• Title/Summary/Keyword: leachates

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Characteristics of Perfluorinated Compounds Detected in Landfill Leachates on Jeju Island (제주도 쓰레기매립장 침출수 중 과불화화합물의 검출 특성)

  • Paik, Byeong Cheon;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.30 no.8
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    • pp.673-684
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    • 2021
  • Raw leachates from three landfills and treated leachates from two landfills on Jeju Isalnd were analyzed for ten perfluorinated compounds (PFCs) detected in aquaruc environments. The leachates were collected six times in 2014 and 2015. Among the ten PFCs, three were not detected, namely perfluoroundecanoic acid (PFUnDA), perfluorododecanoic acid (PFDoDA), and perfluorodecane sulfonate (PFDS). The total concentrations of PFCs ranged as 724-3313 ng/L (mean 1999 ng/L) in raw leachates and from less than the limit of quantification (LOQ) to 394 ng/L (mean 133.2 ng/L) in treated leachates. The domonant compounds measured were perfluorooctanoic acid (PFOA) (mean contribution 37.7%) and perfluorobutane sulfonate (PFBS) (mean contribution 38.2%) in raw leachates, and PFOA (mean contribution 40.7%), perfluorohexanoic acid (PFHxA) (mean contribution 27.3%) and PFBS (mean contribution 26.5%) in treated leachates. No significant correlations were observed between total/several individual PFCs and leachate pH and CODCr, which may be due to complex chemical nature of landfill leachates and characteristics of waste and landfills.

Study on Reutilization with Aerobic Microbes of Organic Food Waste Leachates (호기성 미생물을 이용한 음폐수의 처리 및 자원화에 관한 연구)

  • Kang, Bo-Mi;Hwang, Hyeon-Uk;Kim, Ji-Hoon;Yang, Yong-Woon;Kim, Young-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.1
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    • pp.54-59
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    • 2011
  • This test established the bioavailability and sample input by mixing the maintaining the microbial machine parts and food waste leachates in weight of 2:1 as advanced experiment, maintaining the constant temperature, agitating and observing its weight and property change for 60 hours. And, I injected daily the established microbial machine parts and food waste leachates rate, maintained the temperature in the reactor with $55{\sim}65^{\circ}C$, and agitated with constant speed. I studied the recycling possibility of food waste leachates by extracting the sample after 24 hours, verifying its characteristics, and repeating the food waste leachates input and sample extraction for about 40 days. Considering all about the results of this study, I saw that 87.32% of food waste leachates was reduced, and the solid of bluebug or food included in the food waste leachates was decomposed within 24 hrs. pH for 43 days after 9 days of stabilization period was maintained from 3.7~3.9 and the ignition loss from 88.67~87.3%, and the quantity of organic matter from 77.6~80.88%. With the similar result daily maintained, it is considered to progress more the minimization by inputting the future food waste leachates. C/N rate satisfies the less than 25 that is the composting basis within 8 days, maintaining between 13~15, with 2% of salt not exceeded, it is able to recycle as the compost of food waste leachates as based on the composting with no extracted heavy metal content.

Tritium Distribution in Leachates from Domestic Solid Waste Landfills (생활폐기물 매립장 침출수의 삼중수소 분포)

  • Park, Soon Dal;Kim, Jung Suk;Joe, Kih Soo;Kim, Jong Gu;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.251-262
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    • 2004
  • It is for the purpose of investigating the tritium distribution in the leachates, the raw and treated leachates and the condensates of the methane gas, which have occurred from domestic solid waste landfills. Also it aims to measure the tritium distribution level on the colloid size of the leachates, the raw and treated leachates. It was found that the major inorganic contaminants of the leachates were Na, K, Ca, Mg, $NH{_4}^+$-N and $Cl^-$. The mean tritium level of the raw leachates of the investigated 13 landfill sites for 6 months was 17 ~ 1196 TU. It corresponded to a several scores or hundreds of magnitude higher value than that of the normal environmental sample level except for two landfill sites. Also such a high concentration of the tritium was found in the treated leachates and methane gas condensates as well. Nevertheless it is important to emphasize that the tritium level which was found in this research is about 100 times lower than the tritium limit for the drinking water quality. And most of the tritium existed in the dissolved colloid of the leachate of which the colloid size is below $0.45{\mu}m$. Also, according to the tritium analysis results of the leachates after filtration with $0.45{\mu}m$ membrane filter for some landfills, it is likely that some tritium of the leachate would be distributed in a colloid size over $0.45{\mu}m$. In general the relationship between the tritium and other contaminants in the raw leachate was low, but it was relatively high between the tritium and TOC. However, the tritium content in the leachate had no meaningful relationship with the scale, hydrological characteristics and age of the landfill.

Evaluation of Daphniamagna for the Ecotoxicity Assessment of Alkali Leachate from Concrete

  • Choi, Jae Bang;Bae, Sung Min;Shin, Tae Young;Ahn, Ki Yong;Woo, Soo Dong
    • International Journal of Industrial Entomology and Biomaterials
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    • v.26 no.1
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    • pp.41-46
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    • 2013
  • The cladoceran Daphniamagna has been used as an aquatic test species in aquatic toxicology. To evaluate the aquatic toxicity of leachate from concrete, the immobilization of D. magna was observed after treatment of various concentrations of leachate specimens. Reliabilities of the culture condition and the experimental protocol for acute toxicity test were successfully achieved from the standard toxicity test. The leachates were prepared from the mixture of Ordinary Portland Cement (OPC) and pozzolanic admixtures, Pulverised fuel ash (PFA), Ground granulated blast furnace slag (GGBS) and GGBS containing loess. Acute toxicity test showed 100% immobilization of D. magna for OPC or PFA. The leachates from OPC or PFA had high pH 10 to 12. However, GGBS and GGBS containing loess showed less toxicity according to the concentrations. Especially, immobilization was not observed at the concentrations below 12.5% of GGBS containing loess. Also the range of pH for these specimens was 8 to 9. This suggested that the use of loess as the admixture in concrete may be useful to reduce eco-toxicity of leachates from concrete. This our study provided the harmfulness of the alkali leaching from concrete in aquatic environment and the usefulness of D. magna to evaluate the toxicity of leachates from concrete.

Effect of Seed Leachates of 'Vernal' Alfalfa on Inhibition of Alfalfa Germination and Root Growth

  • Chon, Sang-Uk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.2
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    • pp.134-138
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    • 2000
  • Most parts of alfalfa plant have been reported to contain autotoxic substances that inhibit seed germination and early seedling growth, however, the chemical(s) is not still studied much. Effect of seed leachates of 'Vernal' alfalfa (Medicago sativa L.) was evaluated for inhibition of alfalfa germination and root growth through bioassay. Alfalfa seeds were extracted in 1 L deionized water for 1 h after soaking and the leachates caused to reduce root length of alfalfa significantly as the soaking time increased. Crude seeds at 4 g L$L^{-1}$ exudated autotoxins that reduce significantly root length by 34 % compared to the control, when the seeds soaked in deionized water for 24 h. However, the extracts did not affect final germination as well as speed of germination. Extracts from ground seeds significantly reduced speed of germination (GT 50) and root length. The results indicate that release of autotoxic substances from seeds during seed imbibition was increased with increase of soaking time and seed amount, and that autotoxicity was more occurred in ground seeds than in crude seeds.

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Growth of Soil Microorganisms for the Leachates from Leaf Litter (낙엽 세탈액에 따른 토양 미생물의 생장)

  • Kim, Joung-Hee;Lee, Ho-Won
    • The Korean Journal of Ecology
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    • v.12 no.2
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    • pp.67-73
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    • 1989
  • The action and growth of soil microorganisms were studied in accordance with the leachates from leaf litter over the time lapse, and soil properties and species compositions in studied area were investigated. The investigations of soil microorganisms were made through dividing into two groupsbacterial and fungal groups. The abundance of soil microorganisms showed high correlation with organic matter(0.98) and total nitrogen(0.97) of soil. The amount of soil microorganisms was found the highest in litter layer and the next were humus and A layer in order. The bacterial growth rate in leachates from leaf letter was increased continuously by two weeks. The fungal growth rate was increased only for one week and after then it was decreased abruptly.

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Carbon-13 NMR Analysis of Organic Carbons from a Nothern Hardwood Litter and Leachates, Central Maine, U.S.A. (미국(美國) 북부(北部) 활엽수림 litter로부터 발생(發生)되는 유기산(有機酸)의 탄소-13 NMR 분석(分析))

  • Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.81-90
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    • 1993
  • 나무로부터 발생되는 유기물질이 자연상태에서 어떻게 변화되는가를 탄소-13 핵자기 공명 스펙트럼에 의하여 분석하였다. Litter를 구성하는 주요탄소의 형태는 지방족 탄화수소, 탄수화물, 그리고 방향족 탄소들이었으며, 메톡실, 카르복실과 카르보닐형 탄소들은 부후의 정도가 커짐에 따라 리그닌의 농도가 litter 중에서 증가하므로 점차 증가한다. Hydrophobic과 hydrophilic형 유기탄소가 litter의 자연 여과액(leachates)에 많이 존재하며, 그들의 탄소의 구조는 산성, 염기성 그리고 중성으로 분류되었을 때 서로 특이한 탄소의 형태를 갖는다.

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Heavy Metal Contamination in Soils and Groundwater in the Vicinity of the Sindae-dong Waste Disposal Site, Taejon (대전시 신대동 폐기물매립지 주변지역에서의 지하수 및 토양의 중금속오염)

  • 김경웅;손호웅
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.2
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    • pp.85-89
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    • 1994
  • Groundwater and soil contamination by the leak of leachates from the waste disposal site (WDS) is one of the serious environmental problems, and leachates are generally produced by the biogeochmical decomposition and/or precipitation in the WDS. At the Sindae-dong waste disposal site in Taejon, the average Cu, Pb and Zn concentrations in the surrounding soils are higher than those in other Korean soils but these are not high enough to cause any harmful effect to man through the crop plants. Copper, Pb and Zn are not detected in the groundwater samples but the pH of the sample is 5.6 which is not suitable for the drinking water. In contaminated soil samples, the heavy metal concentrations are higher in subsurface soil than in surface soil and it may be influenced by the leachates in groundwater. With the electric resistivity method, the water contains layers are found in contaminated soils and the resistivity values are considerably low because of the dispersion of plume by the leak of leachates. According to the distance from the leak point of leachate, resistivity values increased and heavy metal concentraions in soils decreased due to the reduction of plume.

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Effects of volatile fatty acids on microalgae growth and N, P consumption in the advanced treatment process of digested food waste leachate by mixotrophic microalgae (Mixotrophic microalgae에 의한 음폐수 소화액 고도처리에 있어 유기산이 microalgae의 성장 및 질소, 인 제거에 미치는 영향)

  • Zhang, Shan;Hwan, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.357-362
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    • 2017
  • Acetate, propionate, butyrate are the major soluble volatile fatty acids metabolites of fermented food waste leachates. This work investigate the effects of volatile fatty acid on the growth rate and $NH_4-N$, $PO_4-P$ removal efficiency of mixotrophic microalgae Chlorella vulgaris to treat digested food waste leachates. The results showed that acetate, propionate and butyrate were efficiently utilized by Chlorella vulgaris and microalgae growth was higher than control condition. Similar trends were observed upon $NH_4-N$ and $PO_4-P$ consumption. Volatile fatty acids promoted Chlorella vulgaris growth, and nutrient removal efficiencies were highest when acetate was used, and butyrate and propionate showed second and third. From this work it could be said that using mixotrophic microalgae, in this work Chlorella vulgaris, fermented food waste leachates can be treated with high efficiencies.