• Title/Summary/Keyword: iron mineral

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Nitrate Reduction by Fe(0)/iron Oxide Mineral Systems: A Comparative Study using Different Iron Oxides (영가철과 여러 가지 산화철 조합공정을 이용한 질산성질소 환원에 관한 연구)

  • Song, Hocheol;Jeon, Byong-Hun;Cho, Dong-Wan
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.63-69
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    • 2014
  • This paper presents the feasibility of using different iron oxides (microscale hematite (HT), microscale magnetite (MT), and nanoscale maghemite (NMH)) in enhancing nitrate reduction by zero-valent iron (Fe(0)) under two solution conditions (artificial acidic water and real groundwater). Addition of MT and NMH into Fe(0) system resulted in enhancement of nitrate reduction compared to Fe(0) along reaction, especially in groundwater condition, while HT had little effect on nitrate reduction in both solutions. Field emission scanning electron microscopy (FESEM) analysis showed association of MT and NMH with Fe(0) surface, presumably due to magnetic attraction. The rate enhancement effect of the minerals is presumed to arise from its role as an electron mediator that facilitated electron transport from Fe(0) to nitrate. The greater enhancement of MT and NMH in groundwater was attributed to surface charge neutralization by calcium and magnesium ions in groundwater, which in turn facilitated adsorption of nitrate on Fe(0) surface.

Applying 3D U-statistic method for modeling the iron mineralization in Baghak mine, central section of Sangan iron mines

  • Ghannadpour, Seyyed Saeed;Hezarkhani, Ardeshir;Golmohammadi, Abbas
    • Geosystem Engineering
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    • v.21 no.5
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    • pp.262-272
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    • 2018
  • The U-statistic method is one of the most important structural methods to separate the anomaly from background. It considers the location of samples and carries out the statistical analysis of the data without judging from a geochemical point of view and tries to separate subpopulations and determine anomalous areas. In the present study, 3D U-statistic method has been applied for the first time through the three-dimensional (3D) modeling of an ore deposit. In order to achieve this purpose, 3D U-statistic is applied on the data (Fe grade) resulted from the drilling network in Baghak mine, central part of the Sangan iron mines (in Khorassan Razavi Province, Iran). Afterward, results from applying 3D U-statistic method are used for 3D modeling of the iron mineralization. Results show that the anomalous values are well separated from background so that the determined samples as anomalous are not dispersed and according to their positioning, denser areas of anomalous samples could be considered as anomaly areas. And also, final results (3D model of iron mineralization) show that output model using this method is compatible with designed model for mining operation. Moreover, seen that U-statistic method in addition for separating anomaly from background, could be very efficient for the 3D modeling of different ore type.

Total Dietary Fiber and Mineral Absorption

  • Gordon, Dennis-T.
    • Journal of Nutrition and Health
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    • v.25 no.6
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    • pp.429-449
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    • 1992
  • The consumption of foods rich in TDF should not be associated with impaired mineral absorp-tion and long-term mineral status. In surveys of populations consuming high amounts of TDF e.g Third World populations and vegetarinas gross deficiencies in mineral nutrition have not been noted. If mineral status is low among these groups it is most likely caused by the inadequacy or imbalance of the diet and not by the TDF. The key word is interaction which should be inte-rpreted in dietary imbalances that produce nut-rient deficiencies. There are no strong data to support the concept that TDF inhibits mineral absorption through a binding chelation mechanism. Limited data sug-gest that positively charged groups on polymers such as chitosan and cholestyramine will decrease iron absorption in humans and animals. Because TDF does not contain positively charged groups future research should be directed at the possible role of protein consumed along with TDF and the combination of effects on mineral nutrition Phytic acid is acknowledged as a potent chela-tor of zinc. However its association with zinc and its propensity to lower Zn bioavaiability may enhance the absorption of other elements notably copper and iron. The importance of interactions among nutrients including TDF will gain addi-tional attention in the scientific community. Soluble and insoluble dietary fiber function di-fferently in the intestine. Insoluble fibers accele-rate movement through the intestine. Soluble die-tary fibers appear to regulated blood concentra-tions of glucose and cholesterol albeit by some unknown mechanism. In creased viscosity produ-ced by the SDF in the intestine may provide an explanation of how this class of polymers affects plasma glucose cholesterol and other nutrients. Employing a double-perfusion technique in the rat we demonstrated that viscosity produced by SDF will delay transfer of zinc into the circulatory system. This delayed absorption should not be interpreted as decreased utilization. A great deal of additional research is required to prove the importance of luminaly viscosity produced by SDF on slowing nutrient absorption or regulating bllod nutrient homeostasis. Increased intake of TDF in the total human diet appears desirable. A dietary intake of 35g/day should not be considered to have a negative effect on mineral absorption. It is important to educate people that an intake of more than 35g TDF/day may cause an imbalance in the diet that can adve-rsely affect mineral utilization. Acknowledgments. Appreciation is given to Dr. George V. Vahouny(deceased) who was intense a great competitor in and out of science and who gave the author inspiration Portions of this work were supported by the University of Missouri Ag-ricultural Station and by a grant from the Univer-rch Support Grant RR 07053 from the National Institutes of Health. Contribution of the Missouri Agriculatural Experiments Station Journal Series No. 10747.

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Iron Nutritional Status by ALAD Genotype and Intervention Study for Rural Area Residents (농촌 여성들의 ALAD 유전형질별 철분영양상태와 철분제 섭취에 따른 영양상태의 변화)

  • Kim, Hee-Seon;Kim, Min-Kyung;Kim, So-Hee;Lee, Sung-Soo;Lee, Byung-Kook
    • Korean Journal of Community Nutrition
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    • v.11 no.6
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    • pp.771-778
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    • 2006
  • Previous studies have suggested that delta-aminolevulinic acid dehydratase (ALAD) phenotype differently affect mineral metabolism. The objective of this study was to determine the effectiveness of 6-month iron supplementation as syrup of NaFeEDTA in improvement of iron status according to ALAD genotype. One hundred thirty adult women living in rural areas of Asan were provided NaFeEDTA syrup once a week for 6 months at the dose of 64mg Fe/week. Three hundred control subjects were observed during the study period. Fasting blood was obtained for analyzing hemoglobin (Hb) and zinc protophorphyrin (ZPP) and serum was analyzed for ferritin, iron and total iron capacity (TIBC) levels before and after iron supplementation. Ninety percent of ALAD 1-1 (ALAD1) and 10% of ALAD 1-2 (ALAD2) genotype were observed in the control group. However in the intervention group, 98% showed ALAD1 while only 2% was ALAD2, which is significantly lower proportions of ALAD2 compared to the control group (p<0.01). The iron status of Intervention group significantly improved except for ferritin and TIBC regardless or ALAD genotype, while the control group did not show any changes in iron status except for ZPP. ZPP concentration of the control group significantly increased in both ALAD1 and 2 while the intervention group showed significantly decreased ZPP after supplementation in ALAD1. Iron supplementation in the form of NaFeEDTA seems to be effective in reduction of ZPP levels although ALAD2 did not show significant changes due to the small number. However, it is difficult to make a conclusion from these results, and more specified further investigation is needed with more participants.

Seasonal Changes in Energy-related Blood Metabolites and Mineral Profiles of Nguni and Crossbred Cattle on Communal Rangelands in the Eastern Cape, South Africa

  • Mapiye, C.;Chimonyo, M.;Dzama, K.;Marufu, M.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.6
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    • pp.708-718
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    • 2010
  • The objective of the current study was to determine seasonal changes in glucose, cholesterol, non-esterified fatty acids (NEFA), serum inorganic phosphorous (SIP), calcium, magnesium and iron concentrations in Nguni and crossbred cattle on the sweet and sour rangelands of the Eastern Cape Province of South Africa. Body weights, body condition scores (BCS) and serum concentrations of energy-related metabolites and mineral profiles were determined in late cool-dry, hot-dry, hot-wet, post-rainy and early cool-dry seasons in 100 cattle raised on communal rangelands from August 2007 to May 2008. Nguni cattle had lower (p<0.05) and higher (p<0.05) serum concentrations of glucose in the hot-wet and post-rainy seasons, respectively, compared to crossbreds in the same seasons. Serum cholesterol and NEFA concentrations in Nguni were lower (p<0.05) than in the crossbreds. Nguni and crossbred cattle had higher (p<0.05) serum NEFA concentrations on the sweet rangeland during the late cool-dry season than on sour rangeland. Nguni cattle had higher (p<0.05) SIP concentration in the hot-wet season than the crossbreds. Generally, both breeds had lowest SIP concentration during the hot-wet season on the sour rangeland. The lowest magnesium and highest iron concentrations were observed in the hot-wet and post-rainy seasons, respectively, compared to other seasons. Cattle on the sour rangeland had lower (p<0.05) iron concentrations than those on the sweet rangeland. It was concluded that Nguni cattle had lower cholesterol and NEFA, and higher SIP concentrations in the hot-wet season than crossbreds and energy deficits mostly occurred during the late cool-dry season on the sweet rangeland.

Recovery of Cu and Sn from the Bioleaching Solution of Electronic Scrap (전자(電子)스크랩의 미생물(微生物) 침출액(浸出液)으로부터 구리 및 주석의 회수(回收)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Kim, Meong-Woon;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.15 no.6 s.74
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    • pp.41-47
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    • 2006
  • A study for recovering of copper and lead from electronic scraps has been carried out using a combination of bioleaching and solvent extraction. It was found that the citric acid generated by Aspergillus niger could be an imporant leaching agent acting in the solubilization of copper, iron, lead and tin from the electronic scrap. Copper could be selectively extracted by 10% LIX84 from the leaching solution and it recoved 99.9% of metallic copper by electrowinning process. Tin and iron were extracted from the remaining solution by 10% Alamine336 and stripped by NaCl solution. Finally, tin could be recovered as a metallic precipitates from the mixed solution of tin and iron by cementation with iron powder.

Iron Extraction Characteristics of Sediment Samples from a River Bank Filtration Site (강변 여과 취수 지역 퇴적물의 철 화학종 추출 특성)

  • Hyun, Sung Pil;Moon, Hee Sun;Yoon, Pilsun;Kim, BoA;Ha, Kyoochul
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.129-138
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    • 2013
  • River bank filtration has been considered as a promising alternative water management scheme, in which groundwater is extracted from an aquifer near a river after infiltration of the river water into the aquifer, thereby improving and maintaining the quality of water recovered. Iron (Fe) associated with sediment in contact with groundwater and infiltrating surface water is an important factor in determining the quality of water recovered from the pumping wells in river bank filtration. This study reports the results of Fe speciation in the aquifer sediment samples collected from different depths at the river bank filtration site in Changwon, studied using four different chemical extraction methods, namely, ferrozine, oxalate, HCl, and DCB methods. Overall, the results show that Fe(II) as well as the total Fe content decreases with depth down to ~20 m and then increases further below. This trend is consistent with the redox characteristics suggested by visual observation. The silt/clay size fraction (${\phi}$ < 62.5 ${\mu}M$) has up to 2~10 times more Fe compared with the sand size fraction (62.5 ${\mu}M$ < ${\phi}$ < 2 mm), depending on the extraction method. Of the four extraction methods, DCB solution extracted the most Fe from the sediment samples. The amounts of Fe extracted by the different extraction methods can be a good indicator of the redox conditions along the depth of the aquifer.

Comparison of Bioleaching Kinetics of Spent Catalyst by Adapted and Unadapted Iron & Sulfur Oxidizing Bacteria - Effect of Pulp Density; Particle Size; Temperature

  • Pradhan, Debabrata;Kim, Dong-Jin;Ahn, Jong-Gwan;Gahan, Chandra Sekhar;Chung, Hun-Saeng;Lee, Seoung-Won
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.956-966
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    • 2011
  • Bioleaching studies of metals from a spent catalyst were conducted using both adapted and unadapted bacterial cultures. The bacterium used in this experiment was Acidithiobacillus ferrooxidans. A comparison of the kinetics of leaching was made between the two cultures by varying the leaching parameters, including the pulp density, particle size and temperature. Both cultures showed similar effects with respect to the above parameters, but the leaching rates of all metals were higher with the adapted compared to the unadapted bacterial cultures. The leaching reactions were continued for 240 h in the case of the unadapted bacterial culture, but only for 40 h in the case of the adapted bacterial culture. The leaching reactions followed first order kinetics. In addition, the kinetics of leaching was concluded to be a diffusion control model; therefore, the product layers were impervious.

A Comparative Analysis on the Export Competitiveness between Korea and China: Focusing on RCA and TSI (한·중 주요 수출품의 경쟁력 분석: RCA 및 TSI 지수를 중심으로)

  • Shen, Zhi-Feng;Kim, Tae-In;Gu, Ji-Jian
    • Asia-Pacific Journal of Business
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    • v.8 no.2
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    • pp.57-73
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    • 2017
  • In this paper RCA and TSI has been analyzed based on Korean and Chinese lists of export (HS 6 units) and list of companies and products with competitive advantage has been deduced. The results of RCA and TSI analysis are as follows. From the list of 20 most exported items from Korea to China the RCA index for eleven of them (based on common items from 2011-2015) is bigger than 1, thus showing comparative advantage. As for the TSI index, all of the items has shown (+) value, and has been analyzed as specialization in export. In other words, companies in the fields of mineral fuel; mineral oil; organic chemicals; electrical equipment and parts; as well as optical, precision and medical instrument are industries with competitive advantage. From the list of 20 most exported items from China to Korea the RCA index for twelve of them (based on common items form 2011-2015) is bigger than 1, thus also showing comparative advantage, and the TSI index has also shown (+) value for all of the specified items, meaning specialization in export. Industries of mineral fuel; mineral oil; iron and steel, articles of iron and steel; machinery and mechanical parts, electrical equipment and parts; as well as optical, precision and medical instruments have shown competitive advantage.

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A Study on the Mine Development of North Korea and the Inter-Korean Mineral Resources Cooperation (북한의 광물자원개발과 남북간 자원협력방안)

  • Kim You-Dong;Park Hong-Soo;Kim Seong-Yong;Lee Jae-Ho
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.197-206
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    • 2005
  • North Korea is plentiful in the mineral resources as magnesite, gold, zinc, iron, rare metal, and coal resources compared to South Korea and has 6 industrial zones which are located nearby to the mineralized areas. The industrial zones are provided with a sound infrastructures and accumulation of advanced technology. As a huge mineral and energy consuming country, South Korea imports mineral and coal resources equivalent to almost 8 trillion won annually. Inter-Korean cooperation for development of mineral resources in North Korea will be improved by the practical use of the North Korea's plentiful mineral resources, infiastructures related to development and refinement, and basic geo-technology, which would be considered toward combining with South Korean capital and Russian geo-technologies.