• Title/Summary/Keyword: leaching and contents analysis

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Changes of Hydraulic Conductivity During Desalmization of Reclaimed Tidelands (간척지 토양의 제염과정중 수리전도도의 변화)

  • 구자웅;은종호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.30 no.4
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    • pp.85-93
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    • 1988
  • This laboratory study was carried out in order to produce fundamental data for analyzing salt movement and desalinization effects, using samples of silt loam soil collected in Gyehwado and Daeho reclaimed tidelans, and samples of silty clay loam soil collected in Kimie tideland. Desalinization experiments with gypsum treatment were performed to analyze changes of the hydraulicc conductivity with changes of the soil property and the salt concentration during the desalinization of reclaimed tideland soils by leaching through the subsufface drainage, and correlations between factors infl uencing the reclamation of salt affected soils were analyzed by the statistical method. The results were summarized as follows: 1. The reclaimed tideland soils used in this study were saline-sodic soils with the high exchangeable sodium percentage and the high electrical conductivity. 2. Changes of the hydraulic conductivity with the amount of leaching water and the leaching time elapsed were affected by the amount of gypsum except exchangeable sodium and clay contents. The regression equation between the depth of water leached per unit depth of soil (Dw / Ds : X) or the square root of the leaching time elapsed (T $^1$ $^2$ : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a . bx. 3. The more exchangeable sodium and clay contents regardless of the amount of gypsum, the more the leaching time was required until a given volume of water was leached through the soil profile. The regression analysis showed that the relationship between the depth of water leached per unit depth of soil(Dw /Ds:X) and the square root of the leaching time elapsed(T$^1$$^2$ :Y) could be described by Y=a . Xb. 4. The hydraulic conductivity was influenced to a major degree by the salt concentration provided that the electrical conductivity was below 10 mmhos / cm during the desalinization of reclaimed tideland soils. The regression equation between the relative electrical conductivity ( ECr : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a + b . X-$^1$. 5. In conclusion, the hydraulic conductivity, leaching requirements and the leaching time elapsed can be estimated when the salt concentration decreases to a certain level during the desalinization of reclaimed tidelands, and the results may be applied to the analysis of salt movement and desalinization effects.

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The Effective Recovery of Gold from the Invisible Gold Concentrate Using Microwave-nitric Acid Leaching Method (마이크로웨이브-질산침출방법에 의한 비가시성 금의 회수율 향상)

  • Lee, Jong-Ju;Myung, Eun-Ji;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.3
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    • pp.185-200
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    • 2019
  • This study aimed to liberate gold from invisible gold concentrate (Au = 1,840.00 g/t) through microwave nitric acid leaching experiments. For the purpose, this study conducted microwave-nitric acid leaching experiments and examined nitric acid concentration effect, microwave leaching time effect and sample addition effect. The results of the experiments were as follows: Au (gold) contents were not detected in all of the microwave leaching conditions. In the insoluble-residue, weight loss rate tended to decrease as the nitric acid concentration, microwave leaching time and sample addition increased. In an XRD analysis with solid-residue, it was suggested that gypsum and anglesite were formed due to dissolution of calcite and galena by nitric acid solution. When a fire assay was carried out with insoluble-residue, it was discovered that gold contents of the solid-residue were 1.3 (Au = 2,464.70 g/t) and 28.8 (52,952.80 g/t) times more than those of concentrate. But in the gold contents recovered, a severe gold nugget effect appeared. It is expected that the gold nugget effect will decrease if a sampling method of concentrate is improved in the microwave-nitric acid leaching experiments and filtering paper with smaller pore size is used for leaching solution and burned filter paper is used for sampling in lead-fire assay.

A Study on the Engineering and Environmental Characteristics of Phosphogypsum-Cement-Soil Mixtures (인산석고 시멘트 혼합토의 공학적.환경적 특성 연구)

  • Chang, Dong-Su;Yeon, Kyu-Seok;Kim, Ki-Sung;Ha, Seon-Hyo;Kim, Yong-Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.3
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    • pp.83-91
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    • 2011
  • This study aimed to investigate the engineering and environmental characteristics of phosphogypsum-cement-soil mixtures composed of phosphogypsum, soil, and a small amount of cement was analysed on the basis of the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test, SEM and EDS analysis, XRD analysis and Leaching test. The specimens were manufactured with soil, cement and phosphogypsum. The cement contents was 10 %, and the phosphogypsum contents was 10, 20, 30, and 40 % by the weight of total dry soil. Each specimen was manufactured after curing at constant temperature and humidity room for 3, 7 and 28 days, after which the engineering characteristics of phosphogypsum-cement-soil mixtures were investigated using the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test. The basic data were presented for the application of phosphogypsum-cement-soil mixtures as construction materials. To investigate the environmental characteristics, leaching test was performed and the leaching test results were far below than of regulatory requirement of Waste Management Act in Korea. Therefore the results show that phosphogypsum is environmentally safe and can be used as construction materials in environmental aspect.

A study on Bacterical Leaching of Low-Grade Copper Mineral(III) (저품위 동광석의 세균침출에 관한 연구 3)

  • 이강순;민봉희;장정순
    • Korean Journal of Microbiology
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    • v.11 no.2
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    • pp.69-78
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    • 1973
  • In order to investigate the distribution of an iron-oxidizing bacterium, Ferrobacillus ferrooxidans in Korea, the authors had carried out the chemical and microbiological analysis of mine water. The results obtained were as follows : 1. Ferrobacillus ferrooxidans concerned to leaching was isolated from 10 copper mine water out of 46 sites in Korea. 2. As the results of bacterial oxidation, the contents of sulfuric acid, ferric sulphate and copper in the bacteria-bearing solutions were higher than those in bacteria-free solutions.

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Evaluation for Contents of Contaminants and Leaching Characteristics of Bottom Ash (바텀애쉬의 유해물질 함량 측정 및 용출특성 평가연구)

  • Koh, Taehoon;Lee, Sungjin;Shin, Minho;Kim, Byongsuk;Lee, Jeakeun;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.6
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    • pp.77-83
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    • 2010
  • In this study, we tried to determine any detrimental effects on water quality when bottom ash obtained from a coal-fired power plant intended to be used as a fill material in construction sites. Physical-chemical properties of bottom ash were determined using proximate analysis, elemental analysis, XRD, and XRF. Classification of bottom ash as a waste material and soil contamination due to the use of bottom ash were performed by Korea waste standard leaching test and soil toxicity test, respectively. Results of leaching tests were compared to the regulations for water quality and groundwater quality and no harmful effects on water quality were found. Most of heavy metals in leachate were below detection limits but trace amount of $Cr^{6+}$ was found. However, concentration of $Cr^{6+}$ was below the regulation criteria. Column leaching tests indicated that concentrations of Pb and Zn were slightly higher than regulations but below regulations within 1 PVE, but concentrations of sulfate were 10 times higher than regulation and thus, the required time to reach regulation was almost 8 PVE.

Content and leaching characteristics of non-regulated hazardous substances in waste from the paint industry (국내 도료공정 발생 폐기물 중 미규제 중금속류의 배출특성)

  • Jeong, Seong-Kyeong;Kim, Woo-Il;Kang, Young-Yeul;Kim, Dong-Un;Cho, Yoon-A;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.387-394
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    • 2011
  • This study was performed to investigate the contents and leaching characteristics of hazardous wastes from the paint industry. In order to establish a hazardous waste list, samples from industrial discharge have been analyzed for 8 non-regulated inorganic hazardous substances (i.e., Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples from a total of 64 workplaces, e.g. manufacture, formulation, supply and use (MFSU) of coatings, adhesives, sealants and printing inks processing, have been chosen and analyzed. Contents and leaching tests for inorganic metal species in samples show that the non-regulated hazardous substances satisfy all the criteria, while quantitative analyses reveal that some samples of the discharged wastes exceeded the criteria proposed by NIER (National Instituted of Environmental Research). In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

Mineralogical Transformation of Gold-silver Bearing Sulfide Concentrate by Mechanochemical Activation, and their Gold-silver Leaching with Non-cyanide Solution (기계적-화학적 활성화에 따른 금-은-정광의 광물학적 상변화와 비-시안 용매에 의한 금-은 용출 향상)

  • Kim, Bong-Ju;Cho, Kang-Hee;Oh, Su-Ji;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.3
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    • pp.115-124
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    • 2014
  • In order to leach Au and Ag from gold-silver bearing sulfide concentrate, the sulfide concentrate was ground in a ball mill for a dry pre-treatment and a wet pre-treatment process. Mineralogical studies and thiourea leaching experiments were carried out with the pre-treated sulfide concentrate. The results of the pre-treatment with the concentrate samples showed the mean particle size and iso-electrical potential was smaller in the dry pre-treatment sample than in the concentrate sample, and the contents was lower in the wet pre-treatment sample than in the dry pre-treatment sample. In XRD analysis, amorphous properties were only shown in the wet pretreatment sample. The results of the concentrate sample leaching experiments showed that the best Au, Ag leaching parameters were when the addition of thiourea was at a 1.0 g concentration, ferric sulfate was 1.0 M, sulfuric acid was 2.0 M and the leaching temperature was at $60^{\circ}C$. The Au, Ag leaching rate was always much greater and faster with the wet pre-treatment samples than with the dry pre-treatment samples. Accordingly, it is expected that more Au, Ag can be leached in an eco-friendly methodology using wet pre-treatment. The pre-treatment could be improved with an optimized grinding additive reagent and through researching grinding time in future non-cyanide processes.

Study on Leaching Behavior for Recovery of Ga Metal from LED Scraps (LED 공정스크랩으로부터 Ga 회수를 위한 침출 거동 연구)

  • Park, Kyung-Soo;Swain, Basudev;Kang, Lee Seung;Lee, Chan Gi;Uhm, Sunghyun;Hong, Hyun Seon;Shim, Jong-Gil;Park, Jeung-Jin
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.414-417
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    • 2014
  • LED scraps consisting of highly crystalline GaN and their leaching behavior are comprehensively investigated for hydro-metallurgical recovery of rare metals. Highly stable GaN renders the leaching of the LED scraps extremely difficult in ordinary acidic and basic media. More favorable state can be obtained by way of high temperature solid-gas reaction of GaN-$Na_2CO_3$ powder mixture, ball-milled thoroughly at room temperature and subsequently oxidized under ambient air environment at $1000-1200^{\circ}C$ in a horizontal tube furnace, where GaN was effectively oxidized into gallium oxides. Stoichiometry analysis reveals that GaN is completely transformed into gallium oxides with Ga contents of ~73 wt%. Accordingly, the oxidized powder can be suitably leached to ~96% efficiency in a boiling 4 M HCl solution, experimentally confirming the feasibility of Ga recycling system development.

Heavy matal removal in leaching water from the region buried tungsten tailing (중석광 폐재광미의 매립지에서 나오는 침출수 중의 중금속 제거)

  • Lee, Dong-Hoon;Oh, Sae-Gang;Choi, Choong-Lyeal;Park, Man;Choi, Jyung
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.218-222
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    • 2000
  • Wasted${\cdot}$rested mine areas give lots of effect on around-environmental changes after mining development. Leaching water at reclaimed land has been eluted from the solid components through physical, chemical, biological procedures by waters percolated through reclaimed site. The element analysis of waste tungsten ore tailing, leaching water analysis and removal of heavy metal by zeolite were performed to investigate the influent of acid rain on the released contents of H. M. The heavy metal contents in leaching water were determined to be As $1.21\;{\sim}\;1.54\;ppm$, Pb $0.11\;{\sim}\;0.15\;ppm$ and $SO_4\;^{2-}$ was $302\;{\sim}\;378ppm$. As deionized water and simulated acid rain (pH 3,4) were percolated through columns packed tungsten ore tailing, the amount of Mn, Na, Ca which were dissolved by pH4 solution was higher than those by distilled water. However, W and Mo were eluted easily by high pH solution. The change of heavy metal concentration by column experiment packed zeolite was effective a little because heavy metals were adsorved much more by zeolite.

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Content Analysis of the Elementary Science Textbooks Between USA and Korea for leaching the Returnee Students (귀국학생 지도를 위한 미국과 한국의 초등 과학과 교과서 내용 분석)

  • 한영욱;김대홍
    • Journal of Korean Elementary Science Education
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    • v.21 no.1
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    • pp.1-11
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    • 2002
  • The purpose of the study is to compare and analyze the elementary science textbooks' contents between the United States(Science Horizons) and Korea for teaching the Returnee students. The analyzed contents are the name of chapters, the number of chapters, the page amounts of chapters, the structure of chapters and the studying time of chapters. The results of this study are : 1. Korean science textbook's number is 20. 'Science Horizons' has 6. Korean science textbook's total number of chapter is 58, 'Science Horizons' is 75. Korean science textbook's total number of page is 1,60.3, 'Science Horizons' is 2,106. So 'Science Horizons' has more number of chapter and page than Korean textbooks. 2. The ratio of Korean science textbook's contents is as follows: physical area, 22.4%; chemistry area, 12 1%: biology area, 39.6%; earth science area, 25.9%. But the ratio of 'Science Horizons' science textbook's contents is as follows: physical area,21.3%; chemistry area,4.0%; biology area, 46.7%; earth science area. 28.0%. 3. In case of 'Predicting the Weather' chapter, Korean science textbook has 3 lessons, 17 themes and 11 activities, whereas' Science Horizons' has 5 lessons, 10 themes and 5 activities. 4. The themes or chapters of 'Science Horizons' to propose deeper than Korea are about animals and plants, energy and movement, weather and season. our body, and earth and outer space. In case of Korean textbook are about chemistry area, the rock and volcanic activity and electric circuit. There are some differences between Korean and the United States' elementary science curriculum and textbook's contents. And the returnee students has many troubles to adapt korean science curriculum, textbooks and educational environment,;. Therefore, teachers should know and understand that, and help them.

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