• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.50-57
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• 2014

In this study, we investigated the physical properties of kraft pulps made from rice husk, peanut husk and garlic stems. These agricultural byproducts were collected individually, and then various pulps were manufactured from them by controlling active alkali, sulfidity, reaction time and the liquor ratio in the kraft pulping process in order to analyze the applicability of these agricultural byproducts as raw materials for kraft pulps. After kraft pulping, we measured yield, flake content, fiber length, fiber width and freeness of pulps, and the fiber shapes of the pulps were observed by using an optical microscope. When the higher active alkali, longer reaction time and lower liquor ratio were applied in kraft pulping process, reject content decreased and fiber yield increased. The pulp from garlic stems had the longest fiber length and that from rice husk showed the highest intial freeness. All of the pulps from agricultural byproducts showed higher initial freeness, shorter fiber length and the similar fiber width compared to OCC, BCTMP and hardwood BKP. The fibers of the pulps made from agricultural byproducts showed a similar shape to those of commercial pulps. It was concluded that these agricultural byproducts had a potential as raw materials to produce an alternative pulp to the commercial pulps.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.3
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• pp.63-69
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• 2012

The rice husk is one of the major agricultural residue in KOREA. In this paper, the effects of various pulping conditions on the properties of rice husk pulp and handsheets made of rice husk fiber were evaluated in order to utilize the rice husk as an alternative source for wood pulp. Two typical alkali pulping, such as soda pulping and Kraft pulping were applied with various conditions of the pulping processes. The higher effective alkali and higher pulping temperature resulted in the higher efficiency in removal of lignin and ash, which leaded to the higher strength properties of handsheets made of rice husk fiber, but the lower yield of rice husk pulp. The better efficiency in production of rice husk pulp and the stronger handsheets were obtained by the Kraft pulping.

• Journal of the Korean Wood Science and Technology
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• v.33 no.3 s.131
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• pp.79-88
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• 2005

This research studied the utilization of the bed log wastes as a papermaking grade pulp. Five different bed log samples from shiitake mushroom (Lentinus edodes (Berk.) Sing) cultivation were collected by the cultivating periods of 1 to 5 years. The wood chemical composition and the characteristics of kraft pulping of each sample were investigated. The results of chemical composition showed that the rate of carbohydrate (glucose and xylose) content in sapwood was decreased as the cultivation period was increased. In heartwood, there was no significant difference. The screening yield of non-cultivated bed log from kraft pulping was higher than that of cultivated one, but the reject of cultivated one, especially for 5 year-cultivated, was lower than non-cultivated bed log. The fiber length and width was continuously decreased as the cultivation period was increased. Therefore, the freeness of the pulp from the cultivated bed log was sharply decreased comparing to non-cultivated due to the fiber cutting and the increased fine content. The dry strengths were increased according to the increasing addition level of bed log kraft pulp to KOCC and non-cultivated wood pulp. From the overall results, the pulp from 5 years cultivated bed log can be reasonably used if it is mixed with long fiber pulp for advantages such as reducing beating time.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.37 no.3
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• pp.74-80
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• 2005

The compositions of residual extractives in woodmeal, unbleached and oxygen-delignified aspen kraft pulps were investigated with gas chromatography(GC) and gas chromatography-mass spectrometry (GC-MS) with focus on fate of extractives in kraft pulping and oxygen delignification. Steryl esters and shorter retention time (shorter than palmitic acid) extractives were main extractives in aspen woodmeal. Shorter retention time extractives were well removed in kraft pulping. Sterol esters were hydrolyzed to sterols and fatty acids. Sterols and fatty acids were two major extractives classes in unbleached kraft pulps. Linoleic acid was main fatty acids in unbleached pulps compared with palmitic acid which is generally found in aspen woodmeal. Sterolsand fatty acids were also two major extractives classes in oxygen-delignified kraft pulps. However, linoleic acid was well removed in oxygen delignification.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.31 no.2
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• pp.8-14
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• 1999

A screening has been performed to find hyper-ligninolytic fungi, which degtrade beech and pine lignin extensively in order to broaden the understanding of the ligninolytic enzymes elaborated by various white-rot fungi. One hundred and twenty two ligninolytic strains were selected from decayed woods with a selective medium for screening ligninolytic wood-rotting fungi. Two of them, Phanerochaete sordida YK-624 and YK-472, showed much higher ligninolytic activity and selectivity in beech-wood degradation than typical lignin-degrading fungi, phanerochaete chrysosporium and Coriolus versicolor. They also degraded birch dioxane lignin and residual lignin in unbleached kraft pulp(UKP) much more extensively than P. chrysosporium and C. versicolor. During fungal treatment of beech wood-powder, the fungus strain P. sordida YK-624 showed higher activity of extracellular manganese peroxidase (MnP) in the medium than P. chrysosporium. It also showed MnP activity, which would not be lignin peroxidast during treatment of oxygen-bleached kraft pulp(OKP) and under enzyme-inducing conditin.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.295-303
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• 2006

The pulp yield was improved by about 4.5-5% when polysulfide (PS) and anthraquinone (AQ) were added to the kraft cooking liquor (white liquor). The exchange of the black liquor with fresh white liquor further increased the yield. The highest pulp yield was obtained when the PS cooking liquor containing 70% of total active alkali (AA) and 100% of AQ was used from the beginning of the reaction and the black liquor was exchanged with fresh white liquor containing the residual 30% of AA just after temperature reached $135^{\circ}C$. There was a good correlation between kraft pulp yields of a hardwood species and the ratios of the amount of xylose to glucose (X/G ratio), liberated by an acid hydrolysis of the pulps. However, the correlation was dependent on raw material wood species. Therefore, it is required in advance to establish a correlation between the yields and X/G ratios for raw material wood species of a target pulp in order to estimate pulp yield using X/G ratio. The X/G ratios of relatively high yield pulps showed higher values than those expected from the correlation. In a mill trial, the superiority of the PS-AQ isothermal cooking (ITC) process over the kraft ITC process was confirmed by examining X/G ratio of pulps obtained. The pulp yield in the PS-AQ ITC process was estimated at about 57.0%. This yield is very high, which indicates that reaction conditions of the PS-AQ ITC process are optimal.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.1
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• pp.1-10
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• 2014

Xylanase (X) derived from Aurreobasidium pullulans and laccase-mediator system (LM) using Trichophyton sp. LKY-7 laccase (TrL) and N-hydroxy-2-pyridone analogue (NHP) as a mediator were applied in hardwood kraft pulp (HwKP) bleaching. The individual and the synergistic effects of X and LM stage were investigated in the enzymatic bleaching of HwKP. Also, the effects of subsequent alkaline extraction (E) and alkaline/hydrogen peroxide treatment (P) were examined. In X or LM treatment alone, an appreciable bleaching effect of HwKP was not observed, whereas subsequent E or P stage enhanced the increase of brightness and the decrease of kappa number. Especially, P stage significantly enhanced the bleaching effect of pulp. Bleaching of HwKP with XLM sequentially gave significantly higher pulp brightness and lower kappa number than that obtained after the treatment of HwKP with X+LM simultaneously. When HwKP was sequentially treated with XLM followed by P stage, the brightness increased by about 11% ISO and the kappa number decreased by about 3.6 in comparison with the initial pulp. Xylanase and laccase were strongly inactivated by NHP both in the absence and the presence of pulp.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.04a
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• pp.131-138
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• 2011

Currently, many forest residues have been generated by the National Forest Management Operation. Unfortunately, most of the forest residues are supposed to be used as raw materials for burning fuels like wood pellets. Even though the forest biomass must be effectively used for making high value-added products, they may be subject to disposable raw materials for wood pellets. Wood pellets are regarded as burning fuels with less contribution to the decrease in carbon gas emission, compared to raw materials for kraft pulps. In this study, we studied whether or not forest biomass mixed with various ages and, species could be used as raw materials for kraft pulps.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.10a
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• pp.143-149
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• 2011

In recent, many forest residues have been generated by the National Forest Management Operation. Unfortunately, most of the forest residues are supposed to be used as raw materials for burning fuels like wood pellets. In this study, we investigated whether or not this forest biomass mixed in various ages and species could be used as raw materials for making kraft pulps in a view of optical properties.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.291-294
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• 2006

Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.