• 대한화학회지
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• 제56권1호
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• pp.7-13
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• 2012

Ultrasonic velocities (u) for binary mixtures of propylene carbonate (PC) (1) with benzene and substituted benzenes (2) viz. benzene, ethylbenzene, o-xylene and p-xylene have been measured at 288.15-308.15 K over the entire range of composition. The experimental values of ultrasonic velocities (u) have been utilized to calculate isentropic compressibility ($K_s$), intermolecular free length ($L_f$), acoustic impedance (Z).

• Korean Chemical Engineering Research
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• 제55권5호
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• pp.668-678
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• 2017

Intermolecular interactions were studied for binary mixtures of 2-propanol + cyclohexane, n-hexane, benzene, toluene, o-, m- and p-xylenes by measuring ultrasonic speeds (u) over the entire range of composition at 298.15 K and 308.15 K. From these results the deviation in ultrasonic speed was calculated. These results were fitted to the Redlich-Kister equation to derive the binary coefficients along with standard deviations between the experimental and calculated data. Acoustic parameters such as excess isentropic compressibility ($K_s^E$), intermolecular free length ($L_f$) and available volume ($V_a$) were also derived from ultrasonic speed data and Jacobson's free length theory. The ultrasonic speed data were correlated by Nomoto's relation, Van Dael's mixing relation, impedance dependence relation, and Schaaff's collision factor theory. Van Dael's relation gives the best prediction of u in the binary mixtures containing aliphatic hydrocarbons. The ultrasonic speed data and isentropic compressibility were further analyzed in terms of Jacobson's free length theory.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1686-1692
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• 2012

Densities (${\rho}$), Viscosities (${\eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${\Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${\Delta}K_s$, deviation in viscosity ${\Delta}{\eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 동계학술발표대회 논문집
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• pp.157-164
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• 2008

The temperature-entropy diagram of water or vapor displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. On general T-s chart of water, there are temperature, pressure, quality, specific volume, specific enthalpy, specific entropy. However, various state and process values besides above properties can be plotted on T-s diagram. In this study, we developed the software drawing twenty six kinds of properties, that is temperature, pressure, quality, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, coefficient of viscosity, kinematic coefficient of viscosity, thermal conductivity, prandtl number, ion product, static dielectric constant, isentropic exponent, velocity of sound, joule-thomson coefficient, pressure coefficient, volumetric coefficient of expansion, isentropic compressibility, and isothermal compressibility. Also, this software can analyze and print the system values of mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, and reversible work. Additionally, this software support the functions such as MS-Power Point.

• Journal of Hydrospace Technology
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• 제1권1호
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• pp.14-28
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• 1995

The hydrodynamic problem when the pressurized bag submerges partially into water and oscillates was formulated by Lee(1992), and the solution method was given, In his formulation, however, the compressilbility of air was neglected and the pressure inside the bag was assumed to be constant. In this paper, the formulation was done including the air compressibility and the wall to block fling around phenomenon. The compression process was assumed to be a isothermal process for a static problem, isentropic process for a dynamic problem. And the stability was analyzed for the static problem. Through the various numerical calculations, the forces and the shape of the bag were compared with those of a rigid body case, constant pressure case, and variable pressure case.

• 대한조선학회논문집
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• 제30권3호
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• pp.51-61
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• 1993

공기가 차 있는 백이 물에 부분적으로 잠겨서 동요할 때, 유체역학적 문제의 정식화가 Lee(1992)에 의해서 이루어졌으며, 선형항에 대한 계산방법이 주어졌다. 그러나 그의 정식화과정에서는 백내의 압력을 일정하다고 가정하여 공기의 압축성 효과가 무시되었다. 본 논문에서는 공기의 압축성을 고려하여 이 문제를 다시 정식화하였다. 이때 공기의 압축과정은 정역학 문제시에는 등온과정, 동역학 문제시에는 단열과정으로 가정하였다. 또한 정역학 계산시 문제가 되었던 평형상태의 안정성이 다루어졌다. 수치계산을 통하여 강체의 경우, 일정 압력, 변동 압력의 경우에 대한 비교검토가 이루어졌다.

• 대한화학회지
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• 제56권4호
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• pp.424-430
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• 2012

Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume $V^E$, viscosity deviation ${\Delta}{\eta}$, refractive index deviation ${\Delta}n_D$, deviations in speed of sound ${\Delta}u$, deviations in isentropic compressibility ${\Delta}k_s$ and excess intermolecular free length ${\Delta}L_f$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.

• Korean Chemical Engineering Research
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• 제56권5호
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• pp.663-678
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• 2018

Refractive index and speeds of sound for the binary mixture of isomer of butanol (1) + cyclohexane, benzene and toluene (2) were measured at 308.15 K. The measured data were used to calculate deviation in refractive index ${\Delta}n$, ultrasonic speed ${\Delta}u$, isentropic compressibility $K_s^E$, available volume $V_a$, excess intermolecular free length $L_f$ and molecular association $M_A$. All the derived properties were correlated with polynomial equation. Ultrasonic speed data were predicted using various empirical correlations like Nomoto, van Dael, impedance dependence and theoretically with Schaaff's collision factor theory (CFT). Jacobson free length theory (FLT) was used to calculate $L_f$. The measured refractive index was also correlated with various mixing rules. The deviation in refractive index Δn and ultrasonic speed ${\Delta}u$ was used to determine the intermolecular interactions.