• Title/Summary/Keyword: limiting oxygen concentration

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A Study on Dust Explosion Characteristics of Hydroxypropyl Methyl Cellulose (Hydroxypropyl Methyl Cellulose의 분진 폭발특성에 관한 연구)

  • 임우섭;목연수
    • Journal of the Korean Society of Safety
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    • v.15 no.4
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    • pp.95-100
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    • 2000
  • This study was performed in Hartmann type dust explosion apparatus in order to research the dust explosion characteristics of hydroxypropyl methyl cellulose(HPMC): minimum explosive limit, minimum ignition energy, limiting oxygen concentration, maximum explosion pressure, rate of pressure rise, etc. The samples of HPMC dust were distributed into 120-140 mesh, 170-230 mesh and 325 under, and the gap distance of the discharge electrode was setted up at 5mm. The experimental results were obtained as follows: (1) The minimum explosive limit for HPMC dust was founded at 180g/㎥. the minimum ignition energy at 9.8mJ and the limiting oxygen concentration at 12%. (2) The maximum explosion pressure of HPMC dust was $8.1kg/cm^2\;{\cdot}\;$abs at the concentration of $500g/m^3$ and the maximum rate of pressure rise was 203.98 bar/sec at the concentration of $480g/m^3$ for 325 under.

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A Study on The Spontaneous Ignition of a Hydroxy Propyl Methyl Cellulose Dust Cloud (Hydroxy Propyl Methyl Cellulose 분진의 운상자연발화에 관한 연구)

  • Lim, Woo-Sub;Mok, Yun-Soo
    • Journal of the Korean Society of Safety
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    • v.19 no.1
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    • pp.137-140
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    • 2004
  • The minimum ignition temperature at which the dust cloud can spontaneously ignite is considered to be very important in industries to prevent explosion occurring in hot surfaces. This paper has dealt with the experimental study of the determination of minimum ignition temperature of Hydroxy Propyl Methyl Cellulose (HPMC) dust cloud. We have used the Godbert-Greenwald Furnace Apparatus to determine the ignition temperature and limiting oxyten concentration for dust could. The experimental determinations on the minimum ignition temperature were carried out with various particle size with nominal diameters 45, 75 and 106${\mu}m$. The limiting oxygen concentration of dust cloud was determinated for the smaller size(45${\mu}m$) HPMC. Minimum ignition temperature of dust cloud was at 364$^{\circ}C$ for the concentration of 2.5g/L in the air and became higher with the increasing of nitrogen concentration. It was also found that the ignition didn't occur when the oxygen concentration was below 10%, and limiting oxygen concentration is at 11%.

Effects of Pressure and Dissolved Oxygen Concentration on the Activated Sludge (압력 및 용존산소 농도가 활성슬러지에 미치는 영향)

  • 양병수;신현무
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.259-267
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    • 1995
  • This study was conducted to evaluate the effects of pressure and dissolved oxygen concentration on the activated slut비e and to determine the optimum depth of deep shaft process. Some results from this study were summarized as follows. 1. It is considered that low sludge product in the activated sludge system maintaining high dissolved oxygen concentration is attributed to the increase of endogeneous respiration rate caused by the increase of aerobic zone in the sludge floe. 2. The increase of dissolved oxygen concentration does not affect to the increase of organic removal efficiency greatly and therefore the limiting factor is the substrate transfer into the inner part of floe. 3. The yield coefficient, Y is decreased in proportion to the increase of oxygen concentration. In this study, Y values arre ranged from 0.70 to 0.41 according to the variation of dissolved oxygen concentration from 18.0mg/$\ell$ to 258 mg/$\ell$. 4. The optimum depth of deep shaft process should be determined within the limits of non-toxicity to the microorganism and it is about loom in this study.

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A Study on Spontaneous Ignition of Hydroxy Propyl Methyl Cellulose (Hydroxy Propyl Methyl Cellulose의 자연발화에 관한 연구)

  • 최재욱;목연수;하동명
    • Fire Science and Engineering
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    • v.15 no.4
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    • pp.34-40
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    • 2001
  • The spontaneous ignition of hydroxypropyl methyl cellulose(HPMC) was investigated at constant ambient temperature in the oven and minimum ignition temperature of dust clouds with Godbret-Creenwald Furnace respectively, In the experiments of the vessel filled with sample. the larger the vessel was the lower the spontaneous ignition temperature and ambient temperature was calculated from the Frank-Kamenetskii thermal ignition theory. The minimum ignition temperature for the dust cloud state was found under 21% oxygen concentration. At the experiment with the change of oxygen concentration, HPMC was not ignite at 10% $O_2$and so the limiting oxygen concentration was obtained at 10%.

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Effects of Pressure and Dissolved Oxygen Concentration on the Activated Sludge (압력 및 용존산소 농도가 활성슬러지에 미치는 영향)

  • Yang, Byeong-Su;Sin, Hyeon-Mu;Jeong, Hyeong-Suk;Ryu, Dong-Chun;Yun, Jong-Ho;Jeong, Byeong-Gon
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.107-107
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    • 1995
  • This study was conducted to evaluate the effects of pressure and dissolved oxygen concentration on the activated slut비e and to determine the optimum depth of deep shaft process. Some results from this study were summarized as follows. 1. It is considered that low sludge product in the activated sludge system maintaining high dissolved oxygen concentration is attributed to the increase of endogeneous respiration rate caused by the increase of aerobic zone in the sludge floe. 2. The increase of dissolved oxygen concentration does not affect to the increase of organic removal efficiency greatly and therefore the limiting factor is the substrate transfer into the inner part of floe. 3. The yield coefficient, Y is decreased in proportion to the increase of oxygen concentration. In this study, Y values arre ranged from 0.70 to 0.41 according to the variation of dissolved oxygen concentration from 18.0mg/$\ell$ to 258 mg/$\ell$. 4. The optimum depth of deep shaft process should be determined within the limits of non-toxicity to the microorganism and it is about loom in this study.

A study on the whole cell immobilized glucose oxidase from Aspergillus niger

  • Choe, I.S.;Roh, J.K.;Han, M.H.
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1979.10a
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    • pp.245.2-246
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    • 1979
  • Heat treated whole cell of Aspergillus niger containing glucose oxidase-catalase system was entrapped in gelatin matrix crosslinked by glutaral-dehyde. The reaction characteristics of immobilized enzyme was studied in a fludized reactor. Heat treatment enhanced the stability and improved the properties of micellium for the immobilized process. The immobilized enzyme system showed the maximum activity at $35^{\circ}C$ and at pH 5.5. The optimum substrate concentration was 0.04M glucose. The activity of immobilized glucose oxidase was in proportion to the concentration of dissolved oxygen in reaction mixture as other reaction conditions were fixed. It was also demonstrated that the limiting factor for the activity of the immobilized glucose oxidase was the oxygen diffusion resistance which increases proportionally to the glucose concentration.

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Evaluation of Bioremediation Effectiveness by Resolving Rate-Limiting Parameters in Diesel-Contaminated Soil

  • Joo, Choon-Sung;Oh, Young-Sook;Chung, Wook-Jin
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.607-613
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    • 2001
  • The biodegradation rates of diesel oil by a selected diesel-degrading bacterium, Pseudomonas stutzeri strain Y2G1, and microbial consortia composed of combinations of 5 selected diesel-degrading bacterial were determined in liquid and soil systems. The diesel degradation rate by strain Y2G1 linearly increased $(R^2=0.98)$ as the diesel concentration increased up to 12%, and a degradation rate as high as 5.64 g/l/day was obtained. The diesel degradation by strain Y2G1 was significantly affected by several environmental factors, and the optimal conditions for pH, temperature, and moisture content were at pH8, $25^{\circ}C$, and 10%, respectively. In the batch soil microcosm tests, inoculation, especially in the form of a consortium, and the addition of nutrients both significantly enhanced the diesel degradation by a factor of 1.5 and 4, respectively. Aeration of the soil columns effectively accelerated the diesel degradation, and the initial degradation rate was obviously stimulated with the addition of inorganic nutrients. Based on these results, it was concluded that the major rate-limiting factors in the tested diesel-contaminated soil were the presence of inorganic nutrients, oxygen, and diesel-degrading microorganisms. To resolve these limiting parameters, bioremediation strategies were specifically designed for the tested soil, and the successful mitigation of the limiting parameters resulted in an enhancement of the bioremediation efficiency by a factor of 11.

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Limit-current type zirconia oxygen sensor with porous diffusion layer (다공성 확산층을 이용한 한계전류형 지르코니아 산소센서)

  • Oh, Young-Jei;Lee, Chil-Hyoung
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.329-337
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    • 2008
  • Simple, small and portable oxygen sensors were fabricated by tape casting technique. Yttria stabilized zirconia containing cordierite ceramics (YSZC) were used as a porous diffused layer of oxygen in pumping cell. Yttria stabilized zirconia (YSZ) solid electrolyte, YSZC porous diffusion layer and heater-patterned ceramic sheets were prepared by co- firing method. Limit current characteristics and the linear relationship of current to oxygen concentration were observed. Viscosity variation of the slurries both YSZ and YSZC showed a similar behavior, but micro pores in the fired sheet were increased with increasing of the cordierite amount. Molecular diffusion was dominated due to the formation of large pores in porous diffusion layer. The plateau range of limit current in porous-type oxygen sensor was narrow than the one of aperture-type oxygen sensor. However limit current curve was appeared in porous-type oxygen sensor even at the lower applied voltage. The plateau range of limit-current was widen as increasing the thickness of porous diffusion layer of the YSZ containing cordierite. Measuring temperature of $600{\sim}650^{\circ}C$ was recommended for limit-current oxygen sensor. Porous diffusion layer-type oxygen sensor showed faster response than the aperture-type one and was stable up to 30 days running without any crack at interface between the layers.

Statistical Analysis on Water Quality Characteristics of Large Lakes in Korea (우리나라 주요 호소의 수질특성에 대한 통계적 분석)

  • Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.35 no.2
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    • pp.165-180
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    • 2019
  • Water quality data of 81 lakes in Korea, 2013 ~ 2017 were analyzed. Most water quality parameters showed left-skewed distribution, while dissolved oxygen showed normal distribution. pH and dissolved oxygen showed a positive correlation with organic matter and nutrients, which appeared to be a nonsense correlation mediated by the algae. The ratio of $BOD_5$ and $COD_{Mn}$ to CBOD was 21 % and 52 % in the freshwater lakes, respectively. TOC concentration appeared to be underestimated by the UV digestion method, when salinity exceeds $700{\mu}S\;cm^{-1}$. In terms of nitrogen/phosphorus ratio, the limiting factor for algal growth seemed to be phosphorus in most of the lakes. Chlorophyll ${\alpha}$ increased acutely with decrease of N/P ratio. However, it seemed to be a nonsense correlation mediated by phosphorus concentration, since the N/P ratio depended on phosphorus. The N/P ratio of brackish lakes was lower than that of the freshwater, at the same concentration of phosphorus. It is worth examining denitrification that occurs, in bottom layer and sediment, during saline stratification. $Chl.{\alpha}$ concentration decreased in the form of a power function with increase of mean depth. The primary reason is that deep lakes are mainly at the less-disturbed upstream. However, it is necessary to investigate the effect of sediment, on water quality in shallow lakes. Light attenuation in the upper layer, was dominated by tripton (non-algal suspended solids) absorption/scattering (average relative contribution of 39 %), followed by CDOM (colored dissolved organic matter) (average 37 %) and $Chl.{\alpha}$ (average 21 %).

Study on the Charging Characteristics of a Sealed Type Ni-Cd Cell (밀폐식 Ni-Cd 전지의 충전특성에 관한 연구)

  • Yung Woo Park;Chai Won Kim;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.347-352
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    • 1971
  • The variations of the positive and negative electrode potentials, and of internal pressure were measured during the charge of the sealed type Ni-Cd cell. Both polarization characteristics of a paste type Cd-electrode as a gas diffusion electrode in 30% KOH solution and the effects of active carbon electrode as an oxygen consuming auxiliary electrode of the Ni-Cd cell on the charging characteristics of the cell were studied. Peak voltage at the end of charge of the cell is ascribed to the peak at the negative electrode potential, which is due to the concentration polarization by the lack of $Cd^{++}$ ion and oxygen concentration. And the recovery of the negative electrode potential is resulted from depolarization by the increasing diffusion limiting current density with the increasing oxygen pressure. The active carbon electrode was effective as an oxygen consuming auxiliary electrode. The internal pressure of the cell could be maintained below 200mmHg even at one hour rate charge and overcharge by the use of active carbon electrode as an auxiliary electrode.

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