• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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• pp.143-149
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• 2011

In recent, many forest residues have been generated by the National Forest Management Operation. Unfortunately, most of the forest residues are supposed to be used as raw materials for burning fuels like wood pellets. In this study, we investigated whether or not this forest biomass mixed in various ages and species could be used as raw materials for making kraft pulps in a view of optical properties.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.285-290
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• 2006

As an alternative method to solve air pollution problem and difficulty of pulp bleaching of kraft pulping process, NaOH-Urea pulping was applied. The properties of NaOH-Urea pulp were compared to those of NaOH and kraft pulps. Addition of urea in low alkali charges retarded delignification rate compared to NaOH pulping. But, in high alkali application, delignification was significantly enhanced not from the addition of urea but from the high alkalinity. It was disclosed that urea did not participate on delignification reaction by the experiment using lignin model compound. Compared to paper strengths at the same level of sheet density, NaOH-Urea pulp gave as almost same breaking length and tensile index as those of kraft pulp. Especially tensile energy absorption and burst index were higher than those of kraft pulp.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.291-294
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• 2006

Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2015년도 제46회 하계학술대회
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• pp.1202-1203
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• 2015

This paper describes the development of HVDC ${\pm}500kV$ polypropylene laminated paper (PPLP) mass-impregnated (MI) type cable system for HVDC transmission lines. As you know, mass-impregnated type cable generally has only insulating layer with the Kraft paper impregnated with a high-viscosity insulating compound. But polypropylene laminated paper is made of a layer of extruded polypropylene (PP) film sandwiched between two layers of Kraft paper. Thanks to PP film and its combination with Kraft paper, PPLP has higher AC, Impulse (Imp.) and DC breakdown (BD) strengths as well as lower dielectric loss than conventional Kraft paper insulation. In addition, Kraft MI cable has a limitation for the maximum conductor temperature as $55^{\circ}C$ But this PPLP MI cable has higher maximum conductor temperature than that of Kraft MI cable due to advantage of oil drainage characteristics. It is the most economic type of cable for HVDC transmission. Also HVDC ${\pm}500kV$ PPLP MI cable system was developed including land joints and outdoor-terminations. In order to prove the mechanical and electrical performances, the type test was carried out according to CIGRE recommendations. A full scale cable system has been tested successfully. And additional load cycle and polarity reversal tests on the cable system showed a higher performance compared with a similar mass impregnated paper cable.

• 환경생물
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• 제17권2호
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• pp.191-198
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• 1999

침엽수와 활엽수 펄프내의 리그닌(lignin) 제거 효과를 개선하기 위해 호알칼리성 균류인 Cephalospotium sp. RYM-202의 xylanase를 표백 전처리하고 이에 의한 펄프의 표백 증진 효과를 조사하였다. 두 종류의 펄프 모두 5$0^{\circ}C$에서 효소반응을 수행하였을 때 펄프내 xylan의 가수분해가 가장 높게 나타났다. 펄프내 xylan의 가수분해를 위한 효소의 최적 pH는 8.0이었으며, pH 9.0에서도 최대활성의 90%이상이 유지되었다. 각각의 펄프 재료에 효소를 전처리한 결과 표백(리그닌 제거)과정의 증진 효과를 보였으며, 침엽수와 활엽수의 kappa number는 각각 3.7과 2.0 ISO units 만큼 감소되었다. 아울러 효소처리 혹은 효소 미처리 펄프를 각각 표백한 후 수초지를 제조하여 종이의 물성을 상호 비교한 바, 효소처리는 종이의 섬유 구조에 큰 영향을 끼치지 않는 것으로 나타났다. 이러한 결과들은 호알칼리성 Cephalospotium sp. RYM-202의 알칼리내성 xylanase가 알칼리 조건하에서의 펄프 전처리 과정에 매우 적합함을 의미한다.

• 한국전산구조공학회논문집
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• 제24권1호
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• pp.17-22
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• 2011

본 논문에서는 Tsai-Hill기준을 변형하여 조합하중을 받는 이방성재료의 강도를 정확히 예측할 수 있는 새로운 파손기준을 제안하였다. 이 기준의 유효성은 조합하중을 받고 있는 Kraft 판지에 대한 실험결과와 비교하여 나타내었다. 재료축 방향의 전단응력이 주어진 경우, Tsai-Hill기준은 매우 보수적인 결과를 보여주고 있으나, 본 해석에서 제안한 기준은 실험 결과와 잘 일치하고 있다. 또한 Tan-Cheng기준과 비교하여 강도를 더욱 단순하게 해석할 수 있는 능력을 갖고 있다.

• Journal of the Korean Wood Science and Technology
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• 제17권4호
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• pp.44-56
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• 1989

Kraft pulp 폐액에 다량 존재하는 lignin을 회수 이용하기 위하여 폐액을 조제하고 유기용매로 추출 정제하여 각 fraction별로 $^{13}C$-NMR 및 IR 스펙트라로 측정분석하였다. 그 결과 Kirk 방법보다는 M$\ddot{o}$rck 방법으로 정제한 시료가 lignin의 특징적인 signal들을 많이 나타나고 있는 점과 특히 MCS fraction은 방향핵이나 측쇄의 signal들이 잘 나타나고 있으며, KLI fraction에서는 methoxyl기와 C-${\beta}$의 signal이 잘 나타나고 있는 것을 알 수 있었다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.317-321
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• 2006

The investigation of the formation of organic sulfur compounds (i.e., odor species), mainly methyl mercaptan and demethyl suifide, during kraft pulping has been conducted, in which both hardwood and softwood species were used. It was discovered that there is an organic sulfur compounds formation phase transition point with respect to delignification extent. The transition point occurs at a kappa number of approximately 35 and 20 for softwoods and hardwoods, respectively. The results also showed that both low sulfidity and anthraquinone (AQ) addition are helpful to control the formation of theses organic sulfur compounds during kraft pulping. Whereas Hexenuronic acid (HexA) has contribution to Kappa number, the extended delignification not only lead to low pulp yield, but also be adverse to odor control. A significant in-digester odor reduction can be achieved if the pulping is to be terminated before phase transition point and combined with AQ addition.

• Journal of the Korean Wood Science and Technology
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• 제18권2호
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• pp.25-35
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• 1990

To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.

• Journal of the Korean Wood Science and Technology
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• 제33권3호통권131호
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• pp.79-88
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• 2005

연구는 폐표고목을 제지용 원료로 활용하기 위한 기초자료로 1년부터 5년 동안 재배한 표고골목을 이용하여 목재 성분 조성과 크라프트 펄프화 특성을 평가하였다. 그 결과 화학조성의 경우 변재에서는 재배기간이 증가함에 따라 글루코스와 자일로스의 감소가 크게 나타났으나 심재부에서는 큰 차이가 나타나지 않았으며 정선수율과 리젝트 함량 모두 재배기간이 증가함에 따라 감소하였다. 펄프 특성에서도 재배기간 증가에 따라 섬유장과 폭, 여수도는 감소하였으며 폐표고골목 크라프트 펄프를 국산 폐골판지에 첨가 시 종이의 건조 강도가 향상되었다. 이상의 결과로 폐표고목 크라프트 펄프를 다른 장섬유 펄프와 혼합사용 시 강도 향상과 고해 에너지 감소를 기대할 수 있을 것으로 사료된다.