• Title/Summary/Keyword: layered structure

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INFLUENCE OF INVESTMENT/CERAMIC INTERACTION LAYER ON INTERFACIAL TOUGHNESS OF BODY CERAMIC BONDED TO LITHIA-BASED CERAMIC

  • Park, Ju-Mi
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.6
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    • pp.683-689
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    • 2006
  • Statement of problem. Interfacial toughness is important in the mechanical property of layered dental ceramics such as core-veneered all-ceramic dental materials. The interfaces between adjacent layers must be strongly bonded to prevent delamination, however the weak interface makes delamination by the growth of lateral cracks along the interface. Purpose. The purpose of this study was to determine the effect of the reaction layer on the interfacial fracture toughness of the core/veneer structure according to the five different divesting. Materials and methods. Thirty five heat-pressed Lithia-based ceramic core bars (IPS Empress 2), $20mm{\times}3mm{\times}2mm$ were made following the five different surface divesting conditions. G1 was no dissolution or sandblasting of the interaction layer. G2 and G3 were dissolved layer with 0.2% HF in an ultrasonic unit for 15min and 30 min. G4 and G5 were dissolved layer for 15min and 30min and then same sandblasting for 60s each. We veneered bilayered ceramic bars, $20mm{\times}2.8mm{\times}3.8mm$(2mm core and 1.8mm veneer), according to the manufacturer's instruction. After polishing the specimens through $1{\mu}m$ alumina, we induced five cracks for each of five groups within the veneer close to interface under an applied indenter load of 19.6N with a Vickers microhardness indenter. Results. The results from Vickers hardness were the percentage of delamination G1:55%, G2:50%, G3:35%, G4:0% and G5:0%. SEM examination showed that the mean thickness of the reaction layer were G1 $93.5{\pm}20.6{\mu}m$, G2 $69.9{\pm}14.3{\mu}m$, G3 $59.2{\pm}20.2{\mu}m$, G4 $0.61{\pm}1.44{\mu}m$ G5 $0{\pm}0{\mu}m$. The mean interfacial delamination crack lengths were G1 $131{\pm}54.5{\mu}m$, G2 $85.2{\pm}51.3{\mu}m$, and G3 $94.9{\pm}81.8{\mu}m$. One-way ANOVA showed that there was no statistically significant difference in interfacial crack length among G1, G2 and G3(p> 0.05). Conclusion. The investment reaction layer played important role at the interfacial toughness of body ceramic bonded to Lithia-based ceramic.

A Study on Nonstoichiometry and Physical Properties of the Mixed Valency Sr$_{1+x}Er _{1-x} FeO _{4-y}$ Ferrite System (혼합원자가 Sr$_{1+x}Er _{1-x} FeO _{4-y}$ 훼라이트계의 비화학양론과 물성연구)

  • Chul Hyun Yo;Kwang Sun Ryu;Mu Sil Pyun;Sung Joo Lee;Joong Gill Choi
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.99-104
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    • 1991
  • Nonstoichiometric solid solutions of Sr$_{1+x}Er _{1-x} FeO _{4-y}$ system (x = 0.00, 0.25, 0.50, 0.75 and 1.00) with layered $K_2NiF_4$ type structure were prepared at 1350$^{\circ}$C under atmospheric pressure. By the analysis of X-ray diffraction, the crystallographic structures of the solid solution of all compositions were found to be pseudo-tetragonal system. Nonstoichiometric chemical formulas have been determined by Mohr salt analysis. It shows that the amount of Fe$^{4+}$ increases with increasing x up to 0.50 and then decreases, and the value of oxygen nonstoichiometry increases with increasing x value. Mixed valency states of Fe$^{3+}$ and Fe$^{4+}$ in the sample were identified again by Mossbauer spectroscopic analysis at 298 K. Electrical conductivity varied within the semiconductivity range of 10-2 ∼ 10-7(${\Omega}$-1cm-1), activation energy for electrical conduction decreased with the increment of the mole ratio of Fe$^{4+}$ or ${\tau}$ value. The conduction mechanism could be explained by the hopping model of the conduction electrons between the valency states of Fe$^{3+}$ and Fe$^{4+}$.

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The Primary Structure Controlled Mineralization in Weolseong Diatreme, Southern Korea (월성(月城) 다이아튜림의 층준(層準)에 따른 광화(鑛化) 현상(現狀))

  • Park, Ki-Hwa;Oh, Mihn-Soo
    • Economic and Environmental Geology
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    • v.20 no.1
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    • pp.19-34
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    • 1987
  • The Nokdong As-Zn deposit, located 28 km south of Kyeongju City, Southern Korea, has been investigated by a deep drilling programme. The mineralized zone is roughly 290m long and 180m wide at surface and is hosted in a pipe diatreme infilled with poor to well bedded felsic volcaniclastics. The diatreme was formed by explosive volcanic activity, of probably early Tertiary age, subsequent hydrothermal alteration and mineralization took place concurrently within stratigraphic layers in diatreme. Coarse volcaniclastics in the center part of the diatreme, together with complex systems of fracturing, acted as pathways for late hydrothermal fluids which caused alteration of volcanic material to sericite, chlorite and carbonate and precipitated ore minerals, quartz and calcite in the voids. Porosity and permeability were key factors in determining which portions of the layered diatreme were mineralized. The lower part of certain layers retained a relatively high porosity and were extensively mineralized. Metallic mineralization, consisting mostly of pyirte, sphalerite and arsenopyrite, is found as disseminations, tuff-breccia filling and veins.

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The Implementable Functions of the CoreNet of a Multi-Valued Single Neuron Network (단층 코어넷 다단입력 인공신경망회로의 함수에 관한 구현가능 연구)

  • Park, Jong Joon
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.593-602
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    • 2014
  • One of the purposes of an artificial neural netowrk(ANNet) is to implement the largest number of functions as possible with the smallest number of nodes and layers. This paper presents a CoreNet which has a multi-leveled input value and a multi-leveled output value with a 2-layered ANNet, which is the basic structure of an ANNet. I have suggested an equation for calculating the capacity of the CoreNet, which has a p-leveled input and a q-leveled output, as $a_{p,q}={\frac{1}{2}}p(p-1)q^2-{\frac{1}{2}}(p-2)(3p-1)q+(p-1)(p-2)$. I've applied this CoreNet into the simulation model 1(5)-1(6), which has 5 levels of an input and 6 levels of an output with no hidden layers. The simulation result of this model gives, the maximum 219 convergences for the number of implementable functions using the cot(${\sqrt{x}}$) input leveling method. I have also shown that, the 27 functions are implementable by the calculation of weight values(w, ${\theta}$) with the multi-threshold lines in the weight space, which are diverged in the simulation results. Therefore the 246 functions are implementable in the 1(5)-1(6) model, and this coincides with the value from the above eqution $a_{5,6}(=246)$. I also show the implementable function numbering method in the weight space.

Cost Effective Remote Subscription scheme for Ubiquitous Convergence IP-based Network (유비쿼터스 컨버젼스 IP 기반 대용량 네트워크에서 비용 절감형 리모트-서브스크립션 기법)

  • Shin, Soo-Young;Yoon, Young-Muk;Park, Soo-Hyun
    • The KIPS Transactions:PartC
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    • v.14C no.1 s.111
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    • pp.95-104
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    • 2007
  • Mobile multimedia services such as TV-call or video streaming are gradually becoming popular in the 3rd or more generation mobile network (IMT-2000). Multimedia traffic is expected to continue increasing into the coming years, and IP technology is considered to be the efficient way of transporting such huge volumes of multimedia traffic. IP-based IMT network platform represents an evolution from IMT-2000. The structure of IP-based IMT network as ubiquitous platform is three-layered model : Middleware including Network Control PlatForm (NCPF) and Service Support PlatForm (SSPF), IP-BackBone (IP-BB), access network including sensor network. Mobility Management (MM) architecture in NCPF is proposed for IP-based IMT network in order to manage routing information and location information separately. The generous existing method of multicast control in IP-based IMT network is Remote Subscription. But Remote Subscription has problem that should be reconstructed whole multicast tree when sender in multicast tree moves to another area. To solve this problem, we propose the way to put Multicast-manager in NCPF.

Precise Estimation of Nonlinear Parameter in Pulse-Like Ultrasonic Signal (펄스형 초음파 신호에서 비선형 파라미터의 정밀 추정)

  • Ha, Job;Jhang, Kyung-Young;Sasaki, Kimio;Tanaka, Hiroaki
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.2
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    • pp.77-83
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    • 2006
  • Ultrasonic nonlinearity has been considered as a solution for the detection of microcracks or interfacial delamination in a layered structure. The distinguished phenomenon in nonlinear ultrasonics is the generation of higher-order harmonic waves during the propagation. Therefore, in order to quantify the nonlinearity, the conventional method measures a parameter defined as the amplitude ratio of a second-order harmonic component and a fundamental frequency component included in the propagated ultrasonic wave signal. However, its application In field inspection is not easy at the present stage because no standard methodology has yet been made to accurately estimate this parameter. Thus, the aim of this paper is to propose an advanced signal processing technique for the precise estimation of a nonlinear ultrasonic parameter, which is based on power spectral and bispectral analysis. The method of estimating power spectrum and bispectrum of the pulse-like ultrasonic wave signal used in the commercial SAM (scanning acoustic microscopy) equipment is especially considered in this study The usefulness of the proposed method Is confirmed by experiments for a Newton ring with a continuous air gap between two glasses and a real semiconductor sample with local delaminations. The results show that the nonlinear parameter obtained tv the proposed method had a good correlation with the delamination.

Nano-scale Design of electrode materials for lithium rechargeable batteries

  • Gang, Gi-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.72-72
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    • 2012
  • Lithium rechargeable batteries have been widely used as key power sources for portable devices for the last couple of decades. Their high energy density and power have allowed the proliferation of ever more complex portable devices such as cellular phones, laptops and PDA's. For larger scale applications, such as batteries in plug-in hybrid electric vehicles (PHEV) or power tools, higher standards of the battery, especially in term of the rate (power) capability and energy density, are required. In PHEV, the materials in the rechargeable battery must be able to charge and discharge (power capability) with sufficient speed to take advantage of regenerative braking and give the desirable power to accelerate the car. The driving mileage of the electric car is simply a function of the energy density of the batteries. Since the successful launch of recent Ni-MH (Nickel Metal Hydride)-based HEVs (Hybrid Electric Vehicles) in the market, there has been intense demand for the high power-capable Li battery with higher energy density and reduced cost to make HEV vehicles more efficient and reduce emissions. However, current Li rechargeable battery technology has to improve significantly to meet the requirements for HEV applications not to mention PHEV. In an effort to design and develop an advanced electrode material with high power and energy for Li rechargeable batteries, we approached to this in two different length scales - Atomic and Nano engineering of materials. In the atomic design of electrode materials, we have combined theoretical investigation using ab initio calculations with experimental realization. Based on fundamental understanding on Li diffusion, polaronic conduction, operating potential, electronic structure and atomic bonding nature of electrode materials by theoretical calculations, we could identify and define the problems of existing electrode materials, suggest possible strategy and experimentally improve the electrochemical property. This approach often leads to a design of completely new compounds with new crystal structures. In this seminar, I will talk about two examples of electrode material study under this approach; $LiNi_{0.5}Mn_{0.5}O_2$ based layered materials and olivine based multi-component systems. In the other scale of approach; nano engineering; the morphology of electrode materials are controlled in nano scales to explore new electrochemical properties arising from the limited length scales and nano scale electrode architecture. Power, energy and cycle stability are demonstrated to be sensitively affected by electrode architecture in nano scales. This part of story will be only given summarized in the talk.

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Experimental Study on the Deformation and Failure Behavior of Tono Granite (토노(Tono) 화강암의 변형 및 파괴거동에 관한 실험적 연구)

  • Choi, Jung-Hae;Chae, Byung-Gon
    • The Journal of Engineering Geology
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    • v.22 no.2
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    • pp.173-183
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    • 2012
  • The nature of surface deformation of Tono granite was investigated using a confocal laser scanning microscope (CLSM) under water-saturated stress relaxation conditions. A new apparatus was developed for this experiment, enabling continuous measurements of stress-strain and simultaneous observations of surface deformation by CLSM. The amounts of grain contact deformation and intra-granular surface deformation were calculated using a finite element method. The results reveal that intense grain contact deformation and intra-granular surface deformation occurred during the period of stress relaxation, and that the intensity of this deformation increased with increasing applied stress. Finite element method (FEM) results show that the strain of grain boundary was greater than strain of inter-granular surface. Contour maps of these local strains were compiled for individual grains and their boundaries, revealing intense deformation at the boundaries between biotite and quartz under compressional stress. This result was a consequence of the mechano-chemical effect of biotite and quartz minerals. Biotite in granite has a layered structure of iron-magnesium-aluminum silicate sheets that are weakly bonded together by layers of potassium ions. In contrast, quartz occurs as stable spherical grains.

Improvement of Durability in Concrete Structures Using CRM (내화학성 적층보강공법(CRM)을 활용한 콘크리트 구조물의 내구성능 향상)

  • Kim, Chun-Ho;Kim, Sang-Doh;Kim, Nam-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.145-152
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    • 2013
  • As a typical construction material, concrete has been used in building all kinds of structures since the late $19^{th}$ century. Although it was recognized to secure durability as long as the regulations on design and construction have been reasonably complied, the trends of life-shortening and deterioration have frequently occurred due to all kinds of the external effects that have been experienced during the procedures of using the structures. To make matters even worse, deterioration of the concrete structures according to deterioration can not be controlled any more. Finally, the reality is that repair and maintenance are necessary in the maintenance aspect of the concrete structure. In this study, CRM(Chemical Resistance of Laminating Reinforcement Method), which had been developed to reinforce the surface of concrete and specially improve chemical resistance performance, has been applied to enhance the existing repairing and maintenance method. Therefore, the result has been drawn with comparison and analysis of the specimens applied with the general repairing and maintenance method and CRM through a variety of durability test in this study. With the result of the test, durability of the specimen applied with CRM has been more improved than the existing repairing and maintenance method, which is judged as because of the laminating effect due to reinforcement of epoxy impregnated of alkali-resistance fiber and double layered fiber reinforced seat.

Surface Wave Method: Focused on Active Method (표면파 탐사: 능동 탐사법을 중심으로)

  • Kim, Bitnarae;Cho, Ahyun;Cho, Sung Oh;Nam, Myung Jin;Pyun, Sukjoon;Hayashi, Koich
    • Geophysics and Geophysical Exploration
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    • v.22 no.4
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    • pp.210-224
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    • 2019
  • Surface wave (SW) surveys, which have been applied to numerous application fields ranging from micro-scale ultrasonic analysis to geological scale analysis, are widely used to monitor near-surface stability. The survey method is basically made through analysis on dispersion of SW propagating along the earth surface, in order to delineate shear velocity structure of subsurface. SW survey data are inverted with assuming one-dimensional (1D) layered-earth in order to recover shear wave velocities of each layer, after being analyzed to make the dispersion curve that shows phase velocity of SW with respect to frequency. This study reviews surface wave surveys with explaining the basic theory including the characteristics of dispersion and the procedure of general data processing. Even though surface wave surveys can be categorized into active and passive methods, this paper focuses only on active surface wave methods which includes continuous SW (CSW), spectral analysis of SW (SASW) and multichannel analysis of SW (MASW). Passive method will be reviewed in the subsequent paper.