• 한국세라믹학회지
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• 제29권1호
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• pp.9-14
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• 1992

Some of non-isothermal analysis methods are applied to CaO-MgO-Al2O3-SiO2 glass system to find the kinetics parameters of crystallisation, activation energy, Avrami component and frequency factor. The results using the non-isothermal analysis were compared to that of microstructure experiment. Analysis of the result has enabled to some methods to be to recommend as being the most appropriate equation to use in a glass system. It was shown that in the thermal analysis using the non-isothermal method of Kissinger, Augis-Bennett, Bansal, and Marotta, the calculation of activation energy is not much different, while Avrami component and frequency factor are different from applied each methods.

• 한국환경보건학회지
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• 제21권4호
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• pp.17-23
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• 1995

As a basic experiment to develope biological pretreatment proces~ in water treatment, the experiments on biodegradability and isothermal adsorption of activated carbon were performed on refractories such as humic acid, $NH_3-N$, phenol and ABS which caused the problems in drinking water treatment. Also, the treatabilities on humic acid were examined in the continuous flow type reactors. The removal efficiencies of humic acid, $NH_3-N$, phenol and ABS in the biodegradable experiments for 5 days were 20.1%, 73.4%, 91.7% and 97.5%, respectively. In the isothermal adsorption test of refractories on activated carbon to be used as a media in the continuous flow type reactors, ABS and phenol are adsorbed easily, but humic acid and $NH_3-N$ are difficult to be done. The removal efficiencies of humic acid in granular activated carbon(GAC) reactor were about 7-8% higher than in biological activated carbon(BAC) reactor. The removal efficiencies of humic acid in biological fluidized bed(BFB) reactor were about 30% in GAC media, but were almost zero in sea sand media.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.43-47
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• 2002

Weight loss experiments have been performed for unidirectional carbon fiber/epoxy laminates under both isothermal and cyclic thermal conditions. It was found that weight losses were the result of both specimen-geometry dependent oxidative degradation and volumetric geometry dependent thermal degradation. Thermal degradation was found to play a major role in the overall weight loss process, and photomicrographs of cross-sectioned, aged specimens confirmed this fact. A method to predict the effect of isothermal environment on the weight loss was introduced and found to be in good agreement with experimental data at temperatures near Tg (glass transition temperature).

• Elastomers and Composites
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• 제53권1호
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• pp.1-5
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• 2018

In the current research, the curing kinetics of a mixture system consisting of a Bisphenol-A type vinyl ester resin and styrene monomer was studied. Methylethylketone peroxide and cobalt octoate were used as the polymerization initiator and accelerator respectively. Thermograms with several different heating rates were obtained using non-isothermal differential scanning calorimetry. Activation energy values analyzed by the Flynn-Wall-Ozawa isoconversional method showed a three-step change with conversion ${\alpha}$: a slight decrease initially for ${\alpha}$ < 0.1, a constant value of 47.9 kJ/mol in the range 0.1 < ${\alpha}$ < 0.7, and a slow increase for 0.7 < ${\alpha}$. When assuming a constant activation energy of 47.9 kJ/mol, an autocatalytic model of the Sestak-Berggren equation was considered as the proper mathematical model of the conversion function, indicating an overall order of 1.2.

• BMB Reports
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• 제35권3호
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• pp.302-305
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• 2002

Kinetic and thermodynamic studies have been made on the effect of the inosine product on the activity of adenosine deaminase in a 50 mM sodium phosphate buffer, pH 7.5, at $27^{\circ}C$ using UV spectrophotometry and isothermal titration calorimetry (ITC). A competitive inhibition was observed for inosine as a product of the enzymatic reaction. A graphical-fitting method was used for determination of the binding constant and enthalpy of inhibitor binding by using isothermal titration microcalorimetry data. The dissociation-binding constant is equal to $140\;{\mu}M$ by the microcalorimetry method, which agrees well with the value of $143\;{\mu}M$ for the inhibition constant that was obtained from the spectroscopy method.

• 동력기계공학회지
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• 제11권4호
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• pp.98-102
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• 2007

In this study, a measurement method of leakage flow-rate for pneumatic driving apparatus is proposed. The existing measurement methods of leakage flow-rate of air need disassemble the test component. Therefore, there is no effective method to measure the leakage flow-rate while operating pneumatic driving apparatus. In this study, the leakage flow-rate is measured from the pressure change in an isothermal chamber that can realize isothermal conditions by stuffing the steel wool into it. Therefore, a wide range of flow-rate could be measured only from the pressure response and the leakage flow-rate can be measured during operating pneumatic driving apparatus. The effectiveness of the proposed method is proved by experimental results.

• 상하수도학회지
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• 제25권2호
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• pp.241-248
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• 2011

This research was performed to evaluate the efficacy of phosphate removal from wastewater by surface-modified wood powder and to clarify the removal mechanisms. In this work, Pinus rigida which is abundant in Korea and has little economic value was used in preparation of the wood powder as a sorbent material. The experiments were carried out in 2 phases, isothermal adsorption test and column test. The results of adsorption test fitted well both the Langmuir and Freundlich isothermal equations. Adsorption capacity was highest with the bark powder followed by the mixed powder(50% bark powder and 50% woody powder) and woody powder. Phosphate removal efficiency was as high as 98% at initial phosphate concentration of 50mg/L. Specific surface area of the powder increased following the experiment and phosphate removal was speculated to occur through adsorption mechanism. Energy dispersive X-ray analysis(EDXA) revealed that the phosphate adsorbed onto the surface of the powder was in the form of strengite($FePO_{4}$).

• Journal of Welding and Joining
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• 제19권4호
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• pp.423-428
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• 2001

The bonding phenomena of Ni base single crystal superalloy. CMSX-4 during transient liquid phase(TLP) bonding was investigated using MBF-80 insert metal. Bonding of CMSX-4 was carried out at 1,373∼1,548K for 0∼19.6ks in vacuum. The (001) orientation of each test specimen was aligned perpendicular to the bonding interface. The dissolution width of base metal was increased when the bonding temperature and holding time were increased. The eutectic width diminished linearly with the square root of holding time during isothermal solidification process. Borides were formed in the bonded layer during TLP bonding operation. The solid phase grew epitaxially into the liquid phase from substrates and single crystallization could be readily achieved during the isothermal solidification.

• 한국분말재료학회지
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• 제17권2호
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• pp.154-159
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• 2010

In this study, the sintering behavior of (Nd, Dy)-Fe-B powder which fabricated by strip-casting was investigated with various sintering temperatures and holding times. The relative density over 99% could be obtained by both sintering at $1070^{\circ}C$ for 1h and sintering at $970^{\circ}C$ for 20h. The grain growth was observed in sintered specimen at $1050^{\circ}C$ compared to one at $970^{\circ}C$. The isothermal sintering process below $1000^{\circ}C$ led to suppress grain growth showing the improved magnetic properties. The phase transformation of Nd-rich was confirmed by X-ray diffraction pattern.

• 소성∙가공
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• 제9권1호
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• pp.66-71
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• 2000

The present study tackles the metallurgical subjects involving the thin slab-direct hot rolling process, i.e. mini-mill process. In order to clarify the effect of chemical composition of steel and MnS precipitation behaviors on the development of edge cracking during hot rolling, the content of manganese and sulfur in low carbon steel was varied and the isothermal treatment prior to roughing was applied. Edge cracking during roughing in the hot-rolling process of mini-mill was effectively prevented by means of the isothermal treatment at 115$0^{\circ}C$ for 5 minutes in the 0.4% manganese steel containing sulfur lower than 0.013%. With the increase in manganese content in low carbon steel, coarser MnS developed. The edge cracking index which denotes the total length of edge crack per unit edge-length of rolled specimens was proposed in this paper. It was found that the edge cracking index linearly decreased with the increase in the ratio of MnS.