid atmospheres but the contact pressure to minimize the surface roughness was considerably low. The best surface roughness in the present study was obtained in the atmospheres of dioxide carbon and graphite powder and the worst one was in oxygen and argon gas.

• New & Renewable Energy
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• v.2 no.4 s.8
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• pp.4-11
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• 2006

The idea of $CO_2$ sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of $CO_2$ hydrate when liquid carbon dioxide is released at 1,000m and 1,500m in depth are performed. The results show the liquid $CO_2$ injected in the ocean becomes $CO_2$ bubble at between 350 m in depth, and the injection from a moving ship is a more effective method of dissolution than through a fixed pipeline. It so also noted that the ultimate plume generated from $CO_2$ bubbles repeats expansion and shrinking due to the peeling from a fixed pipeline.

• KSBB Journal
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• v.25 no.4
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• pp.337-343
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• 2010

It has been well known that organic solvents like t-butanol and n-hexane can protect lipases from the inhibition by short-chain alcohols in the enzymatic transesterification. However, use of the organic solvents should be minimized considering their negative effects on environment and human health. Therefore, use of the greener solvents has been pursued in various are as including the enzymatic biotranformation. In this study, the liquid carbon dioxide ($LCO_2$) was employed as an alternative media for the enzymatic transesterification of canola oil. The conversion in the $LCO_2$ was comparable with those in organic solvents and the supercritical carbon dioxide, and under optimum conditions, the value reached 99.7%. It is expected that this method can provide a new type of biodiesel production process with higher energy efficiency and lower environmental impact.