• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.395-402
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• 2010

Mineralogical characterization was performed for the mineral assemblages precipitated at the boundary between limestone bedrock and bat guano deposits in the Gossi Cave, Korea. Francoanellite, taranakite, ardealite, brushite and monetite are observed as phosphate minerals and gypsum and a small amount of barite as sulfate minerals in the guano deposits. With the increase of depth, phosphates are changed as following sequence: taranakite ${\rightarrow}$ francoanellite ${\rightarrow}$ ardealite ${\rightarrow}$ brushite ${\rightarrow}$ monetite. This sequence indicates that the major parameters controlling the physico-chemical conditions under which these mineral assemblages were deposited are pH and relative humidity.

• Journal of the Mineralogical Society of Korea
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• v.28 no.3
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• pp.279-292
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• 2015

New occurrences of large-scaled Zn-Pb deposits are recently found in the Danjang-myeon, Milyang. They are skarn-type deposits which replaced the intercalated limestone beds in the Jeonggaksan Formation. This study aims at characterizing occurrences, mineralogy, and chemistry of Zn-Pb ores and skarn minerals. Skarn orebodies are mainly found in 3 areas, named Gukjeon-ri, Gorye-ri, and Gucheon-ri orebodies, where sphalerite found as main ore mineral in 200-300 m in height and amount of galena increases as altitude does. Ores are dark grey to dark green in color and closely related with clinopyroxene zone. They occur with hedenbergite, grossular, actinolite, epidote, and small amounts of axinite, calcite, and quartz. Main ore mineral is sphalerite which includes tiny spotted grains of galena and chalcopyrite and becomes rich in grade in association with clinopyroxene and epidote. FeS contents in sphalerite show relatively wide range between 1.53 and 23.07 mole%, whose contents intend to increase towards biotite granite known as ore-related igneous rocks. CdS contents are in the range of 0.22-0.93 mole%, showing decrease tendency from southwest (Gukjeon-ri) to northeast (Gucheon-ri). Zn-Pb deposits developed in Danjang-myeon reveal decrease in temperature with increase of altitude, leading to gradual changes in compositions of ore and skarn minerals.

• Economic and Environmental Geology
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• v.17 no.3
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• pp.171-177
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• 1984

Representative sulphide samples from the Sangdong skarn orebody and quartz veins show relatively narrow ranges of sulphur isotope values ranging from $^+5.5$ to $^+6.9$ permil and average $^+5.0$ permil with a standard deviation of 0.77 permil. Much higher temperature isotopic temperatures than homogenization temperatures may indicate even minerals in contact did not form together in isotopic equilibrium. Under conditions of formation of the skarn and quartz veins, ${\delta}^{34}\;H_2S$ ranges from $^+4.5$ to $^+5.3$ permil, suggesting a magmatic origin for the sulphur. Carbon and oxygen isotope values seem to show some of the spread of increasing ${\delta}^{13}C$ values of the interbedded limestone with distance from the central zone of the Sangdong mineralization. Negative values of ${\delta}^{13}C$ fluids appear to be typical of many ore deposits including those of magmatic origin. Calculated ${\delta}^{18}C$ values of the fluids are typical of those derived from magmatic sources.

• Economic and Environmental Geology
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• v.18 no.3
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• pp.205-216
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• 1985

Fluid inclusion study reveals that the mineralogical zonal distribution of the Sangdong skarn orebody may be likely related to (homogenization) temperatures of fluids with time and spaces. Firstly limestone beds were replaced by hot boiling fluids ranging from 350 to $550^{\circ}C$ and formed the pyroxene-garnet skarn, which was replaced into the amphibole and the quartz-mica skarns by non-boiling fluids at 300 to $500^{\circ}C$, mainly penetrated the central part of the pyroxene-garnet skarn orebody. Freezing tests identify presence of $CaCl_2$ and $MaCl_2$ as brines in the fluids besides NaCl and KCL that are shown as daughter minerals and show that two or more fluids be involved in mineralization by showing a bimodal distribution of salinities. This study has contributed to find a new orebody and a granitic pluton as a source rock.

• Journal of the Mineralogical Society of Korea
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• v.22 no.3
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• pp.199-206
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• 2009

The aim of this study is to investigate the relations among each white stone and their characteristics through the chemical and mineralogical analysis of them excavated from around some kilns in archaeological sites. Moreover it was intended to infer the function of kilns. Nine white stones were chosen from three different archaeological sites, the each name of which is Sanyang-ri, Youngdu-ri and Gwangdae-ri in Chungcheongnam-do. In the mineralogical characteristics of thin section, eight stones containing calcite are altered and recrystallized by metasomatism and hydrothermal process, and Calcites, major component minerals of limestone, were identified by the analysis of XRD. On the basis of this result, we can infer the stones to be classified into limestone groups. One the other hand, research revealed that one of the white stones was a white pelitic stone composed of quartz, microcline and muscovite. In the analysis of chemical composition, except for the white pelitic stone eight stones are mainly composed of CaO which is major component of Calcite. Besides, as a results of correlation analysis by using a chemical compositions of major and minor elements in white stones, little did each archaeological site have the relativity. In conclusion, each archaeological site was estimated that they would use a limestone ores extracted from different deposits, and there is a high possibility that the function of these kilns is to produce quicklime.

• Economic and Environmental Geology
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• v.20 no.3
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• pp.179-196
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• 1987

Various skarn ore deposits of Pb-Zn, Fe-Cu, W-Mo and others are widely distributed in the study area which consists mainly of Cambro Ordovician calcareous rocks. The ore deposits are all in close association with specific types of granitic rocks of mid-late Cretaceous age according to the kinds of ores: Fe-Cu deposit with granodiorite-quartz monzodiorite, Pb-Zn deposit with granite-granodiorite, W-Mo deposit with granite, and Mn deposit with quartz porphyry. The granitic rock of Fe-Cu deposit has lower content in K and higher in Ca than those of Pb-Zn deposits. On the contrary, the granitic rock of W-Mo deposit has much higher content in K and lower in Ca in comparison to those of Pb-Zn deposits. However, the granitic rock of Mn deposit shows similar variation to those of Pb-Zn deposits. Lithophile trace elements of Sr and Rb tend to vary in close relation with major elements of K and Ca, respectively. In good contrast, chalcophile elements of Cu, Pb, Zn, Wand Mo are enriched in the granitic rocks of their ore deposits, and other trace elements of Ni and Co show a trend to vary in relation with Mg, Fe and Cu, which have the same replacement index (0.14) as Ni and Co. Average K/Rb and Ca/Sr ratios of the granitic rocks range nearly within 300~150 and 150~40, respectively, and the distribution pattern of the ratios is different according to the kind of ore deposits: Fe-Cu deposit is plotted toward K-Rb poor region whereas Pb-Zn and W-Mo deposits toward K-Rb rich region. In contrast, Fe-Cu and Fe deposits are plotted toward Ca-Sr rich region whereas Pb-Zn deposit toward Ca-Sr poor region. The variation trend of chemical elements of the mid-late Cretaceous granitic rocks in the study area is similar to that of the Cretaceous granitic rocks in the Gyeongsang Basin. Therefore, this geochemical result may be applicable to determining what kinds of ore deposits a Cretaceous granitic rock is favourable for, and whether it is productive or non-productive for systematic geochemical exploration works.

• Economic and Environmental Geology
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• v.16 no.1
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• pp.1-10
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• 1983

The Yeonhwa (I, II) and Keodo mines, neighboring in the middle part of the Taebaegsan mineral belt, contain three distinct classes of skarn deposits: the zinc-lead skarn at Yeonhwa (I, II), the iron skarn at Keodo south (Jangsan orebodies), and the copper skarn at Keodo north (78 orebodies). The present study characterizes the three classes of skarn deposits mainly in terms of skarn/ore associations examined from chemical compositional point of view, and applies existing quantitative phase diagrams to some pertinent mineral assemblages in these mines. At Yeonhwa I the Wolam I orebody shows a vertical variation in skarn minerals ranging from clinopyroxene/garnet zone on the lower levels through clinopyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite veins on the upper levels and surface. Ore minerals, sphalerite and galena, associate most closely with the intermediate clinopyroxene zone. At Keodo, the Jangsan iron skarn hosted in quartz monzodiolite as a typical endoskarn, shows a skarn zoning, from center of orebody to outer side, magnetite zone, magnetite/garnet zone, garnet clinopyroxene zone, and clinopyroxene/epidote/plagioclase zone. The 78 copper skarn in the Hwajeol limestone indicates a zoning, from quartz porphyry side toward limestone side, orthoclase/epidote zone, epidote/clinopyroxene zone, and clinopyroxene/garnet zone; chalcopyrite and other copper sulfides tend to be in clinopyroxene/garnet zone. Mioroprobe analyses of clinopyroxenes and garnets from the various skarn zones mentioned above revealed that the Yeonhwa zinc/lead skarns are characterized by johansenitic clinopyroxene (Hd 25-78, Jo 15-23) and manganoan andraditic garnet (Ad 13-97, Sp 1-24), whereas the Jangsan iron skarn at Keodo by Mn-poor diopsidic clinopyroxene (Di 78-93, Jo 0.2-1.0) and Mn-poor grossularitic grandite (Gr 65-77, Sp 0.5-1.0). The 78 copper skarn at Keodo is characterized by Mn-poor diopsidic-salite (Di 66-91, Jo 0.2-1.1) and Mn-poor andraditic grandite(Ad 40-74, Sp 0.5-1.1). The compositional charateristics of iron, copper, and zinc-lead skarns in the Yeonhwa-Keodo mines are in good correlations with those of the foreign counterparts. Compiling a $T-XCO_2$ phase diagram for the Jangsan endoskarns, a potential upper limit of temperature of the main stage of skarn formation is estimated to be about $530^{\circ}C$, and a lower limit to be $400^{\circ}C$ or below assuming $XCO_2=0.05$ at P total=1kb. Applying a published log $fS_2$-log $fo_2$ diagram to the Keodo 78 and Yeonhwa exoskarns, it is revealed that copper sulfides and zinc-lead sulfides do not co-exist stably below log $fS_2=-4$ and log $fO_2=-23$ at $T=400^{\circ}C$ and ${\times}CO=1$ atm.

• Spatial Information Research
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• v.14 no.1 s.36
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• pp.129-150
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• 2006

Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.376-383
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• 2005

In this study, we conducted geophysical investigations for the organization of integrated geophysical methods to detect underground cavities of ground subsidence area at the field test site, located at Yongweol-ri, Muan-gun. We examined the applicability of geophysical methods such as electrical resistivity, electromagnetic, and microgravity to cavity detection with the aid of borehole survey results. Underground cavities are widely present within the limestone bedrock overlain by the alluvial deposits in the area of the test site where the ground subsidences have occurred in the past. The limestone cavities are mostly filled with groundwater and clays in the test site. Thus, cavities have low electrical resistivity and density compared to the surrounding host bedrock. The results of the study have shown that the zones of low resistivity and density correspond to the zones of the cavities identified in the boreholes at the site, and that the geophysical methods used are very effective to detect underground cavities. Furthermore, we could map the distribution of cavities more precisely with the test results incorporated from the various geophysical methods. It is also important to notice that the microgravity method is a very promising tool since it has rarely used for the cavity detection in korea. Beyond the investigation of underground cavities, the geophysical methods are required to provide useful information for the reinforcement design for the ground subsidence areas. It is, therefore, necessary to develop integrated geophysical technique incorporating different geophysical methods to precisely map underground cavities and image the subsurface of the ground subsidence areas.

• Journal of the Korean association of regional geographers
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• v.8 no.4
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• pp.468-479
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• 2002

This study attempts to characterize Taebaek mountainous region as a natural unit, relating to morphoclimatic milieu and landform development patterns of the mountains of each lithologic type. In the case of granitic mountains of Nothern parts of this region, the slopes presents more or less steep or irregular profile because of abundant microforms of exposed bedrocks and blocks. The development of such landscape is essentially due to differential weathering, associated with difference of joint density. In the case of gneissic mountains, the slopes are well regularized straight steep ones, due not only to generalized superficial weathering but also to massmovement of weathered materials. In the Middle parts of this region, especially in Taegwallyong area, with frequent alternations both of freezing-thawing and of snow accumulation-melting, the roles played by cryo-nival processes proved to be important in weathering of granite as well as in morpho-pedogenesis. In this area, weathered mantle, developed by cryogenic activity under humid condition of nival environment, covered almost all over the slopes. Although Southern parts of this region consist of limestone, on the mountainous volume, distribution of Karst forms are limited while predominate none karst forms such as cockpit type peaks, V-shaped type valleys dissecting steep slopes covered with thin deposits in thickness containing rock debris.