• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.42 no.3
• /
• pp.297-302
• /
• 2016

In this study, we prepared liquid crystal emulsions composed of $C_{12-20}$ alkyl glucoside, $C_{14-22}$ alcohol, and behenyl alcohol and performed structure analysis using various analytical equipment. First, as an important characteristic of liquid crystal emulsions, maltese cross patterns and multi-layer structure were observed by a polarized microscope and cryo-SEM. Also, formation of liquid crystal phase was confirmed by DSC and multi-layer lamellar structure having an interlayer spacing approximately $305{\AA}$ was confirmed by small angle x-ray scattering (SAXS). The alkyl chain arrangement formed orthorhombic structure of a lamellar structure of the liquid crystal emulsion was confirmed by wide angle x-ray scattering (WAXS). These results suggest that information on the various physical properties obtained through the research of liquid crystal emulsion structure is expected to be widely used in cosmetics development in the future.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.5
• /
• pp.613-616
• /
• 2003

Effect on hydrothermal treatment of lamellar vanadium oxides was investigated and the formation of hexagonal and cubic mesophase was found. This lamellar materials were prepared by mixing of cetyltrimethylammonium-bromide and pH-controlled sodium metavanadate solution. Thermal method and UV/O₃treatment were applied to extract organic template. The structure of resulting product was studied by powder X-ray diffraction and transmission electron microscopy (TEM).

• Journal of Korea Foundry Society
• /
• v.17 no.2
• /
• pp.188-194
• /
• 1997

The effects of solidification condition and vibration on structure refinement were investigated for unidirectionally solidified $Al-CuAl_2$ eutectic composites. Eutectic composites were unidirectionally solidified under vibration with different growth rates (R) and thermal gradient(G). The lamellar structure was varied according to growth condition (G/R ratio). For the structure refinement the effect of G/R was found out to be greater than that of vibration. The interlamellar spacing(${\lambda}$) in this materials was varied with the growth rates(R) with "${\lambda}^2R$=Constant" relationship.

• Journal of Korea Foundry Society
• /
• v.37 no.6
• /
• pp.199-206
• /
• 2017

In this study, the variations of microstructures and tensile properties of Ti-(44-54)at.%Al binary alloys were investigated. The heat-treated microstructure depended greatly on their solidification structure and annealing temperature. We measured the variations of volume fractions of primary and secondary lamellar structure as a function of the heat treatment temperature in a Ti-47at.%Al alloy. The variation of ductility as a function of Al content was in good agreement with the change of fracture mode in the tensile fracture surface. It can be inferred that the variations of yield stress and hardness of ${\gamma}$ phase in a single ${\gamma}$-phase field region are enhanced by anti-site defects created by deviations from the stoichiometric composition. In a Ti-47at.%Al alloy within the (${\alpha}_2+{\gamma}$) two-phase field, the yield stress tended to be the maximum at a near equal volume fraction of lamellar and ${\gamma}$ grains. The ductility depended sensitively on the overall grain size and Al content. The calculation of fracture strain using Chan's model indicated that the change of ductility as a function of annealing temperature was primarily determined by the variations in the overall grain size and lamellar volume fraction.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.11 no.4
• /
• pp.170-175
• /
• 2001

It was possible to grow the $Al_{2}O_{3}$ based $Y_{3}A_{5}O_{12}(YAG),ZrO_{2}$ binary and ternary eutectic fibers using micro-pulling down method with a growing rate of 0.1~15 mm/min. While $Al_{2}O_{3}/ZrO_{2}$ showed cellular-lamellar structure, $Al_{2}O_{3}$/YAG and $Al_{2}O_{3}$/YAG/$ZrO_{2}$ternary eutectic fibers showed homogeneous Chinese script lamellar structures. The microstructures of $Al_{2}O_{3}/ZrO_{2}$ binary eutectic fibers changed with solidification rate from lamellar pattern to cellular structure. The interlamellar spacing agreed with the inverse-square-root dependance on pulling rate according to $\lambda$=$kv_p\;{-1/2}$. $Al_{2}O_{3}/ZrO_{2}$ binary eutectic fibers recorded the highest tensile strength of about 1560MPa at room temperature. $Al_2O_3/YAG/ZrO_2$ternary eutectic fiber showed excellent thermal stability to $1200^{\circ}C$ without significant decrease. The maximum strength of ternary eutectic fibers recorded were 1100MPa at $25^{\circ}C$ and 970MPa at $1200^{\circ}C$, respectively.

• Journal of the Korean Ceramic Society
• /
• v.35 no.6
• /
• pp.610-618
• /
• 1998

Alumina were added to ceria based ceramic powders upto 9.7 vol% and composite powders were sprayed by plasma spraying process in order to improve the mechanical properties such as hardness fracture tough-ness and thermal shock resistance. The ceria based coating sprayed without alumina has the typical colum-nar and lamellar structure. Alumina addition has lowered the amount of columnar and lamellar sturcture Added alumina was segreagated in the grain boundary and grain of ceria based crystal accompanied with pore. The maximum value of density and the minimum value of porosity were observed at the sprayed coating with 4.8 vol% alumina. The hardness fracture toughness and thermal shock resistance were increased with alumina addition. The improvement of mechanical properties of plasma sparyed ceria based coatings result-ed from the disapperance of the columnar and lamellar sturcture by addition of alumina.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.31 no.5
• /
• pp.550-555
• /
• 2007

The effective fracture toughness testing of materials intended for application in Micro Electro Mechanical Systems (MEMS) devices is required in order to improve understanding of how micro sized material used in device may be expected to perform upon the micro scale. ${\gamma}$-TiAl based materials are being considered for application in MEMS devices at elevated temperatures. Especially, in Alloy 4, both ${\alpha}_2$ and ${\gamma}$ lamellae were altered markedly in 3,000 h, $700^{\circ}C$ exposure. Parallel decomposition of coarse ${\alpha}_2$ into bunches of very fine (${\alpha}_2+{\gamma}$) lamellae. Parallel decomposition of coarse ${\alpha}_2$ into bunches of very fine (${\alpha}_2+{\gamma}$) lamellae. The materials were examined 2 types Alloy 4 on heat exposed specimen($700^{\circ}C$, 3,000 h) and no heat exposed one. Micro sized cantilever beams were prepared mechanical polishing on both side at $25{\sim}30{\mu}m$ and electro final stage polishing to observe lamellar orientation of same colony with EBSD (Electron Backscatter Diffraction Pattern). Through lamellar orientation as inter-lamellae or trans-lamellae, Cantilever beam was fabricated with Focused Ion Beam(FIB). The directional behavior of the lamellar structure was important property in single material, because of the effects of the different processing method and variations in properties according to lamellar orientation. In MEMS application, it is first necessary to have a reliable understanding of the manufacturing methods to be used to produce micro structure.

• Journal of Korea Foundry Society
• /
• v.10 no.4
• /
• pp.332-341
• /
• 1990

The structure and tensile properties of the unidirectionally solidified Al-33wt.%Cu alloy have been investigated. Casted Al-33wt.%Cu alloy was unidirectionally solidified with rates (R) between 1㎝/hr and 24cm/hr maintaining the thermal gradient(G) at solid-liquid interface, $32^{\circ}C/cm$ and $21^{\circ}C/cm$. The entectic struture was varied according to the growth condition(G/R radio). When G/R ratio was larger than $8.5{\times}10^3$ $^{\circ}C/cm^2/sec$ the lamellar structure was formed, and colony structure was formed when G/R ratio was smaller than $8.5{\times}10^3$ $^{\circ}C/cm^2/sec$. The interlamellar spacing(${\gamma}$) in the above alloy system was vaired with the growth rate(R) According to "${\gamma}^2{\cdot}R＝8.8{\times}10＾{-11}cm^2/sec$" relationship. The yield stress (${\sigma}$0.001) and UTS for samples in the as-grown condition increased with the interlamellar spacing decrease and the values corresponding to colony structure are lower than those corresponding to amellar structure with the same lamellar spacing. The yield stress for samples in aged condition did not change with the interlamellar spacing.

• Journal of Biomedical Engineering Research
• /
• v.15 no.4
• /
• pp.389-394
• /
• 1994

The age-hardening behavior and the structural changes in a commercial dental Au-Ag-Cu-Pd alloy were investigated by means of hardness test, optical and scanning electron microscopic observation, energy dispersive spectroscopy and X-ray diffraction study. The drastic reduction in hardness by prolonged aging occurred after a rapid increase in hardness at the initial stage by the isothermal aging at $350^{\circ}C$. This softening was due to the broad precipitates formation of the lamellar structure which was composed of the f.c.t. AuCu I ordered f.c.t. phase containing Pd and the f.c.c. Ag-rich $\alpha$1 solid solution f.c.c.phase containing Au.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2011.05a
• /
• pp.39-39
• /
• 2011

Surface hardening mechanism of AA 2024 was investigated when shot peeningprocess with shot ball of Zn alloy was applied. Zn alloy was transferred into surface region of AA 2024, forming lamellar structure of Al and Zn phase. Nanocrystallization of AA 2024 and alloyed Zn phase was achieved by the different mechanisms. Furthermore, precipitations in AA 2024 remained undissolved. Lamellar structure with different nano-sized grains of two different phase and randomly distributed precipitations contributed to the surface hardening.