• Title/Summary/Keyword: lattice structures

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Structures and Electrochemical Properties of LiNi0.5-xCo2x}Mn0.5-xO2 as Cathode Materials for Lithium-ion Batteries

  • Choi, Hyun-Chul;Kim, Ho-Jin;Jeong, Yeon-Uk;Jeong, Soo-Hwan;Cheong, In-Woo;Jung, Uoo-Chang
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2603-2607
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    • 2009
  • $LiNi_{0.5-x}Co_{2x}Mn_{0.5-x}O_{2}$ (x = 0, 0.1, 1/6, 1.2, 0.3) were synthesized by the solid-state reaction method. The crystal structure was analyzed by X-ray powder diffraction and Rietveld refinement. $LiNi_{0.5-x}Co_{2x}Mn_{0.5-x}O_{2}$ samples give single phases of hexagonal layered structures with a space group of R-3m for x = 0.1, 1/6, 0.2, and 0.3. The lattice constants of a and c-axis were decreased with the increase in Co contents in samples. The thickness of MO2 slab was decreased and inter-slab distance was increased with the increase in Co contents in $LiNi_{0.5-x}Co_{2x}Mn_{0.5-x}O_{2}$. According to XPS analysis, the valence states of Mn, Co, and Ni in the sample are mainly +4, +3, and +3, respectively. The discharge capacity of 202 mAh/g at 0.1C-rate in the potential range of 4.7 - 3.0 V was obtained in $LiNi_{0.3}Co_{0.4}Mn_{0.3}O_2$ sample, and $LiNi_{0.4}Co_{0.2}Mn_{0.4}O_2$ gives excellent cycle performance in the same potential range.

Antibacterial mesoporous Sr-doped hydroxyapatite nanorods synthesis for biomedical applications

  • Gopalu Karunakaran;Eun-Bum Cho;Keerthanaa Thirumurugan;Govindan Suresh Kumar;Evgeny Kolesnikov;Selvakumar Boobalan
    • Advances in nano research
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    • v.14 no.6
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    • pp.507-519
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    • 2023
  • Postsurgical infections are caused by implant-related pathogenic microorganisms that lead to graft rejection. Hence, an intrinsically antibacterial material is required to produce a biocompatible biomaterial with osteogenic properties that could address this major issue. Hence, this current research aims to make strontium-doped hydroxyapatite nanorods (SrHANRs) via an ethylene diamine tetraacetic acid (EDTA)-enable microwave mediated method using Anodontia alba seashells for biomedical applications. This investigation also perceives that EDTA acts as a soft template to accomplish Sr-doping and mesoporous structures in pure hydroxyapatite nanorods (HANRs). The X-ray diffraction (XRD) and transmission electron microscopy (TEM) analysis reveals the crystalline and mesoporous structures, and Brunauer-Emmett-Teller (BET) indicates the surface area of all the samples, including pure HANRs and doped HANRs. In addition, the biocidal ability was tested using various implant-related infectious bacteria pathogens, and it was discovered that Sr-doped HANRs have excellent biocidal properties. Furthermore, toxicity evaluation using zebrafish reports the non-toxic nature of the produced HANRs. Incorporating Sr2+ ions into the HAp lattice would enhance biocompatibility, biocidal activity, and osteoconductive properties. As a result, the biocompatible HANRs materials synthesized with Sr-dopants may be effective in bone regeneration and antibacterial in-built implant applications.

Analysis and Evaluation of Frequent Pattern Mining Technique based on Landmark Window (랜드마크 윈도우 기반의 빈발 패턴 마이닝 기법의 분석 및 성능평가)

  • Pyun, Gwangbum;Yun, Unil
    • Journal of Internet Computing and Services
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    • v.15 no.3
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    • pp.101-107
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    • 2014
  • With the development of online service, recent forms of databases have been changed from static database structures to dynamic stream database structures. Previous data mining techniques have been used as tools of decision making such as establishment of marketing strategies and DNA analyses. However, the capability to analyze real-time data more quickly is necessary in the recent interesting areas such as sensor network, robotics, and artificial intelligence. Landmark window-based frequent pattern mining, one of the stream mining approaches, performs mining operations with respect to parts of databases or each transaction of them, instead of all the data. In this paper, we analyze and evaluate the techniques of the well-known landmark window-based frequent pattern mining algorithms, called Lossy counting and hMiner. When Lossy counting mines frequent patterns from a set of new transactions, it performs union operations between the previous and current mining results. hMiner, which is a state-of-the-art algorithm based on the landmark window model, conducts mining operations whenever a new transaction occurs. Since hMiner extracts frequent patterns as soon as a new transaction is entered, we can obtain the latest mining results reflecting real-time information. For this reason, such algorithms are also called online mining approaches. We evaluate and compare the performance of the primitive algorithm, Lossy counting and the latest one, hMiner. As the criteria of our performance analysis, we first consider algorithms' total runtime and average processing time per transaction. In addition, to compare the efficiency of storage structures between them, their maximum memory usage is also evaluated. Lastly, we show how stably the two algorithms conduct their mining works with respect to the databases that feature gradually increasing items. With respect to the evaluation results of mining time and transaction processing, hMiner has higher speed than that of Lossy counting. Since hMiner stores candidate frequent patterns in a hash method, it can directly access candidate frequent patterns. Meanwhile, Lossy counting stores them in a lattice manner; thus, it has to search for multiple nodes in order to access the candidate frequent patterns. On the other hand, hMiner shows worse performance than that of Lossy counting in terms of maximum memory usage. hMiner should have all of the information for candidate frequent patterns to store them to hash's buckets, while Lossy counting stores them, reducing their information by using the lattice method. Since the storage of Lossy counting can share items concurrently included in multiple patterns, its memory usage is more efficient than that of hMiner. However, hMiner presents better efficiency than that of Lossy counting with respect to scalability evaluation due to the following reasons. If the number of items is increased, shared items are decreased in contrast; thereby, Lossy counting's memory efficiency is weakened. Furthermore, if the number of transactions becomes higher, its pruning effect becomes worse. From the experimental results, we can determine that the landmark window-based frequent pattern mining algorithms are suitable for real-time systems although they require a significant amount of memory. Hence, we need to improve their data structures more efficiently in order to utilize them additionally in resource-constrained environments such as WSN(Wireless sensor network).

A Study on the Hydraulic and Heat Transfer Characteristics for the Wire-woven Bulk Kagome(WBK) Composed of Aluminum Helix Wires (알루미늄 나선형 와이어로 직조된 다층 Kagome truss PCM의 유동 및 열전달 특성에 관한 연구)

  • Joo, Jai-Hwang;Kang, Bo-Seon;Kang, Ki-Ju
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2061-2066
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    • 2007
  • Recently, ultra-lightweight materials with open, periodic cell structures take much attention owing to its potential for multi-functionality such as load bearing, thermal dissipation, and actuation. This paper presents experimental results on the hydraulic and heat transfer characteristics for the Wire-woven Bulk Kagome(WBK) composed of aluminum 1100 wires. The overall pressure drop and heat transfer of the WBK specimen have been experimentally investigated under forced air convection condition. The pressure loss and heat transfer performance of the aluminum WBK are compared with other heat dissipation media. It was shown that heat transfer depended on relative density and surface area density. Comparison with metal foams and other heat dissipation media such as packed beds, lattice frame materials, louvered fins, and other materials suggests that the aluminum WBK competes favorably with the best available heat dissipation media in heat transfer performance.

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Assessment of capacity curves for transmission line towers under wind loading

  • Banik, S.S.;Hong, H.P.;Kopp, Gregory A.
    • Wind and Structures
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    • v.13 no.1
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    • pp.1-20
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    • 2010
  • The recommended factored design wind load effects for overhead lattice transmission line towers by codes and standards are evaluated based on the applicable wind load factor, gust response factor and design wind speed. The current factors and design wind speed were developed considering linear elastic responses and selected notional target safety levels. However, information on the nonlinear inelastic responses of such towers under extreme dynamic wind loading, and on the structural capacity curves of the towers in relation to the design capacities, is lacking. The knowledge and assessment of the capacity curve, and its relation to the design strength, is important to evaluate the integrity and reliability of these towers. Such an assessment was performed in the present study, using a nonlinear static pushover (NSP) analysis and incremental dynamic analysis (IDA), both of which are commonly used in earthquake engineering. For the IDA, temporal and spatially varying wind speeds are simulated based on power spectral density and coherence functions. Numerical results show that the structural capacity curves of the tower determined from the NSP analysis depend on the load pattern, and that the curves determined from the nonlinear static pushover analysis are similar to those obtained from IDA.

Review on Electronic Correlations and the Metal-Insulator Transition in SrRuO3

  • Pang, Subeen
    • Applied Microscopy
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    • v.47 no.3
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    • pp.187-202
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    • 2017
  • The classical electron band theory is a powerful tool to describe the electronic structures of solids. However, the band theory and corresponding density functional theory become inappropriate if a system comprises localized electrons in a scenario wherein strong electron correlations cannot be neglected. $SrRuO_3$ is one such system, and the partially localized d-band electrons exhibit some interesting behaviors such as enhanced effective mass, spectral incoherency, and oppression of ferromagnetism and itinerancy. In particular, a Metal-Insulator transition occurs when the thickness of $SrRuO_3$ approaches approximately four unit cells. In the computational studies, irrespective of the inclusion of on-site Hubbard repulsion and Hund's coupling parameters, correctly depicting the correlation effects is difficult. Because the oxygen atoms and the symmetry of octahedra are known to play important roles in the system, scrutinizing both the electronic band structure and the lattice system of $SrRuO_3$ is required to find the origin of the correlated behaviors. Transmission electron microscopy is a promising solution to this problem because of its integrated functionalities, which include atomic-resolution imaging and electron energy loss spectroscopy.

A Study on the Prediction of the Material Properties of Magnesium Alloys Using Density Functional Theory Method (밀도함수 이론법을 이용한 마그네슘 합금의 재료특성 예측에 관한 연구)

  • Baek, Min-Sook;Won, Dae-Hee;Kim, Byung-Il
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.637-641
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    • 2007
  • The total energy and strength of Mg alloy doped with Al, Ca and Zn, were calculated using the density functional theory. The calculations was performed by two programs; the discrete variational $X{\alpha}\;(DV-X{\alpha})$ method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using $DV-X{\alpha}$. The optimized crystal structures calculated by VASP were compared to the measured structure. The density of state and the energy levels of dopant elements was discussed in association with properties. When the lattice parameter obtained from this study was compared, it was slightly different from the theoretical value but it was similar to Mk, and we obtained the reliability of data. A parameter Mk obtained by the $DV-X{\alpha}$ method was proportional to electronegativity and inversely proportional to ionic radii. We can predict the mechanical properties because $\Delta{\overline{Mk}}$is proportional to hardness.

Fine Structure and Physical Properties of Cotton Fibers and their Fabrics Treated with Liquid Ammonia, NaOH, and NaOH/Liquid Ammonia (액체암모니아, 수산화나트륨, 수산화나트륨/액체암모니아 처리한 면의 미세구조 및 물성)

  • 배소영;이문철;김홍성;이영희;김경환
    • Textile Coloration and Finishing
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    • v.6 no.2
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    • pp.47-54
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    • 1994
  • Cotton fiber, NaOH-mercerized cotton fiber, cotton fabric, and NaOH-mercerized cotton fabric have been treated by liquid ammonia at -33.4$^{\circ}C$. The fine structures, bending properties, tensile strengthes, shrinkages for laundering, and wrinkle recoveries were studied. The treatment of cottons with liquid ammonia brought about the transition of crystal lattice ; transforming cellulose I crystal of original cotton to cellulose I and III crystal, and cellulose II crystal of mercerized cotton to cellulose II and III crystals. The degree of crystallinities were decreased in the order of liquid ammonia>NaOH/liquid ammonia>NaOH-treated cotton. However moisture regain and water absorbency for liquid ammonia-treated cotton were lower than that of NaOH-treated cotton because of a difference in swelling actions of the agents. It seems caused by intermicrofibrillar pores produced in swelling processes. The bending rigidity and bending hysteresis were decreased remarkly by liquid ammonia treatment. Therefore softness and dimensional stability were improved. The liquid amminia and NaOH/liquid ammonia-treated cottons moreover show excellent properties in tensile strength, anti-shrinkage for laundering, and wrinkle recovery.

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A Study on the Fluid Flow and Heat Transfer Characteristics for the Wire-woven Bulk Kagome(WBK) Composed of Aluminum Helix Wires (알루미늄 나선형 와이어로 직조된 다층 Kagome Truss PCM의 유동 및 열전달 특성에 관한 연구)

  • Joo, Jai-Hwang;Kang, Bo-Seon;Kang, Ki-Ju
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.1
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    • pp.15-22
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    • 2008
  • Recently, ultra-lightweight materials with open, periodic cell structures take much attention owing to its potential for multi-functionality such as load bearing, thermal dissipation, and actuation. This paper presents experimental results on the fluid flow and heat transfer characteristics for the Wire-woven Bulk Kagome (WBK) composed of aluminum 1100 wires. The overall pressure drop and heat transfer of the WBK specimen was experimentally investigated under forced air convection condition. The pressure loss and heat transfer performance of the aluminum WBK were compared with other heat dissipation media. It was shown that heat transfer characteristics depended on relative density and surface area density. Comparison with metal foams and other heat dissipation media such as packed beds, lattice frame materials, louvered fins, and others suggests that the aluminum WBK competes favorably with the best available heat dissipation media in heat transfer performance.

Hydrogen Storage Behaviors of Multi-walled Carbon Nanotubes Modified by Physical Activation Process (기상활성화 표면처리된 다중벽 탄소나노튜브의 수소저장거동)

  • Park, Soo-Jin;Lee, Seul-Yi;Kim, Byung-Joo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.765-768
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    • 2009
  • In this work, we prepared the activated multi-walled carbon nanotubes (Acti-MWNTs) with well developed physical surface structures, high specific surface area, and higher adsorption capacity by a physical activation process, in order to enhance the hydrogen storage capacity. The Acti-MWNTs' changes in the crystalline phase and in their lattice distortions were characterized by X-ray diffraction (XRD). The textural properties of the Acti-MWNTs were investigated by a nitrogen adsorption isotherms by Brunauer-Emmett-Teller (BET) equation and Harvath-Kawazoe (H-K) calculation, respectively. The hydrogen storage capacity of the Acti-MWNTs was investigated by BEL-HP at 298 K/100 bar. The hydrogen storage capacity of the Acti-MWNTs was improved with the physical activation, resulted from the formation of new hydrogen-favorable sites on the Acti-MWNT surfaces. In conclusion, the physical activation was one of the effective method to enhance the hydrogen storage capacity of the MWNTs.

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