• Title/Summary/Keyword: latex properties

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Improvement of Abrasion and Debris on Styrene-Butadiene-Styrene Block Copolymer with Carboxylated SBR Latex and Zinc Oxide (카르복실화 SBR 라텍스와 산화아연을 이용한 SBS의 내마모성과 데브리스(debris) 개선 연구)

  • Lee, Jin Hyok;Bae, Jong Woo;Kim, Jung Su;Yoon, Yoo-Mi;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.225-231
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    • 2013
  • In this study, we observed the effect of carboxylated SBR latex and zinc oxide on styrene-butadiene-styrene( SBS) composites for improving abrasion and debris. SBS composite, which added only silica, showed poor mechanical properties, NBS abrasion, and debris, caused by strong filler-filler interaction of silica. In case of adding carboxylated SBR latex, mechanical properties, NBS abrasion and debris of SBS composite were improved. Because of carboxyl group of carboxylated SBR latex interacted with silanol group of silica. Both carboxylated SBR latex and zinc oxide were added, SBS composite showed highest mechanical properties, NBS abrasion, and debris by forming ion cluster between carboxylated SBR latex and zinc oxide. By FT-IR analysis, ion clusters were confirmed that observed zinc carboxylated group stretch peak at $1550{\sim}1650cm^{-1}$ range. SBS composite, SC-4, showed excellent mechanical properties ; tensile strength $156kgf/cm^2$, elongation 936%, tear strength 59.4kgf/cm ; and excellent abrasion characteristics ; NBS abrasion 338%. Also, debris of SC-4 was minimized and showed wave-shape in fracture surface.

Effect on the Properties of Coated Paper by Drying Temperature and Curing Time (건조 온도 및 경화시간이 도공지 품질에 미치는 영향)

  • 박동국;최희연;김영하;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.4
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    • pp.16-21
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    • 2002
  • It was observed that drying temperature and curing time in the paper coating process as well as Tg of the latex used as a binder, greatly affected the properties of the coated paper such as roughness, paper and print gloss, K & N ink drop, and ink set-off. The higher drying temperature induced faster water evaporation and change in binding density, which caused an increase in paper roughness, ink gloss and ink set-off, but decrease in paper gloss and K & N ink drop. The increased curing time promoted latex filming and redistribution of the binder in coating layer. This increased pick strength and ink gloss, but decreased ink trapping. Finally, the higher Tg of the latex showed the wider changing range of these properties.

Influence of the Type and Blending Ratio of Binders on Ink-jet Printing Properties (바인더의 종류 및 배합비율이 잉크제트 인쇄특성에 미치는 영향)

  • 이희명;김창근;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.2
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    • pp.22-31
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    • 2002
  • In this paper, PVA(polyvinylalcohol), oxidized starch and SBR latex were used as binders for ink-jet printing papers, and their effects of the type and blending ratio of binders on ink-jet printing properties were compared. In case of coating color using PVA mainly used for a binder in ink-jet printing, spreading of printed letters decreased and excellent images were manifested resulting from strong hydrophilic of PVA. However, increasing solids content of coating color was somewhat limited because of the interaction of PVA and functional groups in silica as well as high molecular weight of PVA. When oxidized starch and SBR latex were mixed with PVA at desirable ratio to solve these problems, runnability in coating process was improved and good printing properties were shown. Gloss was improved when latex was used along with PVA as a binder because of the thermoplastic property of the latex. From this result, possibilities of high solids content and high gloss ink-jet printing papers were investigated.

Preparation of NR/MG Latex Blend Films and its Mechanical Properties (NR/MG Latex 블랜드필름의 제조 및 그의 기계적특성)

  • Kim, K.S.;Park, J.H.;Eum, J.S.;Kim, S.J.
    • Elastomers and Composites
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    • v.29 no.1
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    • pp.9-17
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    • 1994
  • Methylmetharylate grafted latex(MGL) was prepared by emulsion graft copolymerization of methyl methacrylate onto natural rubber latex(NRL) by using t-butyl hydroperoxide and tetraethylene pentamine in an aqueous medium. Blending of MGL and NRL with different mixing ratio carried out and viscosity and particle size distribution of blend latex were determined. It was found that the optimum condition of mature time, vulcanizing temperature and time for preparation of blend latex films were investigated. latex films prepared by dipping process were meaured. As the reuslt, blend latex(NR-d-MG) films obtained from two-dipping system were more excellent than NR and MG film obtained from one-dipping system.

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Development of Water-Permeable Polymer Concrete for Pavement (투수성 포장 폴리머 콘크리트의 개발)

  • 이윤수;주명기;연규석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.147-152
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    • 2001
  • The purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29%, polymer-cement ratios of 0, 5, 10, 15 and 20% are prepared, and tested for compressive strength, tensile strength, flexural strength, water permeability. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

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Drying Shrinkage Properties of Latex Modified Concrete with Water-Cement Ratios (라텍스개질 콘크리트의 물-시멘트비에 따른 건조수축 특성)

  • Jeong, Won-Kyong;Kim, Seong-Hwan;Kim, Dong-Ho;Lee, Joo-Hyung;Lee, Bong-Hak
    • Journal of Industrial Technology
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    • v.22 no.A
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    • pp.193-200
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    • 2002
  • Drying shrinkage cracking which may be caused by the relatively large specific surface IS a matter of grave concern for latex modified concrete(LMC) overlay and rapid-setting cement latex modified concrete(RSLMC) overlay. LMC and RSLMC were studied for field applications very actively in terms of strength and durability in Korea. However, there were no considerations in drying shrinkage. Therefore, the purpose of this dissertation was to study the drying shrinkage properties of LMC and RSLMC with the main experimental variables such as cement types(ordinary portland cement, rapid setting cement), water-cement ratios and curing days at a same controlled environment of 60% of relative humidity and $20^{\circ}C$ of temperature The drying shrinkage for specimens was measured with a digital dial gauge of Demec. The test results showed that the drying shrinkage of LMC and RSLMC were considerably lower with low water-cement ratio, respectively This might be attributed to the interlocking of hydrated cement and aggregates by a film of latex particles, water retention due to hydrophobic, and colloidal properties of the latexes resulting in reduced water evaporation.

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The Physical Properties of Ethylene Vinylacetate Emulsion Mixed with SBR, Urethane, Epoxy and Acryl Latex (아크릴, 에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌 비닐아세테이트계 에멀젼 수지의 물리적 특성)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.196-204
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    • 2000
  • SBR, polyurethane, acryl and epoxy latex were separately mixed with ethylene -vinylacetate emulsion(EVA) in the range of $0{\sim}50wt%$. For the mixtures, the various physical properties such as defoamerability, mechanical property, and water resistance were experimentally examined. The excellent defoamer was BYK-021 and the appropriate use of it was 0.3 phr for the total components. The shrinkage of compounds was influenced by the compatability of resins and the formation of voids. The mechanical properties was related to the cohesive force of resin particles, the coagulation of cement particles and the co-bonding of resin particles with cement particles. Mixing latex separately showed better properties then non-mixing in the shrinkage ratio, flexural strength, adhesive strength, and impact strength. The water resistance of composites mixed with cement was worse than that of EVA resin.

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Freezing and Thawing Resistance of Latex Modified Concrete with Latex Content (라텍스 혼입에 따른 LMC의 동결융해 저항특성평가)

  • 이주형;정원경;김동호;이봉학;원치문;이정호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.497-502
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    • 2000
  • This study was performed to change the latex content for properties of freezing-thawing resistance. When styrene-butadiene latex is added to portland cement, aggregate and water, a concrete with the color, consistency and workability of ordinary conventional concrete results, but with 20% to 35% less water. When cured, the concrete consists of hydrated cement and aggregate interconnected by a film of latex particles. In general, increasing the amount of latex will produce concrete with increased tensile and flexural strength and lower modulus of elasticity. Air entrainment has been used in conventional concrete for the past 50 years to impart freeze-thaw resistance. Latex modified concrete does not need additional air entrainment for freeze-thaw resistance provided adequate cure occurs.

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Effect of Vinyl Acetate-Ethylene(VAE) Emulsion on Coated Paper Properties (비닐아세테이트 에틸렌 공중합체 바인더가 도공지의 품질에 미치는 영향)

  • Lee, Yong-Kyu;Won, Jong Myoung;Lee, Woo-Jae;Choi, Yong-Hae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.5
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    • pp.37-43
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    • 2013
  • This study was focused on applying a new paper coating binder, vinyl acetate-ethylene(VAE) emulsion, with SB-latex and acrylic emulsion for paper coating application. VAE emulsion has a low monomer cost and is non-toxic chemical than conventional adhesive for paper coating such as styrene-butadiene latex( SB-latex) and acrylic emulsion. We conducted double coating in order to test VAE emulsion, which was applied on top surface only. The results showed that optical properties of the coated paper with VAE were similar with the SB-latex binders. In case of bonding strength, dry-pick of the coated paper with VAE showed almost same with other binders while wet-pick of the coated paper with VAE had a little bit lower strength than that with SB-latex.