• Title/Summary/Keyword: lattice change

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Titanium Incorporation in (Znl-xNix)2TiO4 Spinel Ceramics (티타늄 합침에 의한 (Znl-xNix)2TiO4 스피넬 세라믹스)

  • 강귀원;김효태;황준철;이종원;백운규
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.97-97
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    • 2003
  • Composition in the (Znl-xNix)2TiO4+ yTiO2 system (x=0-0.5, y=0-0.35) were synthesized via the solid-state reaction route. The incorporation of titanium, in the form of TiO2, in (Znl-xNix)2TiO4 spinel ceramics were investigated by analyzing the crystal structure and measuring the dielectric properties. The result of the crystal structure analysis suggested that TiO2 level of 0.01 y 0.33 could be incorporated into the (Znl-xNix)2TiO4 spinel. The change of incorporated TiO2 level is related with Co-content as a inverse proportion and the variation of lattice parameter and dielectric properties were supported the result.

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Study on nuclear magnetic resonance of superionic conductor NH4HSeO4 in rotating frame

  • Choi, Jae Hun;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.1
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    • pp.41-46
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    • 2014
  • In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.

Synthesis of MnFeP1-xAsx Nanocrystalline Powders by High-Energy Ball Milling (고에너지볼밀링을 이용한 MnFeP1-xAsx 나노분말의 합성)

  • 조영환
    • Journal of Powder Materials
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    • v.10 no.2
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    • pp.129-135
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    • 2003
  • Nanocrystalline powders of $MnFeP_{1-x}As_x$(x=0.45-0.6) have been synthesized by mechanochemical reaction at room temperature using high-energy ball milling from mixtures of Mn, Fe, P, and As Powders. It has been found that a mechanically induced self-propagating reaction (MSR) occurs within 2 hours of milling and it produces very fine polycrystalline powder having a hexagonal $Fe_2P$ structure. Further milling up to 24 hours did not change the crystalline and average particle sizes or the phase composition of the milling product. When x is 0.65, no reaction among the reactants has been observed even after 24 hours of milling. As the P content decreases in $MnFeP_{1-x}As_x$, the incubation time for the MSR has increased and the lattice constants in both a and c axes have changed.

Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries (리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성)

  • Park, Jong-Wan;Ascencio Jorge A.
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.297-301
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    • 2006
  • Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.

The Jeogori Included in The Buddist Statue in 1748 (1748년 불복장 저고리 소고)

  • 김선경;조효숙
    • Journal of the Korea Fashion and Costume Design Association
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    • v.5 no.2
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    • pp.65-74
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    • 2003
  • The Purpose of this study is to investigate the jeogori included in the buddist statue in 1748. The jeogori was similar in shape to excavated costume of Andong Kwon, Papyung Yoon, and Chungyeongunju in 18th century. This jeogori was useful to estimate the interesting process of shape change of jeogori in 18th century. Four different silk fabrics were used in the jeogori. Outer fabrics were satin weave with floral, lattice strip, dragon, and cloud patterns. The ground area was 5-harness warp faced satin and the patterned area was 5-harness filling faced satin. An inner fabric was simple plain weave. Warp and filling yarns of all fabrics in this jeogori had no twist.

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A doulbe talk detector using the reflection coefficients (반사계수를 이용한 동시통화 검출기)

  • 유재하;조성호;윤대희
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.34S no.10
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    • pp.141-150
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    • 1997
  • In this paepr, we propose an intelligent double talk detector that can enhance the performance of the acoustic echo cancellation system. The conventional double talk detection methods often misunderstand the echo path changes as double talk. Although there exist several detection methods that can distinguish the echo path changes from the double-talks, they show poor tracking performance because of the excessive decision delay for the discrimination and can only be used after the adaptive digital filter converges. A new and more effective ditetion algorithm has been proposed, where the detection mechanism is performed by observing the change rate of the reflection coefficients of the two lattice predictors that re placed on the near-end and far-end terminals. The excellence of the proposed method is verified by extensive computer simulations using real speech signals.

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Effects of Temperature Coefficients for Dielectric Constants on Thermoreflectances and Thermal Responses of Metal Thin Films Exposed to Ultrashort Pulse Laser Beams

  • Seungho Park
    • International Journal of Air-Conditioning and Refrigeration
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    • v.10 no.1
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    • pp.1-9
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    • 2002
  • Effects of temperature coefficients fur dielectric constants on transient reflectances and thermal responses have been investigated for a metal(gold) thin-film during ultrashort pulse laser heating. Heating processes are simulated using the conventional conduction model(parabolic one-step, POS), the parabolic tow-step model(PTS), the hyperbolic two-step model(HTS). Results fro the HTS model are very similar to those from the PTS model, since the laser heating time in this study is considerably greater than the electron relaxation time. PTS and HTS models, however, result in completely different temperature profiles from those obtained by the POS model due to slow electron-lattice interactions compared to laser pulse duration. Transient reflectances are directly estimated from the linear relationship between electron temperature and complex dielectric constants, while conventional approaches assume that the change in reflectances is proportional to that in temperatuer. Reflectances at the front surface vary considerably for various dielectric constants, while those at the rear surface remain unchanged relatively.

Feasibility Study on the Utilization of Mixed Oxide Fuel in Korean 900MWe PWR Core Through Conceptual Core Nuclear Design and Analysis

  • Joo, Hyung-Kook;Kim, Young-Jin;Jung, Hyung-Guk;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.29 no.4
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    • pp.299-309
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    • 1997
  • The neutronic feasibility of typical Korean three-loop 900MWe class PWR core loaded with mixed oxide fuels for both annual and 18-month cycle strategies has been investigated as a means for spent fuel management. For this study, a method of determining equivalent plutonium content was developed under the equivalence concept which gives the same cycle length as uranium fuel. Optimal plutonium zoning within the MOX assembly was also designed with the aim of minimizing the peak md power. Conceptual core designs hate hen developed for equilibrium cycle with the following variations: annual and 18-month cycle, 1/3 and full MOX loading schemes, and typical and high moderation lattice. The analysis of key core physics parameters shows that in all cases considered satisfactory core designs seem to be feasible, though addition of control rod system and change in Technical Specification for soluble boron concentration are required for full MOX loading in order to meet the current design requirements.

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BRIEF REVIEW OF LATEST DIRECT NUMERICAL SIMULATION ON POOL AND FILM BOILING

  • Kunugi, Tomoaki
    • Nuclear Engineering and Technology
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    • v.44 no.8
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    • pp.847-854
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    • 2012
  • Despite extensive research efforts, the mechanism of the nucleate boiling phenomena is still not clear. A direct numerical simulation of the boiling phenomena is one of the promising approaches in order to clarify its heat transfer characteristics and discuss their mechanism. Therefore, many DNS procedures have been developed based on recent highly advancing computer technologies. This brief review focuses on the state of the art in direct numerical simulation of the pool boiling phenomena over the past two decades. In this review, the fundamentals of the boiling phenomena and the bubble departure and micro-layer models are briefly introduced, and then the numerical procedures for tracking or capturing interface/surface shape such as the front tracking method, level set method, volume of fluid treatments, and other methods (Lattice Boltzmann method, phase-field method and so on) are briefly reviewed.

The Conductivity Percolation of Conducting Plastic Materials (도전성 플라스틱의 전도 퍼콜레이션)

  • Kim, In Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.713-721
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    • 1999
  • A composite plastic, where long metallic fibers are used as filling materials, is transformed from nonconducting to conducting medium as the volume fraction of filling metallic fibers is increased from zero : such drastic change in property is called the percolation. It is desired both for practical and theoretical purposes to understand the physics underlying the percolation and to estimate the percolation threshold that is defined by the minimum volume fraction of the metallic fibers for which the percolation occurs. In this study, percolation thresholds are calculated by Monte Carlo Computer simulation. Both lattice and continuum spaces are considered and detailed microstructures of metallic fibers are modelled as rigid and flexible bodies for both model spaces. Simulations are carried out for wide range of aspect ratios and discussions are given.