• 제목/요약/키워드: lignin content

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The Effect of Electron Beam Irradiation on Chemical and Morphological Properties of Hansan Ramie Fibers

  • Lee, Jung Soon
    • 한국의류산업학회지
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    • 제15권3호
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    • pp.430-436
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    • 2013
  • The purpose of this study investigates the effects of electron beam(EB) irradiation on the chemical and morphological properties of Hansan ramie fiber. Hansan ramie fibers were irradiated with electron beam doses of 0, 1, 3, 5 and 10kGy. The effect of electron beam irradiation on the chemical components of fibers as well as the surface chemical and morphological properties were investigated using chemical component analysis methods based on TAPPI standards, XPS, and SEM. The results indicate that the surface layers can be removed under suitable EB irradiation doses. Alcohol-benzene extraction and lignin content increases gradually with an increase in EB irradiation and reaching a maximum at an EB dose of 3kGy, and decreases at 10kGy. The surface chemical changes measured by XPS corresponded to the chemical composition analysis results. The C1 peak and the O/C ratio decreased with the removal of the multi-layer and primary layer by EB irradiation. The SEM images show the inter-fibrillar structure etched by EB irradiation up to 5kGy. At 10kGy, the surface structure of the ramie fiber shows highly aligned and distinctive striations in a longitudinal direction. The removal of these exterior layers of the fiber was confirmed by changes in surface morphology as observed in SEM images.

Influence of Sowing and Harvest Date on Yield and Nutritional Quality of Forage Rye

  • Kwon, Byung-Sun;Shin, Dong-Young
    • Plant Resources
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    • 제7권3호
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    • pp.206-210
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    • 2004
  • In order to find out the optimum harvest (dipping) date combined with sowing date on yield and nutrient quality of forage rye which is suitable at the Southern part of Korea, Paldanghomil variety was grown Sep. 2001 to May 2002 at Sunchon National University, and yield and nutrient quality of plant were observed. As harvest date and sowing date were delayed, the plant length was longest, number of leaves per plant was increased in the time of May 20 clipping. Fresh yield was the heaviest in the time of May 20 clipping and Oct. l0 sowing, and the most dry matter yield was the heaviest in the time of May 20 clipping and Oct. 10 sowing. Content of crude protein was the highest and that of crude fiber such as NDF, ADF, hemicellulose, cellulose and lignin were the lowest in the late time of clipping and sowing. Further more IVDMD was high and dry matter yield and digestible dry matter yield were the highest in the time of May 20 dipping and Oct. 10 sowing. Judging from the results reported above, at optimum harvest (dipping) date combined with sowing date for yield and nutrient quality of forage rye seemed to be the time of May 20 clipping and Oct. 10 sowing.

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상백피로부터 분리한 면역세포 증식작용을 지닌 다당체 (Isolation of Lymphocyte Proliferating Polysaccharide from Mori Cortex Radicis)

  • 김철영;이은주;김환묵;허훈
    • 약학회지
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    • 제42권4호
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    • pp.467-471
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    • 1998
  • Numerous efforts have been made to isolate immunologically active component from Mori Cortex Radicis, since it has been used in the treatment of bronchial asthma, and immune dis order in human. Recently, we reported the purification of an anti-allergic component of the Mori Cortex Radicis. Among the fractions we prepared in the previous study, a fraction was active in the proliferation of murine lymphocytes. The active component (HHM 3-1) was elucidated as a polysaccharade with a small amount of lignin. When it was subjected to MALDI-MS by using 3-hydroxypicolinic acid as a matrix, the molecular weight of the component was estimated as 792688.2dalton. Total hexose and protein content of the component were estimated as 62.6% and 0.51%, respectively and it was composed mainly of glucose, galactose and mannose. The remaining part of the component was estimated as ligin because of the characteristic functional groups in IR and UV spectra. Concomitant treatment of HHM 3-1 with known mitogens synergistically increased the proliferation of B-cells and T-cells.

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해양에서 열화된 완도선 수침고목재의 화학적.미시형태적 변화 (Chemical and micromorphological changes of archaeological waterlogged wood degraded in marine situations.)

  • 김익주
    • 보존과학연구
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    • 통권11호
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    • pp.87-105
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    • 1990
  • Chemical and micro morphological changes of archaeological waterlogged woods from shipwrecked materials in marine situations were investigated which were submerged in seabed for over 900 years. Tested Wood species were Pinusdensiflora, Zelkova serrata, Quercus acutissima and Camellia japonica. The obtained results were summarized as follows; Chemical analysis showed that lignin content was increased, whereas the amout of holocellulose was heavily decreased in the degraded archaeological lwoods(DAW), when compared to the recent woods. The amount of alkalineextractives in the DAW was extremley high. IR spectra showed that disappearance of absortion band at $1,730㎝^-1$ intensity increase at 1,600, 1,500 and $1,270㎝^-1$ and the emergence of single band around $1,050㎝^-1$.Microscopic investigation showed that cell wall of latewood tracheids and fiber in the DAW were severely degraded while, early wood tracheids less degraded. Degradation in the cell wall was mainley occurred in $S_2$layer, while the middle lamella was the least degraded. The micro morphological characteristics of DAW were separation of secondary wall from middle lamella, cavities aligned with micro fibril angle in $S_2$layer and granular appearance of secondary wall by the bacterial attack.

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반탄화 과정을 통한 바이오매스의 소수성 개선 연구 (A Study on the Improved the Hydrophobicity of Torrefied Biomass)

  • 정재성;김경민;정현준;김규보;전충환
    • 한국수소및신에너지학회논문집
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    • 제30권1호
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    • pp.49-57
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    • 2019
  • Biomass, a carbon-neutral fuel, has great advantages because it can replace fossil fuels to reduce greenhouse gas emissions. However, due to its low density, high water content, and hydrophilicity, biomass has disadvantages for transportation and storage. To improve these properties, a pretreatment process of biomass is required. One of the various pre-treatment technologies, torrefacion, makes biomass similar to coal through low-temperature pyrolysis. In this study, torrefacion treatment was carried out at 200, 230, 250, 280, and $300^{\circ}C$ for wood pellet, empty fruit bunch (EFB) and kenaf, and the feasibility of replacing coal with fuel was examined. Hygroscopicity tests were conducted to analyze the hydrophobicity of biomass, and its chemical structure changes were investigated using Infrared spectrum analysis. It was confirmed that the hygroscopicity was decreased gradually as the torrefacion temperature increased according to the hygroscopicity tests. The hydrophilicity was reduced according to the pyrolysis of hemicellulose, cellulose, and lignin of biomass.

목질분해균에 의한 인피섬유의 미생물분해 특성 (Characteristics of Microbial Decomposition of Bast Fibers by Wood Rot Fungi)

  • 윤승락;최인규;이재원;김재경
    • 임산에너지
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    • 제20권1호
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    • pp.6-11
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    • 2001
  • 한지의 원료가 되는 닥섬유의 펄프화를 위해 인피부에 목질 분해균을 처리하여 인피섬유의 단섬유화를 위한 미생물의 분해특성과 처리시간별 인피섬유의 분리에 대하여 검토하였다. 판막버섯이나 구름버섯으로 20일간 처리시 중량감소율이 약 50%에 이르러 오히려 이용 가능한 섬유소의 분해도 함께 초래하는 것으로 추정할 수 있다. 그러나 꽃구름버섯이나 벽돌빛뿌리 버섯은 인피섬유의 제일 외피에 존재하는 흑청색 부분을 잘 본해시키고 섬유소 손상을 적게하는 특성을 가진 것으로 나타났다. 꽃구름버섯은 처리 10일째가지 78.9%의 셀룰로오스 함량을 유지하고, 리그닌은 7.2%를 나타내어 제일 양호한 분해 양상을 보였다. 현미경적 관찰의 결과에서는 느타리버섯의 경우 처리 30일부터 인피부의 섬유가 분리되어 단섬유화 되며, 50일간 장기간 처리하여도 섬유표면의 손상은 발견되지 않았다.

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Radial and Circumferential Variations in Hygroscopicity and Diffusion Coefficients within a Tree Disk

  • Kang, Wook;Chung, Woo Yang;Eom, Chang Deuk;Han, Yeon Jung;Yeo, Hwan Myeong;Jung, Hee Suk
    • Journal of the Korean Wood Science and Technology
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    • 제35권2호
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    • pp.29-38
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    • 2007
  • This study was undertaken to investigate the variation of equilibrium moisture content (EMC) in transverse direction and three different directional (longitudinal, radial, and tangential) linear movements, and diffusion coefficients within a tree disc of Korean red pine (pinus densiflora). The EMC gradually increased in heartwood from pith. Therefore, the chemical components might differ even in heartwood and the radial variation in EMC might have a close relationship with the cellulose content within a cross section. The specific gravity increases gradually from pith and the porosity has not direct influence on the variation of EMC within a tree disk. Both the radial and tangential diffusion coefficients exhibited clear trend of increase from pith. The EMC change (${\Delta}EMC$) and tangential diffusion coefficient were close to be axisymmetrical but others were deviated from axisymmetry. The diffusion coefficient decreases with decreasing an activation energy and specific gravity, The diffusion coefficient increased with increasing ${\Delta}EMC$ and hygroscopicity of wood might be inversely proportional to the activation energy, The fJEMC may depend on the chemical constituents of cellulose, hemicellulose and lignin. As the number of sorption sites and sorption capacity of wood increase, therefore, it might be assumed that the hygroscopicity of wood increases while activation energy decreases. Modeling physico-mechanical behavior of wood, the variations should be considered to improve the accuracy.

새로운 사초자원 개발을 위한 Festulolium braunii의 이용에 관한 연구 (Study on the Utilization of Festulolium braunii for the Development of NewForage Resources)

  • 이인덕
    • 한국초지조사료학회지
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    • 제16권1호
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    • pp.27-38
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    • 1996
  • This study was conducted to evaluate the potential of Festulolium braunii(Festuca pratensis Huds. $\times$ Loliurn mulrijZorum Lam.)as forge sources. The experiment was arranged in a split plot design with four replications from Feb. 1995. to Jan. 1996 at Hohenheim university. Main plots consisted of three forage species, Festulolirtrn braunii(Paulita), Lolium multiJomm(Lemtla), and Secale cereale(Halo) and subplots consisted of three maturity, boot, heading, and anthesis. The growth characteristics, DM yields, nutritive value, N and energy balance were observed. The heading date of Festulolium braunii was about two days earlier than that of Loliunz mrtltiflorum, farthermore Fesrulolium braunii retained higher leaf weight ratio(LWR) than other species. Festulolium brarrnii failed to show any significant differences in grass length, number of tillers, LAI, CGR, and DM accumulation when harvested at the same stage of maturity as compare with Loliurn mulriiflorutn or Setale cerede, bur the content of CP, OMD, and mineral elements and NEL value of Festulolium braunii compare to othes were slightly increased(P<0.05), while the content of NDF, ADF, and lignin decreased(P<0.05). The yield of CP was greater for Festulolium braunii than for Lolium multfimm and yields of DOM and NEL per unit area(ha) for Festulolium braunii were greater than for other species(P<0.05). The equivalent or higher DM production and nutritive value are obtained when Festulolium braunii are cut during the period from boot to anthesis stages, therefor DM intake, preference, and N and energy balance were also higher for Festulolirtm braunii compare to for other species. It could be suggested that Lolium multrfirum would be a more suitable substitute to Festuloliron braunii without decreasing forage production and quality, but the substitutive effect of Secale cereale would be difficult because of the maor differences in growth type and period compare to Fesrulolium braunii. From above the results of this experiment it appears that Festulolium braunii have a potential to provide forage sources. but funher research is needed to ascertain their potential under the climate of Korea.

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산양에 의한 초지유형별 목초의 섭취량 및 영양가치 이용성 비교 (A Comparison of Sward Types on the Intake and Nutrients Utilization of Herbage by Korean Native Goats)

  • 이형석;이인덕
    • 한국초지조사료학회지
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    • 제15권4호
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    • pp.297-302
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    • 1995
  • The objective of this experiment was to compare the dry matter intake, nutrients digestibility, nitrogen and energy utilization of hehage among the orchardgrass(OG) pure, orchardgrass(OG)-red clover(RC) mixture and complex rnixtures(C. mix) by Korean native goat. The results obtained were surnmerized as follows: 1. Crude protein(CP) content was higher in OG-RC and C. Mix diets than in OG pure diets(P<0.05). NDF content was higher in OG pure diets than other diets(P<0.05). But ADF, Lignin contents and gross energy did not differ among all diets. 2. Dry matter intake by Korean native goat tend to be high in OG-RC diets, and low in OG pure diets. But there was no significant difference statistically. Dry matter and cellular constituents digestibilities were higher for OG-RC and C. Mix diets than OG pure diet, but CP and NDF digestibilities were no significant difference among diets. 3. The amount of nitrogen consumed amount by Korean native goat in the OG-RC diet was higher than other diets. But, due to largely relative urinary and fecal nitrogen loss, Apparrently digested nitrogen and retained nitrogen percents were not significant difference among diets. 4. The amount of energy consumed by Korean native goat in OG-RC diet was higher than other diets. But, due to largely relative urinary and fecal energy loss, digestable energy percent was lower than C. Mix diets. But.metabolic energy percent was no significant difference among diets. Therefore, there was no significant differences among sward types for the utilization of nitrogen and energy by Korean native goats.

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Comparative Rumen Degradability of Some Legume Forages between Wet and Dry Season in West Sumatra, Indonesia

  • Evitayani, Evitayani;Warly, L.;Fariani, A.;Ichinohe, T.;Abdulrazak, S.A.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제17권8호
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    • pp.1107-1111
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    • 2004
  • An experiment was conducted to evaluate the potential nutritive value of five legume forages (leaves and twigs) in West Sumatra during wet and dry seasons. The chemical composition, in vitro dry matter (IVDMD), organic matter (IVOMD) and crude protein digestibility (IVCPD), in vitro gas characteristics and estimated metabolizable energy (ME) showed variation among legume forages and between different seasons. Crude protein (CP) ranged from 14.2 to 27.8% DM in the wet season, with a significant (p<0.05) reduction in dry season. C. pubescens, G. maculata, L. leucocephala and P. phaseloides showed the least reduction in CP content. The NDF, ADF and lignin were about 39.0, 26.5 and 6.1% DM, respectively in the wet season, and significantly (p<0.05) increased in the dry season, except for NDF of C. mucunoides and C. pubescens. For IVDMD, IVOMD and IVCPD significantly increased in the wet season, but values remained as high as over 50.0% of DM. The in vitro gas characteristics and metabolizable energy were significantly (p<0.05) higher in wet season than the dry season. During both seasons, the rate of constant (c) for G. maculata and ME content for C. pubescens and P. phaseloides were not significantly (p<0.05). Results demonstrated that P. phaseloides and L. leucocephala have a good nutritive value during both wet and dry seasons. Further studies on feeding trials are needed to quantify the animal responses when offered these legume forages.