• Applied Microscopy
• /
• v.52
• /
• pp.6.1-6.5
• /
• 2022

We examined the morphology of the fertilized egg and the fine structure of fertilized egg envelopes of Poropanchax normani belonging to the family Poeciliidae, also known as Norman's lampeye using light and electron microscopes. The fertilized eggs with narrow perivitelline space were found to be spherical and demersal, additionally containing small oil droplets in the vitelline membrane. Further, a bundle of adhesive filaments was observed to be present on one side of the fertilized egg. These filaments possessed remarkably high elasticity and were approximately 1-3mm in length. The size of the fertilized egg was determined to be about 1.49 ± 0.07mm (n=30). The outer surface appeared smooth, and adhesive filaments originating at different location of the surface of the envelope were found to be distributed around the egg envelope and were joined together to form a single long bundle in scanning electron microscopic observation. A peak-like structure formed of several straight wrinkles was observed around the micropyle. However, the complete structure of the micropyle could not be studied due to the depth at which it was located. Additionally, the total thickness of the egg envelope was ascertained to be approximately12.5-14.5㎛. The egg envelope consisted of two distinct layers, an outer electron dense layer and an inner lamellar layer, further consisting of 10 sublayers of varying thicknesses. Collectively, it was observed that the morphological characteristics of the fertilized egg, fine structures surrounding the micropyle, outer surface, adhesive structure consisting adhesive filaments, and sections of fertilized egg envelope displayed species specificity.

• Journal of the Korean institute of surface engineering
• /
• v.28 no.2
• /
• pp.67-76
• /
• 1995

The microstructure of 95wt.%Pb/5wt.%Sn and 63wt.%Sn/37wt.%Pb solders for flip chip bonding process has been characterized. Solders were deposited by thermal evaporation and reflowed in the conventional furnace or by rapid thermal annealing(RTA) process. As-deposited films show columnar structure. The microstructure of furnace cooled 63Sn/37Pb solder shows typical lamellar form, but that of RTA treated solder has the structure showing an uniform dispersion of Pb-rich phase in Sn matrix. The grain size of 95Pb/5Sn solder reflowed in the furnace is about $5\mu\textrm{m}$, but the grain size of RTA treated solder is too small to be observed. The microstructure in 63Sn/37Pb solder bump shows the segregation of Pb phase in the Sn rich matrix regardless of reflowing method. The 63Sn/37Pb solder bump formed by RTA process shows more uniform microstructure. These result are related to the heat dissipation in the solder bump.

• Journal of Korea Foundry Society
• /
• v.15 no.4
• /
• pp.408-415
• /
• 1995

Polycrystalline Al-Cu ribbons were produced by planar flow casting(PFC). Solidification behavior and microstructual changes of the ribbons have been investigated as a function of ribbon thickness and processing parameters. The solidification front velocity, V varies within the ribbon, decreasing with increasing the distance, S from the wheel-contact surface, as $V=17.6S^{-1}$. In Al-4.5wt%Cu alloy, rapid decrease in solidification velocity toward the free surface causes a change in solidification morphology from planar to cellular, and finally, to dendritic. The length and inclination of columnar grains solidified with planar front were related to the wheel velocity. The transition from particulate degenerate eutectic structure to regular lamellar eutectic structure was observed to be caused by a difference of the relative growth velocites of ${\alpha}-Al$ and ${\theta}$ during solidification in the Al-Cu eutectic alloy.

• Journal of the Korean Ceramic Society
• /
• v.22 no.4
• /
• pp.21-25
• /
• 1985

For studying the influence of addition of Polyvinyl alcohol (PVA)-montmorillonite complex on the hydration of Portland cement the PVA-montmorillonite derivatives were prepared in advance an characterized system-of Portland cement the PVA-montmorillonite derivatives were prepared in advance and characterized systema-tically. PVA with the polymerizationdegree ranging from 500 to 2000 have been intercalated into the lamellar structure of hydrated montmorillonites which were fractionated under 2㎛ by Stock's rule. In all cases the constant basal spacing of ∼20Å was determined whatever the molecular weight of PVA used. And the carbon chain orientation of PVA in the interfoliar space has been deduced to be parallel with bilayer structure.

• Macromolecular Research
• /
• v.14 no.6
• /
• pp.588-595
• /
• 2006

The morphology, structure and melting behaviour of cold-crystallized isotactic polystyrene (iPS) were studied by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). The polymer was found to crystallize according to the dual-lamellar stack model. The two populations of lamellae, along with a melting-recrystallization phenomenon, determined the appearance of multiple melting peaks in DSC traces. The annealing peak was attributed to the relaxation of a rigid amorphous phase, rather than to the melting of crystalline material.

• Journal of the Korean institute of surface engineering
• /
• v.12 no.3
• /
• pp.161-166
• /
• 1979

Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

• Fibers and Polymers
• /
• v.5 no.3
• /
• pp.245-251
• /
• 2004

Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate)s (P(TT-co-TN)s) with various copolymer composition were synthesized, and their chain structure, thermal property and crystalline structure were investigated by using $^1$H-NMR spectroscopy, differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD), respectively. It was found from sequence analysis that all the P(TT-co-TN) copolymers synthesized have a statistical random distribution of TT and TN units. It was also observed from DSC thermograms that the glass transition temperature increases linearly with increasing the TN comonomer content, whereas the melting temperature of copolymer decreases with increasing the corresponding comonomer content in respective PTT- and PTN-based copolymer, showing pseudo-eutectic melting behavior. All the samples melt-crystallized isothermally except for P(TT-co-66 mol % TN) exhibit multiple melting endotherms and clear X-ray diffraction patterns. The multiple melting behavior originates from the dual lamellar population and/or the melting-recrystallization-remelting. The X-ray diffraction patterns are largely divided into two classes depending on the copolymer composition, i.e., PTT and PTN $\beta$-form diffraction patterns, without exhibiting cocrystallization.

• Applied Chemistry for Engineering
• /
• v.16 no.2
• /
• pp.231-237
• /
• 2005

The sizes and structure of micelles and vesicles formed in ammonium dodecyl sulfate (ADS)/octadecyl trimethyl ammonium chloride (OTAC) mixed aqueous solutions were analyzed by small-angle neutron scattering. In micellar regions of pure ADS and OTAC aqueous solution, the spherical micelles were formed at given concentrations and their sizes were 40 and $61{\AA}$, respectively. The structure transition of pure micelles occurred above 300 mM due to the constancy of the intermicellar distance above 250 mM. The coexisting region of mixed micelles and vesicles in phase diagram of mixed system was also assured. It was investigated that vesicle formed spontaneously took a bilayer structure. The lamellar thickness of vesicles decreased with increasing concentration of vesicle samples. However, the size could not be determined for mixed micelle and vesicle above 100 nm due to limitation of low q ranges. Finally, The 9 mM solution of ADS mole fraction 0.9 (${\alpha}$=0.9) showed bilayer structure compared to phase diagram classified into mixed micelle.

• Journal of Power System Engineering
• /
• v.5 no.2
• /
• pp.63-70
• /
• 2001

To obtain the optimal condition of heat treatment of wear-resistant alloy, hardness and Charpy V-notch test have been performed with Co-based Stellite No.4, No.6 and Tribaloy 800 alloys, following by heat treatment at the various conditions. Heat treatment at $1250^{\circ}C$ for 1 hours caused the as-casted Tribaloy 800 with FCC crystal structure to transform to HCP structure and lamellar eutectic structure was disappeared, which did not influence on the hardness. Aging at $800^{\circ}C$ for 20 hours, following by $1250^{\circ}C$ for 2 hours heat treatment has enhanced hardness significantly, which is due to the precipitation of large amounts of Laves-phase. The hardness of Stellite alloys was increased by the aging at $800^{\circ}C$ to 5 hours, and was nearly constant by the aging over 5 hours. The toughness of Stellite alloys was a few influenced by the aging treatment.

• Journal of Korea Foundry Society
• /
• v.25 no.1
• /
• pp.30-35
• /
• 2005

The structures and mechanical property of the unidirectionally solidified Al-Co eutectic alloy were investigated. Al-Co eutectic alloy was unidirectionally solidified with growth rates(R) between I cm/hr and 10 cm/hr in the induction furnace maintaining the thermal gradient (G) at solid-liquid interface, $32^{\circ}C$/cm. The eutectic microstructure was varied with the growth condition(G/R ratio). When the G/R ratio was larger than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a lamellar structure was formed, But the G/R ratio was smaller than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a colony structure was formed. It was found that the interlamellar spacing(${\lambda}$) was dependent on the growth rate(R) with the relationship, ${\lambda}^{2}{\cdot}R=constant$. The microhardness of this eutectic alloy increased with increase in the growth rate.