• Title/Summary/Keyword: lattice structures

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Temperature and the Interfacial Buffer Layer Effects on the Nanostructure in the Copper (II) Phthalocyanine: Fullerene Bulk Heterojunction

  • Kim, Hyo Jung;Kim, Jang-Joo;Jeon, Taeyeol;Kong, Ki Won;Lee, Hyun Hwi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.275.1-275.1
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    • 2014
  • The effects of the interfacial buffer layer and temperature on the organic bulk heterojunction (BHJ) nanostructures of copper phthalocyanine (CuPc) and fullerene (C60) systems were investigated using real time in-situ x-ray scattering. In the CuPc:C60 BHJ structures, standing-on configured ${\gamma}$-CuPc phase was formed by co-deposition of CuPc and C60. Once formed ${\gamma}$-phase was thermally stable during the annealing upon $180^{\circ}C$. Meanwhile, the insertion of CuI buffer layer prior to deposition of the CuPc:C60 BHJ layer induced lying-down configured CuPc crystals in the BHJ layer. The lying CuPc peak intensity and the lattice parameter were increased by the thermal annealing. This increment of the intensity seemed to be related to the strain at the interface between CuPc:C60 and CuI, which was proportional to the enhancement of the power conversion efficiency of the device.

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Expansion of Multi-wall Carbon Nanotubes and its Lithium Storage Property

  • Ahn, Jung-Ho;Ahn, Jeong-Seok
    • Journal of Powder Materials
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    • v.24 no.4
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    • pp.275-278
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    • 2017
  • In the present work, we apply a technique that has been used for the expansion of graphite to multiwall carbon nanotubes (MWCNT). The nanotubes are rapidly heated for a short duration, followed by immersion in acid solution, so that they undergo expansion. The diameter of the expanded CNTs is 5-10 times larger than that of the as-received nanotubes. This results in considerable swelling of the CNTs and opening of the tube tips, which may facilitate the accessibility of lithium ions into the inner holes and the interstices between the nanotube walls. The Li-ion storage capacity of the expanded nanotubes is measured by using the material as an anode in Li-ion cells. The result show that the discharge capacity of the expanded nanotubes in the first cycle is as high as 2,160 mAh/g, which is about 28% higher than that of the un-treated MWCNT anode. However, the charge/discharge capacity quickly drops in subsequent cycles and finally reaches equilibrium values of ~370 mAh/g. This is possibly due to the destruction of the lattice structures by repeated intercalation of Li ions.

Static Aeroelastic Response of Wing-Structures Accounting for In-Plane Cross-Section Deformation

  • Varello, Alberto;Lamberti, Alessandro;Carrera, Erasmo
    • International Journal of Aeronautical and Space Sciences
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    • v.14 no.4
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    • pp.310-323
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    • 2013
  • In this paper, the aeroelastic static response of flexible wings with arbitrary cross-section geometry via a coupled CUF-XFLR5 approach is presented. Refined structural one-dimensional (1D) models, with a variable order of expansion for the displacement field, are developed on the basis of the Carrera Unified Formulation (CUF), taking into account cross-sectional deformability. A three-dimensional (3D) Panel Method is employed for the aerodynamic analysis, providing more accuracy with respect to the Vortex Lattice Method (VLM). A straight wing with an airfoil cross-section is modeled as a clamped beam, by means of the finite element method (FEM). Numerical results present the variation of wing aerodynamic parameters, and the equilibrium aeroelastic response is evaluated in terms of displacements and in-plane cross-section deformation. Aeroelastic coupled analyses are based on an iterative procedure, as well as a linear coupling approach for different free stream velocities. A convergent trend of displacements and aerodynamic coefficients is achieved as the structural model accuracy increases. Comparisons with 3D finite element solutions prove that an accurate description of the in-plane cross-section deformation is provided by the proposed 1D CUF model, through a significant reduction in computational cost.

Effects of post-annealing ZnO seed layers on structural and optical properties of ZnO nanostructures (씨앗층의 후-열처리가 산화아연 나노구조의 구조적 광학적 성질에 미치는 영향)

  • Kim, So-A-Ram;Nam, Gi-Ung;Park, Hyeong-Gil;Yun, Hyeon-Sik;Kim, Byeong-Gu;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.127-128
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    • 2012
  • ZnO nanostructures were grown by the hydrothermal method on ZnO seed layers post-heated in the range $350-500^{\circ}C$. The effects of the post-heated ZnO seed layers on the structural and optical properties of the ZnO nanostructures were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD) spectroscopy, and photoluminescence (PL) spectroscopy. The average grain sizes in the ZnO seed layers increased with increasing post-heating temperature, and nano-fibrous structures were observed on the surface of the ZnO seed layers post-heated at $450^{\circ}C$. The ZnO seed layers post-heated in the range $350-500^{\circ}C$ affected the residual stress, lattice distortion in the ZnO nanostructures and the intensity, positions, and full widths at half maximum of the 2-theta and PL peaks in the XRD and PL spectra for the ZnO nanostructures.

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A Study on the Holographic Process for Photonic Crystal Fabrication (광자결정 제작을 위한 홀로그라피 공정 연구)

  • Yeo, Jong-Bin;Yun, Sang-Don;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.726-730
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    • 2007
  • Two dimensional photonic crystals (2D PCs) have been fabricated by a double exposure holographic method using a He-Cd laser with a wavelength of 442nm. The arrays of the 2D PCs exhibit variable lattice structures from square to triangle according to a change of rotating angle $({\gamma})$ for double exposure beams. In addition, the period and filling factor of PCs as well as the forms (dot or antidot) could be controlled by experimental conditions. $A l.18-{\mu}m-thick$ resist was spin-coated on Si substrate and the 1st holographic exposure was carried out at incident angle $({\theta})$ of $11^{\circ}$. Then the sample was rotated to ${\gamma}=45^{\circ}{\sim}90^{\circ}$ and the 2nd holographic process was performed at ${\theta}=11^{\circ}$. The variation of diffraction efficiency during the exposure process was observed using a He-Ne laser in real time. The images of 2D PCs prepared were analyzed by SEM and AFM. We believe that the double holographic method is a tool suitable to realize the 2D PCs with a periodic array of large area.

Improvement of the Spin Transfer Induced Switching Effect by Copper and Ruthenium Buffer Layer

  • Nguyen T. Hoang Yen;Yi, Hyun-Jung;Joo, Sung-Jung;Jung, Myung-Hwa;Shin, Kyung-Ho
    • Journal of Magnetics
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    • v.10 no.2
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    • pp.48-51
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    • 2005
  • The spin transfer induced magnetization switching has been reported to occur in magnetic multilayer structures whose scope usually consists of one stack of ferromagnetic / non-ferromagnetic / ferromagnetic (F / N / F) materials. In this work, it is shown that: 1) Copper used as a buffer layer between the free Co and the Au cap-layer can clearly increase the probability to get the spin transfer induced magnetization switching in a simple spin valve Co 11 / Cu 6/ Co 2 (nm); 2) Furthermore, when Ruthenium is simultaneously applied as a buffer layer on the Si-substrate, the critical switching currents can be reduced by $30\%$, and the absolute resistance change delta R $[{\Delta}R]$ of that stack can be enlarged by $35\%$. The enhancement of the spin transfer induced magnetization switching can be ascribed to a lower local stress in the thin Co layer caused by a better lattice match between Co and Cu and the smoothening effect of Ru on the thick Co layer.

Practical second-order analysis and design of single angle trusses by an equivalent imperfection approach

  • Cho, S.H.;Chan, S.L.
    • Steel and Composite Structures
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    • v.5 no.6
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    • pp.443-458
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    • 2005
  • Steel angles are widely used in roof trusses as web and chord members and in lattice towers. Very often angle members are connected eccentrically. As a result, not only an angle member is under an axial force, but it is also subject to a pair of end eccentric moments. Moreover, the connection at each end provides some fixity so neither pinned nor the fixed end represents the reality. Many national design codes allow for the effects due to eccentricities by modifying the slenderness ratio and reducing the compressive strength of the member. However, in practice, it is difficult to determine accurately the effective length. The concept behind this method is inconsistent with strength design of members of other cross-sectional types such as I or box sections of which the buckling strength is controlled by the Perry constant or the initial imperfection parameters. This paper proposes a method for design of angle frames and trusses by the second-order analysis. The equivalent initial imperfection-to-length ratios for equal and unequal angles to compensate the negligence of initial curvatures, load eccentricities and residual stresses are determined in this paper. From the obtained results, the values of imperfection-to-length ratios are suggested for design and analysis of angle steel trusses allowing for member buckling strength based on the Perry-Robertson formula.

A Study on the Estimation of Elasto-Plastic Buckling Loads for Sing1e Layer Latticed Domes by Unit Member Modeling Technique. (단위부재 모델화에 따른 단층 래티스 돔의 탄소성 좌골하중의 산정에 관한 연구)

  • 한상을;이상주;유용주;이경수
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1998.10a
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    • pp.290-297
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    • 1998
  • In this paper, we propose to a method to estimate the elasto-plastic buckling for single layer latticed domes. First, we assume that each member consists of the rigid zone and elastic spring at both end joint, the elastic element and three elasto-plastic spring to judge for yeilding the member. Next, the member which has most influence on buckling for structures is determined by a distributed pattern of the strain energy which is calculated through linear eigenvalue analysis. And then, normalized slenderness ratio of the element is derived considering the axial force at elastic buckling load. Later, we execute elasto-plastic nonlinear analysis that based on loading increasement method and displacement increasement method. From this results, we discusses the effect of the joint rigidity and the half open angle $\theta$$_{0}$ on the buckling strength of single layer lattice domes ; (1) how the joint rigidity contributes to the reduction of buckling loads, (2) how the reduction can be interrelated to compressive strength curves in terms of the generalized slenderness for the member most relevant to the overall buckling of domes.s.

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Mianorm-based Logics with right and left n-potency axioms (좌 우, n-멱등 공리를 갖는 미아놈 논리)

  • Yang, Eunsuk
    • Korean Journal of Logic
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    • v.23 no.1
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    • pp.1-23
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    • 2020
  • This paper deals with mianorm-based logics with right and left n-potency axioms and their fixpointed involutive extensions. For this, first, right and left n-potent logic systems based on mianorms, their corresponding algebraic structures, and their algebraic completeness results are discussed. Next, completeness with respect to algebras whose lattice reduct is [0, 1], known as standard completeness, is established for these systems via Yang's construction in the style of Jenei-Montagna. Finally, further standard completeness results are introduced for their fixpointed involutive extensions.

The Effect of Thickness and Solidification Rate on the Rapidly Solidified Structure of Al-Cr Alloys (급냉응고(急冷凝固)한 Al-Cr계합금(系合金)의 응고조직(凝固組織)에 미치는 응고속도(凝固速度)와 두께의 영향)

  • Cho, Soon-Hyoung;Nam, Tae-Yoon;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.5 no.2
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    • pp.118-124
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    • 1985
  • The thickness ranges and conditions to form the supersaturated solid solution in Al-Cr alloys were investigated with various rapid solidification conditions. Al-Cr alloys, rapidly solidified by using the small droplet chill quenching method, were examined by means of micro-vickers hardness, lattice parameter, thermal analysis and microscopic observation. The results obtained were as follows; 1. With the increase of solidification rate, the solidified structures were changed to intermetallic compound + solid solution, incompletely supersaturated solid solution, completely supersaturated solid solution, in turn. 2. The minimum solidification rate required to form completely supersaturated solid solution was $2.5{\times}10^{-2}cm/sec$, $3.6{\times}10^{-2}cm/sec$ and $6.0{\times}10^{-2}cm/sec$ for Al-1.0wt%Cr, Al-1,2wt%Cr and Al-1.5wt%Cr, respectively. 3. The maximum distance from the chill surface required to form completely supersaturated solid solution was 5mm, 1.3mm and 0.3mm for Al-1.0wt%Cr, Al-1.2wt%Cr and Al-1.5wt% Cr, respectively.

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