• Title/Summary/Keyword: latent heat effect

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Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex

  • Kim, Kyung-A;Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.505-509
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    • 2013
  • A low temperature ($65^{\circ}C$) thermal deposition process was developed for depositing a silver coating on thermally sensitive polymeric substrates. This low temperature deposition was achieved by chemical reduction of a silver alkylcarbamate complex with latent reducing agent. The effects of acetol as a latent reducing agent for the silver 2-ethylhexylcarbamate (Ag-EHCB) complex and their blend solutions were investigated in terms of reducing mechanism, and the size and shape of silver nanoparticles (Ag-NPs) as a function of reduced temperature and time, and PVP stabilizer concentration were determined. Low temperature deposition was achieved by combining chemical reduction with thermal heating at $65^{\circ}C$. A range of polymer film, sheet and molding product was coated with silver at thicknesses of 100 nm. The effect of process parameters and heat treatment on the properties of silver coatings was investigated.

A Study on Thermal Performance of Cement Mortar with PCM (PCM을 혼입한 시멘트 모르타르의 열적성능에 관한 연구)

  • Kim, Bo-Hyun;Lee, Han-Seung
    • Journal of the Korea Concrete Institute
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    • v.23 no.4
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    • pp.521-528
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    • 2011
  • Recently, environmental concerns and issues have become great concerns for the public. Therefore, this study is conducted with the objective of preventing energy depletion and $CO_2$ emission. PCM (Phase Change Materials) having latent heat characteristic is mixed in mortar to find a proper mix proportion. Also, the mortar properties and performances as well as a melting point of PCM when applied to air conditioning and heating conditions in at building environments were obtained by performing experiments. Also, latent heat and heat transfer characteristics were obtained from experiments by test of thermal performance to formulate temperature gradient about amount of heat transfer of PCM content using the Fourier's thermal equation. The study results can be used in the application of PCM in buildings and expected effect of air conditioning and heating energy.

The Analysis of the Energy Saving Performances of Building Materials using Phase Change Materials (상변화물질을 적용한 건축자재의 에너지절약 가능성 분석)

  • An, Sang-Min;Hwang, Suck-Ho;Kim, Tae-Yeon;Leigh, Seung-Bok
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.162-167
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    • 2011
  • Thermal storage plays an important role in building energy saving, which is greatly assisted by the incorporation of latent heat storage in building materials. A phase change material is a substance with a high heat of fusion which, melting and solidifying at a certain temperature, can be storing and releasing large amount of energy. Heat is stored or released when the material changes from solid to liquid. Integration of building materials incorporating PCMs into the building envelope can result in increased efficiency of the built environment. The aim of this research is to identify thermal performance of PCMs impregnated building materials which is applied to interior of building such as gypsum and red clay. In order to analyze thermal performance of phase change materials, test-cell experiments and simulation analysis were carried out. The results show that micro-encapsulated PCM has an effect to maintain a constant indoor temperature using latent heat through the test-cell experiments. PCM wallboard makes it possible to reduce the fluctuation of room temperature and heating and cooling load by using EnergyPlus simulation program. Phase change material can store solar energy directly in buildings. Increasing the heat capacity of a building is capable of improving human comfort by decreasing the frequency of indoor air temperature swings so that the interior air temperature is closer to the desired temperature for a long period of time.

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A Study on the Cooling Characteristics Improvement of TMA-Water Clathrate Compound by Ethanol (에탄올에 의한 TMA-포접화합물의 냉각특성 개선에 대한 연구)

  • Lee, Jong-In;Kim, Chang-Oh
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.23-28
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    • 2007
  • This study aims to find out cooling characteristics of TMA(Tri-Methyl-Amine, $(CH_3)_3N$) 25wt%-water clathrate compound with ethanol($CH_3CH_2OH$) such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at $-6{\sim}-8^{\circ}C$, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as $3.8^{\circ}C$ according to cooling source temperature in case that 0.5wt% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is $0.9^{\circ}C$ and minimum supercooling is 0.8, $0.7^{\circ}C$ according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is $3.013{\sim}3.048\;kcal/kg^{\circ}C$ according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol. This can lead to shorten refrigerator operation time of low temperature latent heat storage system and improve COP of refrigerator and efficiency of overall system. Therefore energy can be saved and efficiency can be improved much more.

Derivation of a Simplified Heat Transfer Correlation for AP 600 Passive Containment Cooling System

  • Chung, Bum-Jin
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.122-130
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    • 1998
  • A simplified heat transfer model for the cooling capability of the AP 600 PCCS is proposed I this paper. As the PCCS domain is covered with very thin and long water film, it is phenomenologically divided into 3 regions; water entrance effect region, asymptotic region, and air entrance effect region. As the length of the asymptotic region is estimated to be over 90% of the whole domain, the phenomena in the asymptotic region is focused. Using the analogy between heat and mass transfer phenomena in a turbulent situation, a new dependent variable combining temperature and vapor mass fraction was defined. The similarity between the PCCs phenomena in the asymptotic region and the buoyant air flow phenomena on a vertical heated plate is derived. Using the similarity, the simplified heat transfer correlations for the interfacial heat fluxes and the ratios of latent heat transfer to sensible heat transfer were established. To verify the accuracy of the correlation, the results of this study were compared with those of other numerical analyses performed for the same configuration and they are well within the range of 15% difference.

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PCM mixed the amount of Thermal Conductivity of Cement mortar Experimental Study on the effect. (PCM 혼입량이 시멘트 모르타르의 열전도율에 미치는 영향에 관한 실험적 연구)

  • Jeong, You-Gun;Kim, Bo-Hyun;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.245-246
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    • 2011
  • In recent research in this emerging and latent heat storage material features an innovative temperature - controlled Phase Change Materials to evaluate the superior thermal performance would like to calculate the thermal conductivity. Specified in KS F 4040 test specimen dimensions were equivalent in specifications, test methods according to KS L 9016 was an experiment in progress. As a result, the thermal conductivity of plain cement mortar mixed with more PCM came out with low thermal conductivity of mortar, thermal performance was excellent.

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Effect of Paper Properties on the Performance of a Enthalpy Exchanger (종이 물성이 전열교환 엘리먼트 성능에 미치는 영향)

  • Kim, Nae-Hyun;Cho, Jin-Pyo;Song, Gil-Sup;Kim, Dong-Hoon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.414-418
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    • 2008
  • The effects of paper properties such as density, air permeability, water vapor transmission rate on the thermal performance of plate-type enthalpy exchanger were experimentally investigated. Three enthalpy exchanger samples having different properties were made, and were tested according to the standard test procedure (KS B 6879). Effective efficiencies were defined, which accounted for the air leakage between supply and exhaust streams. Results showed that paper density affected the sensible heat transfer of the samples. Sensible heat transfer increased with density of the paper. It was also shown that water vapor transmission rate alone was not a proper indicator for the efficiency of latent heat transfer. Air permeability should also be considered for adequate evaluation of the latent heat transfer. Best performance was obtained for the sample having highest paper density and moderate water vapor transmission ratio.

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Role of Atmospheric Turbulences and Energy Balances in the Atmospheric Surface Layer (접지층에서 대기난류의 역할과 에너지 평형)

  • Kwon, Byung-Hyuk;Kim, Geun-Hoi;Kim, Kwang-Ho;Kang, Dong-Hwan
    • Journal of Wetlands Research
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    • v.11 no.1
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    • pp.105-113
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    • 2009
  • Heat energy exchange is very important processes in the coastal wetland ecosystems. We observed and analyzed the net radiation flux, the sensible heat flux, the latent heat flux and the soil heat flux, which are balanced in the heat energy balance, over a reclaimed land covered with reeds at Goheung, Jeonllanamdo where is horizontally plane. The atmospheric turbulence had been measured in order to estimate the heat transfer during 5 intensive observation periods (IOPs). It was considered that the soil consists of water, fine particles, and vegetation canopy that changes color and density according to the season. We examined the characteristics of the heat flux and the vegetation effect on the air temperature control. It was noted that the heat was transported mainly by latent heat flux in the summer season and the vegetation canopy decreased the daily temperature range due to the heat storage. The air temperature was lower at the IOPs site than near urban area. This showed that the coastal wetland covered with the vegetation control the thermal environment.

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Heat Storage Material by Using Phase Change Materials to Control Buildings Thermal Environment Characteristics (건축물 열환경 특성제어를 위한 상변화 축열재)

  • Yun, Huy-Kwan;Han, Seong-Kuk;Shim, Myeong-Jin;Ahn, Dae-Hyun;Lee, Woong-Mok;Park, Jong-Soon;Kim, Jae-Yong
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.522-526
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    • 2010
  • Heat storage application techniques can be categorized into the sensible heat storage and the latent heat storage according to the method of heat storage. Heat storage is the way of saving remaining heat when heating and cooling loads are light, and then using it when the heating and cooling loads are heavy. Latent heat storage is defined as the method of saving heat by using substances which have high potential heat when phase change is in the range of a certain temperature and when heat storage space is small, compared to those of sensible heat storage and it is possible that absorption and emission of heat at a certain temperature. This study is conducted to save energy when either air-conditioning or heating is operated in a building. We have tried to find out the essential properties of matter and the optimum mixing rate about cement and gypsum for building materials, which have been widely used for proper phase change materials (PCM), when thermal environment property is applied. So we obtained the result of the cooling delay effect about 19% with heat storage mortar containing 3 wt% of PCM.