• Title/Summary/Keyword: kinetic energies

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Evaluations of the Equations of State and Thermodynamic Quantities of Fluid Metal at High Temperatures and Densities

  • Shin, Hyun-Joon;Hong, Jong-Ha;Oh, Byung-Wan
    • Nuclear Engineering and Technology
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    • v.10 no.3
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    • pp.127-136
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    • 1978
  • We have applied the temperature dependent Thomas-Fermi theory to evaluate the equations of state, chemical potentials, entropies, % ionizations, total energies and kinetic energies of an atom, and seveal thermodynamic quantifies of one of metallic substance, Na, for a density range of 0.1$\rho$$_{0}$ ~ 10$\rho$$_{0}$, where $\rho$$_{0}$ is the normal density of Na at its melting point, and for a temperature range of 60.88Ryd. ~0.0216 Ryd., where the system is expected to be in a gaseous or liquid state. The main interest of present work lies in physical quantities at high temperatures and high densities, however, we have included those quantities of Na at sufficiently low temperatures and low densities to show that the approximation is not so crude as one might expect. Particularly, at high temperatures, the calculated equations of state, kinetic energies of an atom, chemical potentials and entropies are compared with those, of an ideal Fermi gas. The results show that, at high temperatures, the agreement seems good for chemical Potentials. However, the differences in, entropy, kinetic energy of an atom, and equation of state are not negligible even at such high temperature as $textsc{k}$T=60.88Ryd.

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Numerical Analysis on the Turbulent Mixing Flow Field of $45^{\circ}$ Impinging Round Jet ($45^{\circ}$ 원형충돌분류의 난류혼합유동장에 대한 수치해석)

  • Kim, J.K.;Oh, S.H.
    • Journal of Power System Engineering
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    • v.15 no.3
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    • pp.38-45
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    • 2011
  • The computational flow numerical analysis was introduced to predict thc turbulent characteristics in the mixing flow structure of $45^{\circ}$ impinging round jet. This analysis has been carried out through the commercial fluent software. Realizable(RLZ) k-${\varepsilon}$ was used as a turbulent model. It can be known that mean velocities analysed through RLZ k-${\varepsilon}$ turbulent model comparatively predict well the experiments and show well the elliptic shape of mixing flow structure in the Y-Z plane, but analysed turbulent kinetic energies show somewhat differently from the experiments in certain regions.

Kinetic Study for the Reaction of Pyridine under High Pressure (고압하의 피리딘 반응에 대한 속도론적 연구)

  • 김명자
    • The Korean Journal of Food And Nutrition
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    • v.16 no.4
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    • pp.321-327
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    • 2003
  • The reaction rates of 4-ethyl pyridine with p-methyl benzylbromide have been measured by conductometry in acetonitrile, and the rate constants of these reactions are determined in accordance with various temperatures (20, 25, 30$^{\circ}C$) and pressures (1, 200, 500, 1000 bar). The rate constants increased with the higher pressure and temperature. The activation energies and activation parameter values of these reactions are calculated by determination of the rate constants the same. The activation volume, activation compressibility coefficient and the activation entropy are all negative. The result of kinetic studies for the pressure show that this reaction proceeds in typical bimolecular nucleophilic substitution reaction.

Crystallization Behavior of $CaO.Al_2O_3.2SiO_2$ Glass with Kinetic Parameters (열분석에 의한 $CaO.Al_2O_3.2SiO_2$ 유리의 결정화 고찰)

  • 이승한;류봉기;박희찬
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1545-1551
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    • 1994
  • Various kinetic parameters of the nucleation and crystallization in anorthite glass (CaO.Al2O3.2SiO2) were calculated by nonisothermal differential thermal analysis. Base glass and glass with TiO2 were prepared by melting. In base glass, the temperature where nucleation can occur ranges from 85$0^{\circ}C$ to 9$25^{\circ}C$ and the temperature for maximum nucleation was 900$\pm$5$^{\circ}C$. In glass with TiO2, the nucleation temperature range was 800~875$^{\circ}C$ and the maximum nucleation temperature was 850$\pm$5$^{\circ}C$. Kissinger equation, Bansal equation, and modified Ozawa equation were used for calculating activation energy for crystallization, Ec. The results showed the same activation energies for both glasses with and without TiO2 in the different equations. The shape of maximum exotherm peak and Ozawa equation were used for Avrami exponent, n. The n value for each glass was 2, indicating that each glass crystallized primarily by bulk crystallization.

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A Kinetic Study on the Electrodeposition of Ni-Zn-P Ternary Alloys onto a Steel (강상에 니켈-아연-인 삼원 합금도금에 관한 속도론적 연구)

  • 안종관;이응조
    • Journal of the Korean institute of surface engineering
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    • v.28 no.4
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    • pp.199-206
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    • 1995
  • A kinetic study on the electrodeposition of Ni-Zn-P ternary alloys onto a steel in chloride solutions was carried out using a rotating disc electrode. The coatings were characterized using SEM/EPMA and A. A. analysis. The results showed that the plating rates of three components were increased with applied potential, disc rotating speed and temperature. The activation energies of Ni, Zn and P of the coatings were 6.1, 5.1 and 8.0 kcal/mole respectively. Therefore, the deposition rates were controlled partly by surface electrochemical reaction and partly by mass transport. As the potential, temperature of bath and rotating speed of cathode disc were raised, the vol. % ratios of Ni and P of coating layer were increased but that of Zn decreased. The effect of coating parameters on the surface morphology was also examined.

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An Analysis of Plastic Stress in Square Bar Impacting Plate (평판에 충동하는 사각봉의 소성응력해석)

  • 김기선;조재웅;최두석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.5
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    • pp.198-204
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    • 2004
  • Dynamic fracture is investigated in plate applied by impacting bar. Numerical simulations of the experiments are made by using a finite element method(FEM) code, LS-DYNA. The eroding surface-to-surface contact allows between impacting bar and impacted plate. The occurrence of hourglass deformations in an analysis can invalidate results and hourglass energy is minimized to obtain the good accuracy of result. Total, internal and kinetic energies, von Mises plastic stress and X,Y,Z velocities of impacting bar are analyzed in this study.

Comparing the statistics of isothermal compressible turbulence in simulation : Single versus Double forcing

  • Yoo, Hyun-Ju;Cho, Jung-Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.108.1-108.1
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    • 2011
  • Turbulence is ubiquitous in astrophysical fluids such as the interstellar medium(ISM) and the intracluster medium(ICM). There are many driving mechanisms which can inject energy into the fluid in variety driving scales, But the plausible driving scale of ISM/ICM turbulence are yet unknown. Therefore, understanding different statistical properties between turbulence with single driving scale and turbulence with double driving scale is required. In this work, we performed 3-dimensional isothermal compressible, magnetohydrodynamic(MHD) turbulence simulations. We drive turbulence in the Fourier space in two ranges, 2

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Femtosecond Photoelectron Imaging of N2 at 410 nm

  • Guo, Wei;Wei, Shanshan;Lu, Xingqiang;Wang, Li
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3693-3696
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    • 2010
  • We experimentally measure the kinetic energy and angular distributions of photoelectrons of $N_2$ as a function of 410 nm femtosecond laser intensity by using velocity map imaging technique. The strong-field multiphoton ionization of molecules shares many of the characteristics with those of atoms. Electron kinetic energies are nearly independent of laser intensities. The independence suggests that the electron peaks in the photoelectron spectrum actually result from a two-step process, indicative of the occurrence of real population in the intermediate states. The relative amplitudes of electron peaks indicate that in the two-step process, nonresonant population transfer dominates for low intensities, while resonant population transfer dominates for higher intensities.

Analysis of Airflow due to the Configuration of Automotive Diffuser (자동차 디퓨저의 형상에 따른 공기흐름의 해석)

  • Choi, Kyekwang;Cho, Jaeung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.11
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    • pp.16-22
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    • 2020
  • This study was aimed at analyzing the velocity and pressure changes in the airflow corresponding to different configurations of a diffuser for three types of cars. According to the flow results of the three automotive models, in model 3, the vortex was formed slightly upward on the outlet plane, whereas in models 1 and 2, the vortex was generated lower than that in model 3. The values of the pressure distribution in model 3 were larger than those for models 1 and 2 on the planes located at the same distance from the end of the rear part. The maximum turbulent kinetic energies in models 1 and 2 occurred at a location lower than that in model 3. The shape corresponding to the airflow that enhanced the driving performance was determined through the flow analysis.

The finite Element Formulation and Analysis of the Dynamic Flexible Timoshenko Beam (유연한 Timoshenko 빔의 동역학적 유한요소 정식화 및 해석)

  • Liu Zhi-Qiang;Yun Seong-Ho
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.17-24
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    • 2004
  • This paper established the dynamic model of a flexible Timoshenko beam with geometrical nonlinearities subject to large overall motions by using the finite element method. The equations of motion are derived by using Hamilton principle based on expressing the kinetic and potential energies of the flexible beam in terms of generalized coordinates. The nonlinear constraint equations are adjoined to the system equations of motion by using Lagrange multipliers.

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