• 제목/요약/키워드: lead free

검색결과 1,078건 처리시간 0.028초

저온 동시 소성용 후막 NTC 서미스터의 전기적 특성에 미치는 무연계 프릿트 및 RuO2의 영향 (Effect of lead-free frit and RuO2 on the electrical properties of thick film NTC thermistors for low temperature co-firing)

  • 구본급
    • 한국결정성장학회지
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    • 제31권5호
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    • pp.218-227
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    • 2021
  • 저온 동시 소성용 후막 NTC 서미스터를 Mn1.5Ni0.4Co0.9Cu0.4O4 조성의 NTC 분말과 lead free frit 및 RuO2를 이용하여 제조한 페이스트를 96 % 알루미나 기판 위에 인쇄와 소결을 통해 제조한 후, 이 후막 NTC의 전기적 특성에 미치는 프릿트 및 RuO2의 영향을 연구하였다. 후막 NTC 서미스터의 저항은 동일한 온도에서 소결한 벌크 상에 비해 높게 나타났으나 저항-온도 특성에서 부 저항 온도 특성은 더 명확하게 직선적으로 나타남을 알 수 있었다. 한편, 소결온도 증가에 따라 면적저항은 감소하였고 프릿트 첨가량이 많을수록 면적저항은 높게 나타났다. 후막 NTC 서미스터의 B 정수는 3000 K 이상의 값 나타냈는데 그 중 프릿트를 5 wt% 첨가한 페이스트로 만든 후막 NTC를 900℃에서 소결한 시편의 B 정수가 가장 높게 나타남을 알 수 있었다. 또한, RuO2 첨가에 따라 면적저항의 감소가 나타남을 알 수 있었으며 RuO2를 5 wt% 첨가한 페이스트를 900℃에서 소결한 후막 NTC 서미스터의 면적저항 감소의 변화가 가장 뚜렷이 나타남을 알 수 있었다.

Bi0.5Na0.5TiO3-BiFeO3-SrTiO3 삼성분계 무연 압전 세라믹스의 강유전체-완화형 강유전체 상전이 거동 (Ferroelectric to Relaxor Transition Behavior in Lead-Free Ternary (Bi0.5Na0.5)TiO3-BiFeO3-SrTiO3 Piezoceramics)

  • 이상섭;이창헌;즈엉 짱 안;웬 호앙 티엔 코이;한형수;이재신
    • 한국전기전자재료학회논문지
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    • 제34권1호
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    • pp.1-7
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    • 2021
  • This study investigated the structural, dielectric, ferroelectric, and strain properties of (0.98-x)Bi1/2Na1/2TiO3-0.02BiFeO3-xSrTiO3 (BNT-BF-100xST, x=0.20, 0.22, 0.24, 0.26, and 0.28). All samples were successfully synthesized using the conventional solid-state reaction method and sintered at 1,175℃ for 2 h. The average grain size of the BNT-BF-100x ceramics decreased with increasing ST content. Furthermore, we observed that the ferroelectric- relaxor transition temperature (TF-R) decreased with increasing ST content, which eventually vanished in the BNT-BF-24ST ceramics. The results indicated that a ferroelectric to relaxor phase transition could be induced by ST modification. Consequently, a large electromechanical strain of 633 pm/V at 4 kV/mm was observed for the BNT-BF-26ST ceramics. These results imply that our materials have the competitive advantage of larger strain under lower operating field conditions compared with other BNT-based lead-free piezoelectric ceramics. We expect that BNT-BF-ST lead-free piezoelectric ceramics are promising candidates as a novel ternary BNT-based system and can find potential applications in actuators.

비스무스계 무연 압전 세라믹스의 상전이 거동 및 전기 기계적 변형 특성에 대한 La2O3 도핑 효과 연구 (Effects of La2O3 Doping on Phase Transition Behavior and Electromechanical Strain Properties in Bismuth-Based Lead-Free Piezoelectric Ceramics)

  • 강은서;형성재;강유빈;박민성;즈엉 짱 안;이재신;한형수
    • 한국전기전자재료학회논문지
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    • 제37권4호
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    • pp.457-463
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    • 2024
  • (Bi1/2Na1/2)TiO3(BNT) piezoelectric ceramics are one of the promising materials that can replace Pb(Zr, Ti)O3(PZT) piezoelectric ceramics due to the high electromechanical strain properties. However, it is still difficult to use practical applications because the required electric field for inducing electromechanical strain is relatively higher than that of PZT ceramics. To overcome this problem, it has been intensively studied on doping impurity or modifying other ABO3 for BNT-based piezoelectric ceramics. Therefore, this study investigated the effects of La2O3 doping on the phase transition behavior and electromechanical strain properties in BNT-SrTiO3 (BNT-ST) lead-free piezoelectric ceramics. In the case of the temperature-dependent dielectric properties, it was confirmed that a phase transition from ferroelectrics to relaxors is induced with increasing La2O3 content. As a result, the electromechanical strain properties of BNT-ST ceramics were improved. The highest Smax/Emax value corresponding to 300 pm/V was obtained at 2 mol% La2O3-dopped BNT-ST ceramics. Accordingly, this study successfully demonstrated that La2O3 doping is effective on the inducing phase transition from ferroelectrics to relaxors and the improving electromechanical strain properties of BNT-ST lead-free piezoelectric ceramics.

독립헝 태양광 발전 시스템의 제어 알고리즘에 관한 연구 (The Study of Control Algorithm for Stand alone PV System)

  • 김태엽;정맹화;고권성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 B
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    • pp.1382-1384
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    • 2002
  • The flooded type battery is used for solar lighting system. Because the characteristic of flooded type battery is the short life time, the maintenance cost is high. So the using flooded type battery in this system is inappropriate. The valve regulated lead acid batter.(VRLA) is the maintenance free and cycle service purpose. This paper presents the development of control system and monitoring system to applied VRLA battery for maintenance free and long life time in system.

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THE COLLISION EFFECTS OF THE PARTICLES IN THE ACCRETION DISK

  • Yoo, K.H.
    • 천문학논총
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    • 제11권1호
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    • pp.125-137
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    • 1996
  • The collision of two particles in the accretion disk may lead to be a mechanism of heat generation. By using hydrodynamic equations, the mean free path, the collision frequency and the deflection angle due to the collision of the particles are derived as a function of the mass accretion rate. The mean free path seems to be a smaller fraction compared to the dimension parameter of the system. The radiative flux in the disk is obtained under the influence of the collision of the particles.

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Mandibular Reconstruction with Vascularized Osseous Free Flaps: a Review of the Literature

  • Kim, Bong-Chul;Kim, So-Mi;Nam, Woong;Cha, In-Ho;Kim, Hyung-Jun
    • Asian Pacific Journal of Cancer Prevention
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    • 제13권2호
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    • pp.553-558
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    • 2012
  • Purpose: This article reviews a few of the commonly used types of vascularized osseous free flaps in maxillofacial reconstruction, which still represents the gold standard of restoration. We also discuss the developing concepts in maxillofacial reconstruction. Recent findings: Most of the literature reconfirms the established patterns of reconstruction with the aid of vascularized osseous free flaps. This method of free-tissue transfer is also feasible in cases of osteoradionecrosis or bisphosphonate-related osteonecrosis of the jaw. These flaps are also suitable for prosthetic restoration using osseointegrated dental implants. Summary: Vascularized osseous free flaps still remain the standard of care. Improvements upon the free-tissue transfer method employing vascularized osseous free flaps, such as distraction osteogenesis, tissue engineering, and imaging techniques, currently require further development, but these technologies could lead to improved outcomes of maxillofacial reconstruction in the near future.

CNC machine에 의해 생산 가능한 FCP 크기의 결정요인 (Decision Factors on Free-form Concrete Panel Sizes Produced by CNC Machines)

  • 임지영;이동훈;문유미;김선국
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.204-205
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    • 2015
  • Demands for free-form buildings are on the rise, but such building designs require most cost and longer construction schedule, with less constructability due to challenges in construction member production and installation. FCP production technology has been developed using CNC machine in a bid to resolve the difficulties of member production. Exterior finishing panels of free-form building design must be divided in size and shape that can be produced by CNC machine. To solve this problem, constraints of CNC machine and correlations between CNC machine and panel need to be reviewed. Thus, the purpose of this study is to analyze decision factors on free-form concrete panel sizes produced by CNC machines. Through this study, FCP size can be optimized, which in turn can lead to improved FCP productivity and aesthetical quality of free-form building designs determined by the pattern of exterior finishing panels. CNC machine-enabled free-form concrete panel production technology will apply on site in the future, which will not only maximize the economic benefits of the technology but also support shorter construction schedule and better constructability.

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취성/연성 파괴에 대한 수명예측 모델 및 신뢰성 설계 (Development of Reliability Design Technique and Life Prediction Model for Electronic Components)

  • 김일호;이순복
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1740-1743
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    • 2007
  • In this study, two types of fatigue tests were conducted. First, cyclic bending tests were performed using the micro-bending tester. A four-point bending test method was adopted, because it induces uniform stress fields within a loading span. Second, thermal fatigue tests were conducted using a pseudo power cycling machine which was newly developed for a realistic testing condition. The pseudo-power cycling method makes up for the weak points in a power cycling and a chamber cycling method. Two compositions of solder are tested in all test condition, one is lead-free solder (95.5Sn4.0Ag0.5Cu) and the other is eutectic lead-contained solder (63Sn37Pb). In the cyclic bending test, the solder that exhibits a good reliability can be reversed depending on the load conditions. The lead-contained solders have a longer fatigue life in the region where the applied load is high. On the contrary, the lead-free solder sustained more cyclic loads in the small load region. A similar trend was detected at the thermal cycling test. A three-dimensional finite element analysis model was constructed. A finite element analysis using ABAQUS was performed to extract the applied stress and strain in the solder joints. A constitutive model which includes both creep and plasticity was employed. Thermal fatigue was occurred due to the creep. And plastic deformation is main damage for bending failure. From the inelastic energy dissipation per cycle versus fatigue life curve, it can be found that the bending fatigue life is longer than the thermal fatigue life.

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Properties and Functions of Melanin Pigment from Klebsiella sp. GSK

  • Sajjan, Shrishailnath S.;Anjaneya, O;Kulkarni, Guruprasad B.;Nayak, Anand S.;Mashetty, Suresh B.;Karegoudar, T.B.
    • 한국미생물·생명공학회지
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    • 제41권1호
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    • pp.60-69
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    • 2013
  • Purified melanin pigment from Klebsiella sp. GSK was characterized by thermogravimetric, differential thermal, X-ray diffraction and elemental analysis. This melanin pigment is structurally amorphous in nature. It is thermally stable up to $300^{\circ}C$ and emits a strong exothermic peak at $700^{\circ}C$. Its carbon, hydrogen and nitrogen composition is 47.9%, 6.9% and 12.0%, respectively. It was used to scavenge metal ions and free radicals. After immobilizing the pigment and using it to adsorb copper and lead ions, the metal ion adsorption capacity was evaluated by atomic absorption spectroscopy (AAS) and the identity of melanin functional groups involved in the binding of metal ions was determined by Fourier transform infrared (FT-IR) spectroscopy. Batch adsorption studies showed that 169 mg/g of copper and 280 mg/g of lead were adsorbed onto melanin-alginate beads. The metal ion adsorption capacity of the melanin-alginate beads was relatively significant compared to alginate beads. The metal ion desorption capacity of HCl was greater (81.5% and 99% for copper and lead, respectively) than that of EDTA (80% and 71% for copper and lead, respectively). The ability of the melanin pigment to scavenge free radicals was evaluated by inhibition of the oxidation of 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and was shown to be about 74% and 98%, respectively, compared with standard antioxidants.

솔더 스크랩의 재생을 위한 전처리 공정 (Pretreatment Process for the Reuse of Solder Scrap)

  • 정우광;김병수;이재천
    • 한국재료학회지
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    • 제21권12호
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    • pp.673-678
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    • 2011
  • With an increased production of Printed Circuit Boards (PCBs) in electronic equipment, the consumption of solder alloys is growing globally. Recently, increasing importance of recycling solder scrap has been recognized. Generally, solder scrap contains many impurities such as plastics and other metals. Hazardous components must be eliminated for recycling solder scrap. The present work studied pretreatment for reuse of solder scrap alloys. An experiment was conducted to enhance the cleanliness of solder scrap melt and eliminate impurities, especially lead. Physical separation with sieving and magnetic force was made along with pyrometallurgical methods. A small decrease in lead concentration was found by high temperature treatment of solder scrap melt. The impurities were removed by filtration of the solder scrap melt, which resulted in improvement of the melt cleanliness. A very low concentration of lead was achieved by a zone melting treatment with repeated passage. This study reports on a pretreatment process for the reuse of solder scrap that is lead free.