• Title/Summary/Keyword: light cycle

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Effect of Extraction Solvent on the Separation of Sulfur Components in Light Cycle Oil (접촉분해경유로부터 산화황화합물의 분리에 관한 추출용매의 영향)

  • Park, Su-Jin;Jeong, Kwang-Eun;Chae, Ho-Jeong;Kim, Chul-Ung;Jeong, Soon-Yong;Koo, Kee-Kahb
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.965-970
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    • 2008
  • The separation of sulfone components using light cycle oil(LCO) after oxidation was carried out by solvent extraction method using various polar solvents such as water, n-methyl-2-pyrrolidone(NMP), dimethyl sulfoxide, ethyl acetate, acetonitrile, dimethyl formamide, and methyl alcohol. It was found that phase separation between LCO layer and solvent occurred under mixed solvent adding a proper amount of water. The mixture solvent of NMP and water was a promising extraction solvent due to the selective removal and high distribution coefficient of sulfone component in LCO. 99.5% over of sulfur contents in LCO can be removed by 4 stages equilibrium extraction.

Separation and Purification of 2,6-Dimethylnaphthalene Present in the Fraction of Light Cycle Oil by Crystallization Operation (결정화조작에 의한 접촉분해경유 유분에 함유된 2,6-디메틸나프탈렌의 분리·정제)

  • Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.799-804
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    • 2018
  • The separation and purification of 2,6-dimethylnaphthalene (2,6-DMN) present in the light cycle oil (LCO) fraction was investigated by a crystallization operation. Solute crystallization (SC) was performed using LCO fraction and iso-propyl alcohol as a raw material and a SC solvent, respectively. Increasing the operation temperature and volume ratio of the solvent to the raw material (S/F) resulted in improving the purity of 2,6-DMN, whereas the yield decreased. As a result of the crystallization operation in three steps containing the SC using LCO fraction (13.9% 2,6-DMN) and isopropyl alcohol, the re-crystallization 1 (RC 1) using the crystals recovered by SC and methyl acetate, and RC 2 using the crystals recovered by RC 1 and methyl acetate, the crystal with 99.9% 2,6-DMN was recovered with 19.5% yield. Furthermore, the separation and purification process of 2,6-DMN present in the LCO fraction was reevaluated by using the experimental results obtained through each operations of SC, RC 1, and RC 2.

Developmental characteristics and life cycle of the lawn cutworm, Spodoptera depravata (Lepidoptera: Noctuidae)

  • Jeong, Su Yeon;Lee, Byeong Yeon;Kim, Iksoo
    • International Journal of Industrial Entomology and Biomaterials
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    • v.38 no.2
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    • pp.38-50
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    • 2019
  • We investigated the developmental characteristics and life cycle of the lawn cutworm, Spodoptera depravata (Lepidoptera: Noctuidae), which is one of the most important pests causing economic damage in grass production. For larval culture, we provided the zoysiagrass at $25^{\circ}C$ and $60{\pm}5%$ humidity. The durations of the developmental stages were as follows: $4.11{\pm}0.19$ days for eggs, $25.17{\pm}3.02$ for larvae, $8.80{\pm}0.28$ for pupae, and $7.57{\pm}0.95$ for adults. We grew the larvae to the 7th instar stage, unlike previous studies, in which it was assumed that the 6th instar was the final age. There was a significant positive correlation between the body length and head capsule width of each instar larvae. In terms of morphology, the eggs changed from light green immediately following oviposition to black as they developed, and the grass-fed larvae changed from light yellow immediately after hatching to green as development continued. We observed a pattern of black spots at regular intervals on the dorsal sides of the abdomens of the final instar larvae. Furthermore, we detected two notable designs on the dorsal side of the front of the head. The pupal colors changed from light brown and green immediately after pupation, to dark brown as the pupal cuticle hardened. The wingspans of the adults were similar in both sexes. However, the forewings of the males had obvious outer lines and eyespots with dark gray-brown backgrounds, whereas the corresponding features on the female forewings were less obvious. The oviposition preperiod was 2.11 days, the oviposition period was 4.2 days, the average fecundity per female was approximately 341 eggs, and the hatching rate was approximately 76.1%.

Separation and Purification of 2,6-dimethylnaphthalene in the Light Cycle Oil(I) -Concentration of a mixture of dimethylnaphthalene isomers in the light cycle oil- (접촉분해경유에 함유된 2,6-dimethylnaphthalene의 분리, 정제(I) -접촉분해경유에 함유된 dimethylnaphthalene이성체 혼합물의 농축-)

  • Kim, Su-Jin;Kim, Sang-Chai;Kawasaki, Junjiro
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.162-170
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    • 1996
  • Light cycle Oil(LCO) contains 2,6-dimethylnaphthalene (2,6-DMNA) which is used as the basic material for high performance engineering plastics and liquid crystal polymer. This study was experimentally investigated to concentrate a mixture of dimethylnaphthalene(DMNA) isomers in the LCO by extraction-distillation combination as a pretreatment for separation and purification of 2,6-DMNA in the LCO. Furthermore, concentration of a mixture of DMNA isomers in the LCO compared between distillation and extraction-distillation combination. The recovery of aromatics in the LCO was performed by batch cocurrent multistage extraction with dimethylsulfoxide and water mixture as solvent. The concentration of naphthalene group(carbon number 10-12) in the extracted mixture is higher than that in the LCO. The yield for naphthalene group increased with decreasing carbon number. The yield for a mixture of DMNA isomers obtained in 5 equilibrium extration runs was about 65%. the separation of individual components with extractedmixture was tested by batch distillation. Futhermore, for recovery of a mixture of DMNA isomers of high concentration, distillate containing DMNA was distilled. As a result, a mixture of DMNA isomers with high concentration such as 60wt% was recovered. The extraction-distillation combination was more effective than the distillation to concentration a mixture of DMNA isomer in the LCO.

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Design and Implementation of LED Dimming System with Intelligent Sensor Module

  • Cho, Young Seek;Kwon, Jaerock;Kim, Hwan-Yong
    • Journal of information and communication convergence engineering
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    • v.11 no.4
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    • pp.247-252
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    • 2013
  • An intelligent light emitting diode (LED) dimming system is designed and implemented for energy-saving lighting systems. An LED light bulb is powered by an LED driver controlled by a microcontroller using pulse width modulation (PWM) signals. By changing the duty cycle of the PWM signals, the LED driver generates a driving current of up to 1,000 mA. The current consumption by the LED light bulb exhibits a very linear characteristic that indicates that the level of LED dimming can be finely tuned. Multiple sensors-lighting intensity and ultrasonic range sensors-are combined with the LED dimming system to realize an automatically controllable LED lighting system. The light intensity sensor is capable of sensing ambient light. The ultrasonic range sensor can detect objects from 0.15 to 5.6 m at a resolution of 0.0254 m. The collected information by the light intensity and ultrasonic range sensors is processed by the microcontroller that in turn automatically controls the brightness of the LED light bulb. The algorithm of the software for the LED dimming system is also described.

Improvement of Out-coupling Efficiency of Organic Light Emitting Device by Ion-beam Plasma-treated Plastic Substrate (이온빔 플라즈마 처리된 플라스틱 기판에 의한 OLED의 광추출 효율 향상)

  • Kim, Hyeun Woo;Song, Tae Min;Lee, Hyeong Jun;Jeon, Yongmin;Kwon, Jeong Hyun
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.7-10
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    • 2022
  • A functional polyethylene terephthalate substrate to increase light extraction efficiency of organic light-emitting diodes is studied. We formed nano-structured PET surfaces by controlling the power, gas, and exposure time of the linear ion-beam. The haze of the polyethylene terephthalate can be controlled from 0.2% to 76.0% by changing the peak-to-valley roughness of nano structure by adjusting the exposure cycle. The treated polyethylene terephthalate shows average haze of 76.0%, average total transmittance of 86.6%. The functional PET increases the current efficiency of organic light-emitting diodes by 47% compared to that of organic light-emitting diode on bare polyethylene terephthalate. In addition to polyethylene terephthalate with light extraction performance, by conducting additional research on the development of functional PET with anti-reflection and barrier performance, it will be possible to develop flexible substrates suitable for organic light-emitting diodes lighting and transparent flexible displays.

CORE DESIGN FOR HETEROGENEOUS THORIUM FUEL ASSEMBLIES FOR PWR(1)-NUCLEAR DESIGN AND FUEL CYCLE ECONOMY

  • BAE KANG-MOK;KIM MYUNG-HYUN
    • Nuclear Engineering and Technology
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    • v.37 no.1
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    • pp.91-100
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    • 2005
  • Kyung-hee Thorium Fuel (KTF), a heterogeneous thorium-based seed and blanket design concept for pressurized light water reactors, is being studied as an alternative to enhance proliferation resistance and fuel cycle economics of PWRs. The proliferation resistance characteristics of the KTF assembly design were evaluated through parametric studies using neutronic performance indices such as Bare Critical Mass (BCM), Spontaneous Neutron Source rate (SNS), Thermal Generation rate (TG), and Radio-Toxicity. Also, Fissile Economic Index (FEI), a new index for gauging fuel cycle economy, was suggested and applied to optimize the KTF design. A core loaded with optimized KTF assemblies with a seed-to-blanket ratio of 1: 1 was tested at the Korea Next Generation Reactor (KNGR), ARP-1400. Core design characteristics for cycle length, power distribution, and power peaking were evaluated by HELIOS and MASTER code systems for nine reload cycles. The core calculation results show that the KTF assembly design has nearly the same neutronic performance as those of a conventional $UO_2$ fuel assembly. However, the power peaking factor is relatively higher than that of conventional PWRs as the maximum Fq is 2.69 at the M$9^{th}$ equilibrium cycle while the design limit is 2.58. In order to assess the economic potential of a heterogeneous thorium fuel core, the front-end fuel cycle costs as well as the spent fuel disposal costs were compared with those of a reference PWR fueled with $UO_2$. In the case of comprising back-end fuel cycle cost, the fuel cycle cost of APR-1400 with a KTF assembly is 4.99 mills/KWe-yr, which is lower than that (5.23 mills/KWe-yr) of a conventional PWR. Proliferation resistance potential, BCM, SNS, and TG of a heterogeneous thorium-fueled core are much higher than those of the $UO_2$ core. The once-through fuel cycle application of heterogeneous thorium fuel assemblies demonstrated good competitiveness relative to $UO_2$ in terms of economics.

Optimization of the extraction procedure for quantitative analysis of saponarin and the artificial light condition for saponarin production from barley sprout (고함량 사포나린 함유 보리 어린 순 재배를 위한 식물공장내 인공광 조건 및 사포나린 추출 분석법 최적화)

  • Oh, Kyeong-Yeol;Song, Yeong Hun;Lee, Duek-Yeong;Lee, Tae-Geun;Kim, Jin-Hyo
    • Journal of Applied Biological Chemistry
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    • v.64 no.3
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    • pp.197-203
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    • 2021
  • Saponarin is a crucial component of barley sprout, and the production and quantitative analysis are issued to date. In this study, the optimal saponarin extraction conditions were presented on the subject of acetonitrile, ethanol, methanol, and water for the quantitative analysis in barley sprout through the extraction efficiency compared with the solvent concentration and extraction time using the reaction surface methodology. The optimal extraction time and solvent condition for saponarin were 3.9 h and 53.7% of aqueous methanol, respectively. In addition, the effect of LED artificial light on the saponarin production in barley sprouts was evaluated by the light cycle, light quantity, and light quality. The optimal cultivation conditions under artificial light for the growth of barley sprout and saponarin production were most effectively achieved on 220-320 μmol m-2 s-1 of the light quantity with 8 h day-1 of a daylight cycle under 6500K LED combined with red light. Furthermore, blue light was evaluated as the main factor in the biosynthesis of saponarin.

Efficiency of Equilume light mask on the resumption of early estrous cyclicity and ovulation in Thoroughbred mares

  • Kim, Seongmin;Jung, Heejun;Murphy, Barbara Anne;Yoon, Minjung
    • Journal of Animal Science and Technology
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    • v.64 no.1
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    • pp.1-9
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    • 2022
  • Equilume light masks had no impact on hastening the resumption of estrous cyclicity in mares maintained in outdoor pastures on the mainland of Korea due to the cold weather conditions. Jeju Island is a major horse-breeding site in Korea and is warmer than the mainland during the winter season. Therefore, the primary objective of this study was to explore the efficiency of the Equilume light mask on the resumption of seasonal estrous cycles in Thoroughbred mares on Jeju Island. A total of 20 nonpregnant mares were randomly divided into the Equilume light mask (n = 9) and stable lighting (n =11) groups. The experiment was performed at seven different horse-breeding farms located on Jeju Island from November 15, 2020, to February 15, 2021. The mares were exposed to the respective lights from 16:00 to 23:00. Follicle size and uterine edema were measured by ultrasound scanning. Body condition scores (BCS) were also monitored during the experiment. Statistical analysis was conducted using the SAS and SPSS software, and p-values of < 0.05 were considered statistically significant. Two of the nine (22.2%) mares in the Equilume light mask group and three of the 11 (27.28%) mares in the stable lighting group were still cycling in December and January, which were considered as all-year-round cycling mares. On February 15, there was no difference between groups in the resumption of early seasonal estrus cycle, which was determined by follicles > 25 mm in addition to uterine edema. All mares in the Equilume light mask group and five of the eight mares (62.5%) in the stable lighting group had resumed cycling. Interestingly, six of the seven mares (87.5%) in the Equilume light mask and four of eight mares (50%) in the stable lighting group had already ovulated on February 15 (p > 0.05), as determined by the presence of a recent corpus luteum. No difference was observed in BCS and uterine edema between groups (p > 0.05). In conclusion, the Equilume light mask can be an effective approach to induce early seasonal estrus cycles of mares in Jeju Island, and it also enhances the efficiency of farm management by reducing labor.