• Journal of radiological science and technology
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• v.46 no.3
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• pp.187-195
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• 2023

A shield was made by mixing materials such as bismuth(Bi) and barium(Ba) with silicon to evaluate its shielding ability. Bismuth was made into a shield by mixing a bismuth oxide(Bi₂O₃) colloidal solution and a silicon base and applied to a fibrous fabric, and barium was made by mixing lead oxide(PbO) and barium sulfate(BaSO₄) with a silicon curing agent and solidifying it to make a shield. The test was conducted according to the lead equivalent test method for X-ray protective products of the Korean Industrial Standard. The experiment was conducted by increasing the shielding body one by one from the test condition of 60 kVp, 200 mA, 0.1sec and 100 kVp, 200 mA, 0.1 sec. At 60 kVp, 2 lead oxide-barium sulfate shields, 2 bismuth oxide 1.5 mm shields, and 5 bismuth oxide 0.3 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. At 100 kVp, 2 lead oxide-barium sulfate shields and 2 bismuth oxide 1.5 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. It was confirmed that when using 2 pieces of lead oxide-barium sulfate and 1.5 mm of bismuth oxide, respectively, it has shielding ability equivalent to that of lead. Bismuth oxide and lead oxide-barium sulfate are lightweight and have excellent shielding ability, thus they have excellent properties to be used as an apron for radiation protection or other shielding materials.

• Korean Journal of Digital Imaging in Medicine
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• v.12 no.1
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• pp.15-18
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• 2010

Main component of radiography barrier aprons is lead. To manufacture a lead-free barrier sheath, barium sulfate and organic iodine-based chemicals should be mixed with rubber. Barrier capacity was tested in the medical field. To improve adaptation of rubber with the mixture, raw materials went through milling, agitation, and extruding processes. Three sheaths were manufactured with 30%, 80%, and 120% sulfate barium, respectively. This study found 10% lower barrier capacity of lead-free barrier than the traditional lead-containing rubber sheath. Problems, however, were confronted during the agitation and extruding processes. Mixing with rubber was a technically demanding job. Inconsistent depth, problems with thermal processing and dissipation were encountered as well.

• Nuclear Engineering and Technology
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• v.54 no.1
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• pp.318-325
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• 2022

In this study, composites containing undoped and barium-doped Bi₂WO₆:Ba²⁺were investigated for their shielding against diagnostic X-ray. At first, Bi₂WO₆ and barium-doped Bi₂WO₆ were synthesized with different weight percentages of barium oxide through a hydrothermal process. The as-synthesized nanostructures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and Raman spectroscopy (RS). After that, some shields were generated with undoped and barium-doped Bi₂WO₆:Ba²⁺ nanostructure particles incorporated into polyvinyl chloride (PVC) polymer with different thicknesses and 15% weight of the nanostructure. Finally, the prepared samples were exposed to an X-ray tube at 40, 80, and 120 kV voltages, 10 mAs and, 44.5 cm SID (i.e. the distance from the X-ray beam source to the specimen). Linear and mass attenuation coefficients were also calculated for different samples. The results indicated that, among the samples, the one with 7.5 mmol barium-doped Bi₂WO₆ had the most attenuation at the voltage of 40kV, and the attenuation coefficients would increase with an increase in the amount of barium. The samples with 15 and 17.5 mmol barium-doped Bi₂WO₆ had higher attenuation than the others at 80 and 120 kV. Moreover, the half-value layer (HVL), tenth-value layer (TVL) and 0.25 mm lead equivalent thickness were calculated for all the samples. The lowest HVL value was for the sample with 7.5 mmol barium-doped Bi₂WO₆. As the result clearly show, an increment in the barium-doping content leads to a decrease in both HVL and TVL. In every three voltages, 0.25 mm lead equivalent thickness of the barium-doped composites (7.5 mmol and 15 mmol) had less than the other composites. The lowest value of 0.25 mm lead equivalent thickness was 7.5 barium-doped in 40 kV voltage and 15 mmol barium-doped in 80 kV and 120 kV voltages. These results were obtained only for 15% weight of the nanostructure.

• Journal of the Korean Ceramic Society
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• v.22 no.4
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• pp.15-20
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• 1985

$(Ba_{0.5} Pb_{0.5})_{1-x} Nd_x TiO_3$ 중의 $_x(Nd$의 양)를 변화시키면서 격자상수와 전기전도도를 측정하였다 c축과 a축의 비(c/a) 의 극대값은 실온에 있어서 전기전도도의 극대값과 일치하였다. 이것은 Nd원자의 치환위치와 강유 전성의 변화에 의한 것으로 고찰되었다 Curie 온도이하에서는 Nd 첨가량의 증가에 따라 전기전도도의 활성화에너지가 증가하는 경향을 나타내었다 이것은 입경의 감소에 따른 Spontaneous polarization의 저하가 원인으로 고찰되었다 첨가량의 역학을 입계의 potential barrier의 높이와 관련지어 논하였다.

• Journal of the Korean Society of Radiology
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• v.14 no.5
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• pp.627-634
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• 2020

Instead of lead, we intend to develop shielding materials for morphological implementation by mixing barium sulfate, an eco-friendly substance, and PLA filament, a 3D printer material. The environmental substance, barium sulfate powder and PLA filament, a 3D printer material, were used, and the shielding was made with a 3D printer after being fused into an extruder to mix the powder powder of barium sulfate with PLA. To check the mixing ratio of barium sulfate powder and PLA filament, the mixing input was analyzed, and the absorption dose by thickness according to barium sulfate content was obtained to check the shielding function of the mixed shielding. In the evaluation of the mixture of sulfate barium powder particles and PLA filaments, it was mixed in the most appropriate proportion when the content was 30% in the apparent and electron microscopic observation photographs. In the absorption dose results by thickness according to barium sulfate content, the difference between the content of 0% and the content of each % was greatest at 0.5 cm in thickness and the lowest dose value at 3 cm in thickness when the barium content was 30%. In addition, as the barium content began to increase at 30%, the absorbed dose value increased again. Instead of conventional lead, barium sulfate, an eco-friendly substance, could be mixed with PLA, a filament material, to create morphological shielding. Based on this study, it is expected that the mixing ratio of barium to the mixture is the most appropriate 30%, and will be used as the basis for the implementation of morphological shielding using 3D printers in the diagnosis and treatment section.

• Journal of the Korean Society of Radiology
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• v.7 no.6
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• pp.403-408
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• 2013

This study made a tentative estimation of the shielding rate of barium compound by thickness through monte carlo simulation to apply medical radiation shielding products that can replace existing lead. Barium sulfate($BaSO_4$) was used for the shielding material, and thickness of the shielding material specimen was simulated from 0.1 mm to 5 mm by applying $15{\times}15cm^2$ of specimen area, $4.5g/cm^3$ of density of barium sulfate, and $11.34g/cm^3$ density of lead. Entered source was simulated with 10kVp Step in consecutive X-ray energy spectrum(40 kVp ~ 120 kVp). Absorption probability in 40 kVp ~ 60 kVp showed same shielding rate with lead in 3 mm ~ 5 mm of thickness, but it was identified that under 2 mm, the shielding rate was a bit lower than the existing lead shielding material. Also, the shielding rate in 70 kVp ~ 120 kVp energy band showed similar performance as the existing lead shielding material, but it was tentatively estimated as fairly low shielding rate below 0.5 mm. This study estimated the shielding rate of barium compound as the thickness function of x-ray energy band for medical radiation through monte carlo simulation, and made comparative analysis with existing lead. Also, this study intended to verify application validity of the x-ray shielding material for medical radiation of pure barium sulfate. As a result, it was estimated that the shielding effect was 95% higher than the existing lead 1.5 mm in at least 2 mm thickness of barium compound in medical radiation energy band 70 kVp ~ 120 kVp, and this result is considered valid to be provided as a base data in weight lightening production of radiation shielding product for medical radiation.

• Analytical Science and Technology
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• v.19 no.4
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• pp.280-284
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• 2006

The objective of this study is to investigate the removal of heavy metal by using the coprecipitation of barium sulfate. Several parameters governing the efficiency of the coprecipitation method were evaluated by the pH of sample solution, amount of coprecipitant, and addition of sulfide for the removal of As(V), Cd(II), Cr(III), Cr(VI), Cu(II), Hg(II) and Pb(II) metal ions ($10{\mu}g/ml$ each). The coprecipitation was about 80% - 95% only for lead at low pH but under 10% for other ions. The amount of removal was about 95% - 100% for Cd, Hg, Pb, Cu in the all pH range by the addition of sulfide with barium sulfate but As(V) and Cr(III, VI) ions were not affected by the same conditions.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1783-1790
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• 2023

Barium Bismuth Oxide Borate (BBOB) has been synthesized for the first time using solution combustion technique. SEM analysis reveal flower shape of the nanoparticles. The formation of the nanoparticles has been confirmed through XRD & FTIR studies which gives the physical and chemical structure of the novel material. The UV light absorption is observed in the range 200-300 nm. The present study highlights the radiation shielding ability of BBOB for different radiations like X/Gamma rays, Bremsstrauhlung and neutrons. The gamma shielding efficiency is comparable to that of lead in lower energy range and lesser than lead in the higher energy range. The bremsstrauhlung exposure constant is comparably larger for BBOB NPs than that of concrete and steel however it is lesser than that of lead. The beauty of BBOB nanoparticles lies in, high absorption of radiations and low emission of secondary radiations when compared to lead. In addition, the neutron shielding parameters like scattering length, absorption and scattering cross sections of BBOB are found to be much better than lead, steel and concrete. Thus, BBOB nanoparticles are highly efficient in absorbing X/Gamma rays, neutrons and bremsstrauhlung radiations.

• Analytical Science and Technology
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• v.10 no.1
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• pp.31-34
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• 1997

Barium titanyl oxalate which is a precursor of barium titanate has been precipitated at pH 4~5 by a rapid addition of aqueous titanyl oxalate solution to artificial environmental water samples containing equivalent weight of $Ba^{2+}$ ions. Quantitative recoveries of $Cd^{2+}$ and $Pb^{2+}$ from the water samples has been confirmed and found to be usable as a possible method of preconcentration for their determination.

• Journal of radiological science and technology
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• v.33 no.2
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• pp.121-126
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• 2010

Traditionally, lead has been primarily used to shield the radiation in the hospital, because of its soft texture, durability and cost effectiveness. However, lead can be dangerous because of its toxicity when exposed to the human body, and it is classified as a heavy metal like cadmium, mercury, and arsenic etc. In order to compensate its noxious properties on the human body, researchers are trying to develop a radiation shield which has similar shielding efficiency and can also be manufactured in any form. In this study, sulfuric acid barium was mixed with fiber, rubber, and silicon all of which are harmless to the human body, tested, and evaluated for its ability of medical radiation shield. The result of this study showed that the sheet containing silicon and barium has the strongest shielding abilities.