• 제목/요약/키워드: liquid absorption

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Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical inner Tube (1st Report, Characteristics of Absorption) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性) (제(第) 1 보(報), 흡수특성(吸收特性)))

  • Ohm, K.C.;Kashiwagi, T.;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.1-9
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    • 1993
  • Mass transfer coefficients were measured for water vapor absorption into a LiBr-Water solution of 60wt% flowing down an absorber of vertical tube type. The absorber is copper tube of 25mm inner diameter and 1000mm length. The film Reynolds number were varied in the range of 35~130. The solution is fed from the top of the pipe, and the conditions of solution are supercooled liquid and superheated liquid. As results, the flowrates of LiBr solution which takes peak value of average absorption mass flux exist. Mass transfer coefficients decrease with increasing the flowrate of LiBr solution, and the decrease rate in the case of supercooled liquid is large as compared with that in the case of superheated liquid. But the absorption rate of supercooled liquid is decidedly superior to that of superheated liquid.

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Liquid Moisture Management and Surface Properties of the Fabric in Transient Condition (작업복 소재 직물의 액상 수분 전달 특성 및 표면특성 연구)

  • 유신정
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.1
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    • pp.61-70
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    • 2001
  • As important factors determining human sensorial comfort, liquid moisture management and surface properties of heat resistant workwear materials were examined. To figure out liquid moisture management properties of the test materials, absorption capacity, rate of absorption, and evaporation properties were assessed. A modified GATS(Gravimetric Absorbency Testing System) was used to measure the liquid moisture accumulation associated with the wicking of liquid moisture from sweating skin. The GATS procedure measures demand wettability of materials to take up liquid in a direction perpendicular to the fabric surface and it was modified to incorporate a special test cell and cover to assess absorption behavior in the presence of evaporation. Fabric stiffness, smoothness, number and the length of surface fibers, and an estimate of the contact area between the skin and fabric surface were measured to characterize the mechanical and surface properties of the test materials. Also an estimate of the force with which a fabric clings to moist skin was made using as wet-cling index.

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Performance improvement of countercurrent-flow membrane gas absorption in a hollow fiber gas-liquid membrane contactor

  • Ho, Chii-Dong;Sung, Yun-Jen;Chen, Wei-Ting;Tsai, Feng-Chi
    • Membrane and Water Treatment
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    • v.8 no.1
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    • pp.35-50
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    • 2017
  • The theoretical membrane gas absorption module treatments in a hollow fiber gas-liquid membrane contactor using Happel's free surface model were obtained under countercurrent-flow operations. The analytical solutions were obtained using the separated variable method with an orthogonal expansion technique extended in power series. The $CO_2$ concentration in the liquid absorbent, total absorption rate and absorption efficiency were calculated theoretically and experimentally with the liquid absorbent flow rate, gas feed flow rate and initial $CO_2$ concentration in the gas feed as parameters. The improvements in device performance under countercurrent-flow operations to increase the absorption efficiency in a carbon dioxide and nitrogen gas feed mixture using a pure water liquid absorbent were achieved and compared with those in the concurrent-flow operation. Both good qualitative and quantitative agreements were achieved between the experimental results and theoretical predictions for countercurrent flow in a hollow fiber gas-liquid membrane contactor with accuracy of $6.62{\times}10^{-2}{\leq}E{\leq}8.98{\times}10^{-2}$.

Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.35-45
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    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

Effect of PEO viscoelasticity on carbon dioxide absorption in aqueous PEO solution of AMP

  • Park Sang-Wook;Choi Byoung-Sik;Lee Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.17 no.4
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    • pp.199-205
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    • 2005
  • Carbon dioxide was absorbed into aqueous polyethylene oxide (PEO) solution containing AMP in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior of PEO on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP was assumed to be a first-order reaction with respect to the molar concentration of $CO_2$ and AMP respectively. The liquid-side mass transfer coefficient, which was obtained from the dimensionless empirical equation containing the properties of viscoelasticity of the non-Newtonian liquid, was used to estimate the enhancement factor due to chemical reaction. PEO with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid based on the same viscosity of the solution.

A Numerical Model for Heat and Mass Transfer Processes within a Vertical Tube GAX Absorber (수직원관형 GAX 흡수기 내부의 열 및 물질전달과정에 대한 수치모델)

  • 천태식;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.102-111
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    • 2000
  • A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

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Effect of the rheological properties of aqueous xanthan gum solution on chemical absorption of carbon dioxide with diisopropanolamine

  • Son, Young-Sik;Park, Sang-Wook;Park, Dae-Won;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.21 no.2
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    • pp.109-117
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    • 2009
  • Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0~0.15 wt% containing diisopropanolamine (DIPA) of $0{\sim}2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at $25^{\circ}C$ and 101.3 kPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was obtained by the measured physical absorption rate, was correlated with the viscosity and the elastic behavior of XG solution such as Deborah number as an empirical formula. The chemical absorption rate of $CO_2$ ($R_A$), which was estimated by the film theory using the measured $k_La$ and the known kinetics of reaction between $CO_2$ and DIPA, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $k_La$ and $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.

CO2 Absorption in Ionic Liquids (이온성액체를 활용한 이산화탄소 회수)

  • Jeong, Soon Kwan;Kim, Dae Hoon;Baek, Il Hyun;Lee, Si Hyun
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.492-497
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    • 2008
  • The solubility of carbon dioxide in ionic liquids and amine solvents has been investigated in gas-liquid absorption equilibrium reactor. Absorption capacity and kinetics of $CO_2$ with $CO_2$ pressure and absorption time in 9 different ionic liquids and 2 kinds of amine solvents were evaluated. In order to understand the effect of ionic type, we changed the cation or anion of ionic liquids. $CO_2$ absorption capacity and absorption rate of amine solvents were higher than those of ionic liquids. $CO_2$ absorption capacity of [emim][$Tf_2N$], $0.14molCO_2/mol\;IL$ at 1 bar, was the highest among the ionic liquids. $CO_2$ absorption capacity of ionic liquid steeply decreased with increasing temperature. Anion of ionic liquid dominates interaction with $CO_2$ and cation plays secondary role.

Density and Absorption Properties of the Lightweight Material According to the addition ratio of the Powdery and Liquid Type Modified Sulfur (분말형 및 액상형 개질유황의 첨가율에 따른 경량체의 밀도 및 흡수율 특성)

  • Lee, Yong;Kim, Heon-Tae;Bae, Kee-Sun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.158-159
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    • 2015
  • Worldwide refinery industry is a large amount of sulfur is produced by development. what that sulfur, it is produced through the desulfurization process and sulfur recover process. And it is made with the liquid state or solid-state. Also, the trend for structure is being changed from wall construction to rhamen construction. The amount of lightweight panels uesd in rhamen construction is also increasing. Therefore, In this study, it is intended to study density and absorption rate of the blast furnace slag lightweight material by using a sulfur lowered melting point. The plain has highest density and the density is lower when adding modified sulfur more. The plain has the lowest absorption and the absorption is higher according to adding modified sulfur more.

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Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.