• Title/Summary/Keyword: ionic composition

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Correlation between Electrical Conduction and Dielectric Relaxation in the Glass System $Cul-Cu_2S-Cu_2O-MoO_3$ ($Cul-Cu_2S-Cu_2O-MoO_3$계 유리의 전기전도 및 유전환화와의 상관)

  • 이재형;임기조
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.7
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    • pp.1152-1157
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    • 1994
  • The glasses were prpared in the system CuI-CuS12TS-CuS12TO-MoOS13T by rapid quenching technique. These glasses have high ionic conductivities at 2$0^{\circ}C$ in the range of 10S0-1T[S/m], and the conductivities increase with increasing CuI and CuS12TS content. The value of activation energy for dielectric relaxation is nearly identical with that for conductivity. The cole-Cole parameter $\beta$ for representation of the distribution of dielectric relaxation times varies the range from 0.92 to 0.96. This parameter has a weak dependence on the composition of glass, and is independent of temperature. The correlation factors P for the glasses shows from 1.1 to 1.7.

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Separation of Succinic Acid from Organic Acid Mixture Using Electrodialysis (전기투석에 의한 유기산 혼합물로부터 숙신산의 분리)

  • Kim, Sang-Hun;Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.266-271
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    • 2005
  • This paper studied succinic acid recovery from organic acid mixture by using mono-polar membrane electrodialysis. Current efficiency, solute recovery efficiency, energy consumption, and separation factor were measured at various pHs and concentration ratios. The separation factor of succinic acid could be interpreted in terms of ionization degree, molecular weight, ionic conductance, average charge, and initial feed composition.

Ionic Conductivity of Solid Solution Ceramics in The System of Stabilized ZrO2 Prepared by Self-Propagating High-Temperature Synthesis

  • Soh, Deawha;Korobova, N.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.349-355
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    • 2002
  • The ionic conductivity of cubic solid solutions in the systems of CaO-$ZrO_2$, $Y_2O_3-ZrO_2$ prepared by SHS was examined. The higher conductivity appears to be related to a lower activation energy rather than to the number of oxygen vacancies dictated by composition. Conductivity-temperature data was obtained at 1000 $^{\circ}C$ in atmosphere of low oxygen partial pressure (~$10^{-40}$ atm) for $Y_2O_3-ZrO_2$ cubic solid solutions. The data indicated that these materials could be reduced, and the decree of reduction would be related with the measuring electric field.

A comparative study of the ionic composition of aerosols from the North Sea and a North Sea coastal area

  • Lee, Jong-Min;Schrems, Otto
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.47-48
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    • 2001
  • It is well known that atmospheric aerosols play an important role in the radiation balance of the earth and meteorological processes as well as in atmospheric chemistry. Aerosols may origin from both natural and/or anthropogenic sources. Thus, the chemical composition of aerosols can vary considerably. For example, the chemical composition of marine aerosol has been the subject of a considerable number of investigations, including the evaluation of long-range transport of anthropogenic constituents on the chemistry of the remote marine boundary layer. (omitted)

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Synthesis and Ionic Conductivity of Polystyrene Derivative Containing Cyclic Carbonate (Cyclic carbonate를 포함하는 polystyrene 유도체의 합성 및 이온전도 특성)

  • Kim, Doo-Hwan;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.1-6
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    • 2015
  • In this study polystyrene derivative, VBCE, having a cyclic carbonate was synthesized by Williamson reaction and polymerized to poly(VBCE) successfully in an usual polymerization conditions. The obtained polymer was blended with PEGMA and the effect of composition on the ionic conductivity was investigated. Interestingly, the ionic conductivity was decreased from $4.2{\times}10^{-5}S\;cm^{-1}$ to $3.93{\times}10^{-6}S\;cm^{-1}$ with the poly(VBCE) contents of 5.8mol%. From the DSC study, it was found that the $T_g$ of the blend was increased from $-50^{\circ}C$ to $-21^{\circ}C$ by the addition of poly(VBCE). Therefore, it is believed that the presence of a polar cyclic carbonate makes polymer matrix harder and it is necessary to design new structures less hindered the mobility of the matrix.

Comparison of Ionic Equilibria Analysis of ZnSO4-Fe2(SO4)3-Na2SO4-H2SO4-NaOH-H2O System at 25℃ between Pitzer and Vasil'ev Equation (25℃에서 ZnSO4-Fe2(SO4)3-Na2SO4-H2SO4-NaOH-H2O계에 대해 Pitzer식과 Vasil'ev식에 의한 이온평형해석 비교)

  • Lee, Man-Seung;Lee, Kyoung-Ju;Nam, Sang-Ho
    • Analytical Science and Technology
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    • v.16 no.2
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    • pp.159-165
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    • 2003
  • To develop an ionic equilibria model applicable to the sulfuric acid leaching solutions of zinc oxide ore, the method of the Pitzer equation and that of the Vasil'ev equation were compared. As the ionic strength of the solution increased to 9 m, the results of ionic equilibria by the Pitzer equation were more accurate than those by Vasil'ev. To simulate the sulfuric acid leaching solutions of zinc oxide ore, the mixed solutions with the various composition of $ZnSO_4-Fe_2(SO_4)_3-Na_2SO_4-H_2SO_4-NaOH-H_2O$ were prepared. The pH values calculated in this study agreed well with those measured at $25^{\circ}C$.

Composition and Characteristics of ionic Components of Aerosols Collected at Gosan Site in Jeiu Island, Korea

  • Kang, Chang-Hee;Kim, Won-Hyung;Hu, Chul-Goo;Kim, Yong-Pyo;Shim, Shang-Gyoo;Hong, Min-Sun;Kim, Ki-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E4
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    • pp.177-186
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    • 2003
  • The total of 1,454 aerosol samples were collected by high volume tape sampler at the Gosan Site in Jeju Island from 1992 to 1999, and the major water-soluble ionic components were chemically analyzed. The mean concentrations of nss-S $O_4$$^{2-}$, N $H_4$$^{+}$, and N $O_3$$^{[-10]}$ showed high values, which were 6.73, 1.45, and 1.45 ${\mu}{\textrm}{m}$/㎥, respectively, while $Ca^{2+}$ and $K^{+}$ concentrations were low with the values of 0.49 and 0.42 $\mu\textrm{g}$/㎥. The concentrations of most components increased in spring but decreased in summer, especially with the remarkable increase of $Ca^{2+}$ and N $O_3$$^{[-10]}$ concentrations in spring. The seasonal comparison of nss-S $O_4$$^{2-}$ concentrations showed higher values with the order of spring > fall 〉 winter〉 summer, but spring 〉 winter〉 fall 〉 summer for N $O_3$$^{[-10]}$ Meanwhile, the concentration levels of N $a^{+}$ and C $l^{[-10]}$ increased more in winter season. According to the investigation of wind direction effect, the concentrations of most aerosol ionic components showed higher values consistently at the westerly and northerly wind conditions. Based on the factor analysis, the atmospheric aerosols in the Gosan Site are considered to be largely affected by marine sources, followed by anthropogenic and soil sources.urces..

Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

State Observer Based Modeling of Voltage Generation Characteristic of Ionic Polymer Metal Composite (상태 관측기 설계 기법을 적용한 이온성 고분자 금속 복합체의 전압 생성 특성 모델링)

  • Lee, Hyung-Ki;Park, Kiwon;Kim, Myungsoo
    • Composites Research
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    • v.28 no.6
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    • pp.383-388
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    • 2015
  • Ionic Polymer-Metal Composite (IPMC) consisting of soft membrane plated by platinum electrode layers on both surfaces generates electric energy when subjected to various mechanical stimuli. The paper proposes a circuit model that describes the physical composition of IPMC to predict the voltage generation characteristic corresponding to bending motion. The parameter values in the model are identified to minimize the RMS error between the real and simulated outputs. Following the design of IPMC circuit model, the state observer of the model is designed by using pole placement technique which improves the model accuracy. State observer design technique is also applied to find the inverse model which estimates the input bending angles from the output voltage data. The results show that the inverse model estimates input bending angles fairly well enough for the further applications of IPMC not only as an energy harvester but also as a bending sensor.

Ionic composition comparison of atmospheric aerosols at coastal and mountainous sites of jeju island (제주도 해안과 산간 지역 대기 에어러솔의 이온조성 비교)

  • Hong, Sang-Bum;Jung, Duk-Sang;Lee, Soon-Bong;Lee, Dong-Eun;Shin, Seung-Hee;Kang, Chang-Hee
    • Analytical Science and Technology
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    • v.24 no.1
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    • pp.24-37
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    • 2011
  • The ionic compositions of atmospheric aerosols were investigated and characterized in coastal and mountainous sites of Jeju Island, which were Gosan and Mt. Halla-1100 sites respectively. It was found that the concentrations of nss-$SO_4^{2-}$ (non-sea salt sulfate) and $NH_4^+$ at two measurement sites were almost similar and they showed high concentrations in June at the same time. The concentration of soil-originated nss-$Ca^{2+}$ (non-sea salt calcium) was generally associated with that of anthropogenic $NO_3^-$ and its concentration was increased during spring season. From the comparison of time-series variation and regression analysis of ionic species between two measurement sites, TSP (total suspended particulate) in Gosan site was directly influenced by sea salt particles and the concentration levels of nss-$SO_4^{2-}$, $NH_4^+$, nss-$Ca^{2+}$, $K^+$, and $NO_3^-$ were mainly related with long-range transported air pollutants rather than local pollution sources.