• Title/Summary/Keyword: iron state

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Effects of Heat-Treatment and the Addition of Copper on the Processing Window of 3.6wt%C-2.5wt%Si Austempered Ductile Cast Iron (3.6wt%C-2.5wt%Si 오스템퍼드 구상흑연주철의 프로세싱 윈도우에 미치는 열처리 및 구리 첨가의 영향)

  • Kwon, Do-Young;Oh, Jeong-Hyeok;Kim, Gi-Yeob;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.41 no.4
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    • pp.331-341
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    • 2021
  • The effects of austempering temperature, austenitizing temperature and time, added copper content and prior heat-treatment on the processing window of 3.6wt%C-2.5wt%Si ductile cast iron during austempering. The maximum processing window was obtained at 350℃ of austempering temperature. The processing window was increased with increased austenitizing temperature from 850 to 900℃; however, it decreased at 950℃. The processing window was increased with increased austenitizing time from 0.5 to 2 hours and rather decreased for 4 hours. The optimum condition of austenitizing was obained at 900℃ for 2 hours. The processing window was increased with copper content added in the range of 0.0~0.8wt%. The processing window was increased by prior normalizing heat-treatment and decreased by prior annealing in comparison with that for the as-cast state,

The Physicochemical and Optical Characteristics of FeaSibCcHd Films (FeaSibCcHd 박막의 물리·화학 및 광학적 특성)

  • Kim, Kyung-soo;Jean, Bup-Ju;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.105-111
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    • 1999
  • When the preparation method of iron silicide films possess the annealing process, the interfacial state of the films is not fine. The good quality films were obtained as the plasma was used without annealing processing. Since the injected precursors were various active species in the plasma state, the organic compound was contained in the prepared films. We confirmed the formation of Fe-Si bonds as well as the organic compound by Fe and Si vibration mode in Raman scattering spectrum at $250cm^{-1}$ and Ft-IR. Because of epitaxy growth being progressed by the high energy of plasma at the low temperature of substrate, iron silicide was epitaxially grown to ${\beta}$-phase that had lattice structure such as [220]/[202] and [115]. Band gap of the prepared films had value of 1.182~1.174 eV and optical gap energy was shown value of 3.4~3.7 eV. The Urbach tail and the sub-band-gap absorptions were appeared by organic compound in films. We knew that the prepared films by plasma were obtained a good quality films because of being grown single crystal.

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A Novel Efficiency Optimization Control of SynRM Considering Iron Loss with Neural Network (신경회로망에 의한 철손을 고려한 SynRM의 새로운 효율 최적화 제어)

  • Kang, Sung-Joon;Ko, Jae-Sub;Choi, Jung-Sik;Baek, Jung-Woo;Jang, Mi-Geum;Chung, Dong-Hwa
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.776_777
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    • 2009
  • Optimal efficiency control of synchronous reluctance motor(SynRM) is very important in the sense of energy saving and conservation of natural environment because the efficiency of the SynRM is generally lower than that of other types of AC motors. This paper is proposed a novel efficiency optimization control of SynRM considering iron loss using neural network(NN). The optimal current ratio between torque current and exciting current is analytically derived to drive SynRM at maximum efficiency. This paper is proposed an efficiency optimization control for the SynRM which minimizes the copper and iron losses. The design of the speed controller based on adaptive learning mechanism fuzzy-neural networks(ALM-FNN) controller that is implemented using fuzzy control and neural networks. The objective of the efficiency optimization control is to seek a combination of d and q-axis current components, which provides minimum losses at a certain operating point in steady state. The control performance of the proposed controller is evaluated by analysis for various operating conditions. Analysis results are presented to show the validity of the proposed algorithm.

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A study on the Mechanical characteristics of austempered ductile cast iron to hardness and texture variation in drilling (오스템퍼링한 구상흑연주철(ADI)의 드릴 가공시 경도 및 현미경조직변화에 관한 연구)

  • 조규재
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.8 no.1
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    • pp.81-88
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    • 1999
  • This paper was carried out to know the influence of advanced austempered ductile cast iron (ADI) on the tool life and mechanical properties of drilling machinability. For manufactured method of ADI, the spheroidal graphite cast iron were austenized at 90$0^{\circ}C$ for 1 hour and then austempered for 2 hour at 37$0^{\circ}C$ in the salt bath. And interrelationship has been investigated between tool life and mechanical characteristics of specimen material on drilling condition when the ordinary and step-feed drilling are carried out to drill holes of specimens. Tensile strength and hardness of ADI decrease and elongation of ADI increases with the increase austempered temperature. It is known that about 2 times of tool life in the case of step-feed decreases compared with ordinary feed due to the high hardness of ADI and hardness ascribed to the fact that retained austenite became to martensite state due to cutting heat in drilling. Under the constant feed rate 0.1mm/rev relation between hardness and length of end tip after drilling can be formularized to Hv=$788.46L^{-0.096}$ for the cutting speed 6.1m/min.

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Structure and Magnetic Characterization of Core-Shell Fe@ZrO2 Nanoparticles Synthesized by Sol-Gel Process

  • Chaubey, Girija S.;Kim, Jin-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2279-2282
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    • 2007
  • Highly crystalline, uniform Fe nanoparticles were successfully synthesized and encapsulated in zirconia shell using sol-gel process. Two different approaches have been employed for the coating of Fe nanoparticle with zirconia. The thickness of zirconia shell can be readily controlled by altering molar ratio of Fe nanoparticle core to zirconia precursor in the first case where as reaction time was found to be most effective parameter to controlled the shell thickness in the second method. The structure and magnetic properties of the ZrO2-coated Fe nanoparticles were studied. TEM and HRTEM images show a typical core/shell structure in which spherical α-iron crystal sized of ~25 nm is surrounded by amorphous ZrO2 coating layer. TGA study showed an evidence of weight loss of less than 2% over the temperature range of 50-500 °C. The nanoparticles are basically in ferromagnetic state and their magnetic properties depend strongly on annealing temperature. The thermal treatment carried out in as-prepared sample resulted in reduction of coercivity and an increase in saturation magnetization. X-ray diffraction experiments on the samples after annealing at 400-600 °C indicate that the size of the Fe@ZrO2 particles is increased slightly with increasing annealing temperature, indicating the ZrO2 coating layer is effective to interrupt growing of iron particle according to heat treatment.

Near-infrared Spectroscopy of Iron Knots in Cassiopeia A Supernova Remnant

  • Lee, Yong-Hyun;Koo, Bon-Chul;Moon, Dae-Sik
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.68.1-68.1
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    • 2010
  • Cassiopeia A supernova remnant is a young (~330 yr) remnant of Type IIb SN explosion with a massive progenitor. It shows two distinct optical knots; fast moving ejecta knots (FMKs) and quasi stationary circumstellar knots (QSFs). These knots offer an unique opportunity to explore the details of the explosion and also the end state evolution of the Type IIb SN progenitor. We have obtained NIR long-slit (30") spectra of 7 positions around the bright rim of Cas A in [Fe II] 1.644 micron using Triplespec which is a cross-dispersed near-infrared spectrograph that provides continuous wavelength coverage from 0.95-2.46um at intermediate resolution of 2700. Most of the FMKs show strong sulfur, silicon, and iron forbidden lines but no hydrogen or helium lines. The QSFs, on the other hand, show a much richer spectrum with strong hydrogen, helium, and iron lines, but no sulfur and silicon lines. We measure their fluxes and radial velocities, and derive their physical parameters such as electron density and temperature. We also measure the proper motion of these knots from two [Fe II] 1.644 micron images obtained at 3-year interval. We analyze the physical properties of these knots and discuss the evolution and explosion of the progenitor of Cas A.

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The Influence of Chlorine Application on Corrosion and Bacterial Growth in Home Plumbing Systems (급수관내 염소 주입이 미생물의 증식과 부식에 미치는 영향)

  • Kim, Tae-Hyun;Lee, Yoon-Jin;Lim, Seung-Joo
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.431-439
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    • 2006
  • This research was conducted using a model home plumbing system composed of copper, stainless steel, galvanized iron, carbon steel, and PVC (polyvinyl chloride) pipe. The number of bacteria present in stainless steel pipe and PVC was higher than other pipes. High turbidity and zinc release were found in galvanized iron pipe material and detected during the first 6 months. Conversely, there was a decrease in turbidity and zinc release after 6 months resulting in levels similar to other pipes. Copper concentration decreased as operation times increased. In this experiment, the number of bacteria detected in biofilm for a copper pipe continued to increase. Pipe material influenced bacterial numbers in biofilm and water. This showed that elevated chlorine could not control bacterial growth in biofilm for galvanized iron and stainless steel systems. It also suggested that the dosing of chlorine might not be available for all kinds of pipes. Therefore, another complementary method should be introduced to manage biofilm effectively in water distribution systems.

Recovery of Ammonium Salt from Nitrate-Containing Water by Iron Nanoparticles and Membrane Contactor

  • Hwang, Yu-Hoon;Kim, Do-Gun;Ahn, Yong-Tae;Moon, Chung-Man;Shin, Hang-Sik
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.111-116
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    • 2012
  • This study investigates the complete removal of nitrate and the recovery of valuable ammonium salt by the combination of nanoscale zero-valent iron (NZVI) and a membrane contactor system. The NZVI used for the experiments was prepared by chemical reduction without a stabilizing agent. The main end-product of nitrate reduction by NZVI was ammonia, and the solution pH was stably maintained around 10.5. Effective removal of ammonia was possible with the polytetrafluoroethylene membrane contactor system in all tested conditions. Among the various operation parameters including influent pH, concentration, temperature, and contact time, contact time and solution pH showed significant effects on the ammonia removal mechanism. Also, the osmotic distillation phenomena that deteriorate the mass transfer efficiency could be minimized by pre-heating the influent wastewater. The ammonia removal rate could be maximized by optimizing operation conditions and changing the membrane configuration. The combination of NZVI and the membrane contactor system could be a solution for nitrate removal and the recovery of valuable products.

The Research for a Structure of Current Limiter using a Phasic Similitude of Magnetic Circuit (자기회로의 위상학적 상사성을 이용한 전류제한기 구조에 관한 연구)

  • Ji, Geun-Yang;Min, Kyung-Il;Lee, Su-Won;Jang, Bong-Hwan;Moon, Young-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.11
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    • pp.2128-2135
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    • 2009
  • In this paper, current limiter using a magnetic switching which is based on magnetic flux change in the case of fault is proposed. This current limiter consists of iron-core and three parts of coils. One is the primary coil connected to the power system. Another is the secondary coil wound to the opposite direction of the primary coil's winding. The other is the secondary of the secondary coil which is a movable copper plate winding and located below the secondary coil. In the normal state, the magnetic flux produced in the primary and secondary coils flows to the opposite directions each other and becomes to be canceled out. Therefore the voltages induced between the coils are zero. In the case of a fault, at the moment of a fault occurrence recognition, the switch connected to a secondary coil is opened and the secondary of the secondary coil is pulled out to the outside of the iron-core. Then, magnetic flux becomes to flow through the iron-core. Accordingly, the voltage is induced between the both ends of the primary coil and makes the current reduced. Therefore it is possible to cut off the circuit breaker easily with the proposed current limiter. This paper analyzes the current limiting effects and the detailed results are given.

Corrosion Prediction of Metallic Cultural Heritage Assets by EIS

  • Angelini, E.;Grassini, S.;Parvis, M.;Zucchi, F.
    • Corrosion Science and Technology
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    • v.18 no.4
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    • pp.121-128
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    • 2019
  • Electrochemical Impedance Spectroscopy (EIS) was used to predict corrosion behaviour of metallic Cultural Heritage assets in two monitoring campaigns: 1) an iron bar chain exposed indoor from over 500 years in the Notre Dame Cathedral in Amiens (France); and 2) a large weathering steel sculpture exposed outdoor from tens of years in Ferrara (Italy). The EIS portable instrument employed was battery operated. In situ EIS measurements on the iron chain could be used to investigate the phenomena involved in the electrochemical interfaces among various corrosion products and assess and predict their corrosion behaviour in different areas of the Cathedral. Meanwhile, the sculpture of weathering steel, like most outdoor artefacts, showed rust layers of different chemical composition and colour depending on the orientation of metal plates. The EIS monitoring campaign was carried out on different areas of the artefact surface, allowing assessment of their protective effectiveness. Results of EIS measurements evidenced how employing a simple test that could be performed in situ without damaging the artefacts surface is possible to quickly gain knowledge of the conservation state of an artefact and highlight potential danger conditions.