• Journal of the Korean Chemical Society
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• v.11 no.1
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• pp.38-43
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• 1967

In order to explain the positive catalytic action of copper compound for the rate of leaching of zinc sulfide minerals, the electrode and redox potentials of both synthetic and natural sulfides were measured at various conditions of temperatures and pressures. The potentials of Chalcopyrite and copper sulfide were considerably higher than that of zinc sulfide, whereas lead sulfide and Galena had slightly lower potentials than that of zinc sulfide. At elevated temperatures and pressures, the same tendency was obtained. By means of comparing the calculated and measured values of potentials for sulfides, it was suggested that the electrode potentials in acid solution were generated by oxidation of sulfur ion. As a result, it was concluded that the catalytic action of copper compound in the leaching of synthetic zinc sulfide should be arised from the galvanic action between sulfides keeping intimate contact one another in which copper sulfide worked as cathodic and zinc sulfide as anodic part analogous to the metal corrosion under galvanic action.

• Journal of the Korean Chemical Society
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• v.11 no.1
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• pp.33-37
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• 1967

The influence of impurities contained in Marmatite ores on leaching of zinc was investigated. The zinc sulfide having the same crystal structure of natural Sphalerite was prepared by heating the zinc sulfide chemically precipitated, at $650^{\circ}C$ in nitrogen atmosphere. The activation energy of the sample was 25.8 kcal per mole in the leach test when oxygen partial pressure was 5 atm. and the value was exceedingly high compared to that obtained in Marmatite ores. Synthetic zinc sulfides added with small amount of each impurities were treated in same procedure. As a result, it was found that the leaching velocity was accelerated sharply when about 1 percent of $Cu^{++}$ was blended to the sample. Larger amount of iron has also same effect but the effect was minor compared to the copper. The other impurities indicated no appreciable catalytic action.

• Structural Engineering and Mechanics
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• v.86 no.6
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• pp.779-791
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• 2023

Long-termly used in water supply, an underground concrete pipe is easily subjected to the coupled action of pressure loading and flowing water, which can cause the chemo-mechanical damage of the pipe, resulting in its premature failure and lifetime reduction. Based on the leaching characteristics and damage mechanism of concrete pipe, this paper proposes a coupled chemo-mechanical damage and failure model of underground concrete pipe for water supply, including a calcium leaching model, mechanical damage equation and a failure criterion. By using the model, a numerical simulation is performed to analyze the failure process of underground concrete pipe, such as the time-varying calcium concentration in concrete, the thickness variation of pipe wall, the evolution of chemo-mechanical damage, the distribution of concrete stress on the pipe and the lifetime of the pipe. Results show that, the failure of the pipe is a coupled chemo-mechanical damage process companied with calcium leaching. During its damage and failure, the concentrations of calcium phase in concrete decrease obviously with the time, and it can cause an increase in the chemo-mechanical damage of the pipe, while the leaching and abrasion induced by flowing water can lead to the boundary movement and wall thickness reduction of the pipe, and it results in the stress redistribution on the pipe section, a premature failure and lifetime reduction of the pipe.

• Economic and Environmental Geology
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• v.26 no.3
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• pp.421-429
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• 1993

Dissolution reactions of chemical grade zinc sulfide and natural sphalerite were studied in ferric chloride solution as an oxidant. To enhance the leaching reaction, ultrasonic technique was employed in this investigation. For the reaction with pure zinc sulfide, chemical reaction was the rate limiting step in the range of low conversion irrespective of applying ultrasonic wave. And the diffusion through liquid film instead of diffusion through product layer of free sulfur was the rate determining step because ultrasonic vibration removes the product from reaction zone. In the case of sphalerite with the ultrasonic vibrator, it was found that inert mineral layer diffusion was the rate determining step, in which the elemental sulfurs formed were removed by the ultrasonic action. Experimental results showed that the ultrasonic technique proved to be the methods which can significants improve the leaching performance.

• Resources Recycling
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• v.17 no.2
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• pp.30-35
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• 2008

Mixed acidophilic bacteria were approached for leaching of cobalt and lithium from wastes of lithium ion battery industries. The growth substrates for the mixed mesophilic bacteria are elemental sulfur and ferrous ion. Bioleaching of the metal was due to the protonic action of sulfate ion on the metals present in the waste. It was investigated that bioleaching of cobalt was faster than lithium. Bacterial action could leach out about 80 % of cobalt and 20 % of lithium from the solid wastes within 12 days of the experimental period. Higher solid/liquid ratio was found to be detrimental for bacterial growth due to the toxic nature of the metals. At high elemental sulfur concentration, the sulfur powder was observed to be in undissolved form and hence the leaching rate also decreased with increase of sulfur amount.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.5
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• pp.116-124
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• 1996

The purpose of The work described in this paper is to clear up the initial moisture content, specific surface, air drying and freezing-thawing process on liquid limit of clayey soils distributed widely at estuary of three main rivers in the west coast. To this end, a series of tests were conducted on clayey soils samples with natural state and treated state. From the test results, the liquid limit was decreased with decrement of initial moisture content, air drying process, and freezing-thawing cycles and increased with increment of specific surface. The specific surface which influenced on the liquid limit is over $25 m^2$m$^2$/g, and their relationships are well formulated. Air drying process is expected to improve the engineering properties of the soils such the pro-water properties were changed to anti-water proper-ties through lowering of water holding as resulted to incline from A-7-5 to A-5 on the soil classificaction plastic chart. The freezing-thawing process decreased 20% of liquid limit, especially under the first cycle of the behavious, as a result of above mentioned reasons, phase change of soil-water system brought the decrement of specific surface and affected to the liquid limit.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.23 no.3
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• pp.31-46
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• 1978

In order to secure the proper use of herbicides that are frequently used in Korea, the behavior of herbicides in various type of soil were studied. This study includes the variation of phytotoxicity, leaching and movement, and residual activity period of herbicides depending upon the type of soil etc. Experiments were also conducted to establish a guideline for the selection of herbicides according to the type of soil and the proper use of each herbicide in various type of soil in Korea. Experimental results showed that the behavior of herbicides could be characterized based on the series or kind of herbicides and devided into two major groups. One group (nitrofen. CNP, benthiocarb and butachlor) of herbicides showed relatively little crop injury and was very dependable. The action of this group was not remarkably influenced by soil components, rainfall and the quantity of herbicide used with the type of soil that had small adsorption capacity such as most of soil in Korea. The other group(simazine, 2, 4-D. linuron, alachlor and simetryne) showed a wide variation in it's action and retained potentially injurious effect. This group was very susceptable to using condition as well as the type of soil itself. Based on the results of various experiments the disappearance of the residual activity period of major herbicides used in upland and paddy field and the related factors were explained. It is believed that the results of this study can be used as a base for the establishment of a guideline for the proper use of each herbicide and can suggest a direction of developing new herbicides.

• Journal of the Mineralogical Society of Korea
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• v.12 no.1
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• pp.43-53
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• 1999

The medical mineral menas a single mineral or a complex of minerals. It is natural material. using the medical action of he major or the minor elements, and traditional medicine stuff which has been used since long time ago. Jusa, cinnabar as the mineral name, is the product of the hydrothermal process. It is used to relax the body and cure high blood pressure, apoplexy and cardiopathy. Jusais the major component of "An shin hwan" and "Woo hwang chung shim hwan" nowadays because it has such an excellent calm effect. In addition, it is used to cure cancers such as esophageal cancer and gastric cancer. Jusa composed of mercuric sulfide causes mercury poisoning such as Minamata disease. It is dealt with mineralogical property and chemical composition medical stuff in Korea and China, as well asmercury poisoning and medical action of Jusa in this study. In order to predct accumulation of the interior of the body of the major and minor elements in Jusa, leaching experiment of Jusa by artificial gastric juice was done as well as thermodynamic reaction modelling to know concentration of each species of body fluid. The minor elements of 24 species such as As, Pb, Cd, a and Fe by leaching reaction of Jusa and artificial gastric juice were leached. We can know the fact that as is less than 1 ppm, Hg is less than 25 ppm and Cd and m are not detected. In addition, mercury exists as species of Hg2+, HgCl+, HgCl2, HgCl3-, HgCl42-, HgClOH, HgS(H2S)2, Hg(HS)3-, HgS22-, HgOH and Hg(OH)2 by reaction modelling between Jusa and artificial gastric juice. The concentration of sulfide complexes is 24.2 ppm and that of others is less than 10 ppm. According to increasing pH, the concentration of HgS(H2S)2, Hg(HS)3+, HgS22- and Hg(OH)2 increases, whereas the concentration of HgCl+, HgCl2, HgCl3- and HgCl42- decreases. Therefore, Jusa is very useful for the development of new medicine because it is possible to predict formation of the body species and species accumulation on mercury known as a toxic element and concentration changes of toxicity and efficiency.city and efficiency.

• Journal of Environmental Health Sciences
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• v.31 no.6
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• pp.457-466
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• 2005

Industrial plasticizers such as phthalates can induce peroxisome proliferation. A growing concern among environmental and health groups has arisen because phthalates such as di-2-ethy1hexy1 phthalate (DEHP) and DBP may cause hormonal disorders, reproductive toxicity, hepatocellular tumors, genital disorders owing to a capacity to bind estrogen receptors, and a low-dose toxic action during certain periods of fetal development. Phthalate esters are used extensively as a plasticizer for plastic manufacture such as PVC bags and medical devices. This study investigated the effects of leached components from spring water container's cap and seal film. Phthalates, e.g. dimethy1 phthalate (DMP), diethy1 phthalate (DEP), di-n-buty1 phthalate (DBP), benzy1buty1 phthalate (BBP), di-(2-ethy1hexy1) phthalate (DEHP), and bisphenol A (BPA) were measured in the spring water. The bisphenol A was not detected or below the detection limit on the leaching from cap, sealing or spring water. DEHP were detected 90-116 ppb on the leaching from seal after 2 weeks, and 0.48-0.51 ppb from the spring water after I week. BBP were measured from seal within 1 week 25.4-66 ppb and below 0.12 ppb from spring water within 2 days. DMP were detected from seal within 2 weeks 51-68.5 ppb and 0.12 ppb after 2 weeks. DEP were measured from seal within 2 weeks 48.1-141 ppb and the concentrations were increased by the time from 0.10 to 0.31 ppb at spring water. DBP were detected from the seal within 2 weeks 92.3-5100 ppb and the concentration were decreased by the time from 0.24 to 0.10 ppb at spring water. These results indicate that some phthalate esters contaminated with spring water using the intact cap and seal film. It is concluded that the measured levels of phthalates leaching from these materials might in vivo only be slightly less than 1/10 of the LOAEL.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.35 no.3
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• pp.533-544
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• 2015

Unlike the concrete structure built on land, that exposed to the marine environment is greatly degraded in durability due to the exposure to not only the physical action caused by sea wind, tide, and wave, but also the harsh conditions, including the chemical erosion and freeze-thaw which result from $SO_4{^{2-}}$, $Cl^-$ and $Mg^{2+}$ ions in seawater. In the process of the large scaled construction of submerged concrete structures, of course environmental hazardous substance, such as alkaline (pH) and heavy metals, may be leached. Thus, this issue needs to be adequately reviewed and studied. Therefore, this study attempted to develop a CSA (Calcium Sulfo Aluminate) activator using electric arc furnace reducing slags, as well as the eco-friendly concrete for artificial reefs using electric arc furnace oxidizing slag as aggregate for concrete. The strength properties of the eco-friendly concrete exposed to the marine environment were lower than those of the normal concrete by curing 28 days. This suggest that additional studies are needed to improve the early strength of the eco-friendly concrete. With respect to seawater resistance of the eco-friendly concrete, the average strength loss against 1 year of curing days reached 8-9%. the eco-friendly concrete using high volume of ground granulated blast furnace slags and high specific gravity of electronic arc furnace oxidizing slag demonstrated the sufficient usability as a freeze-thaw resistant material. With respect to heavy metal leaching properties of the eco-friendly concrete, heavy metal substances were immobilized by chemical bonding in the curing process through the hydration of concrete. Thus, heavy metal substances were neither identified at or below environmental hazard criteria nor detected, suggesting that the eco-friendly concrete is safe in terms of leaching of hazardous substances.