• Title/Summary/Keyword: ion transport

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Visualization of Ion Transport and pH Change in Ion Concentration Polarization (농도 분극 현상에서의 이온의 흐름과 pH 변화의 가시화)

  • Ko, Sung-Hee;Kang, Kwan-Hyoung
    • Journal of the Korean Society of Visualization
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    • v.8 no.4
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    • pp.38-42
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    • 2010
  • Ion concentration polarization is an electrokinetic phenomenon which occurs in membrane systems, such as in an electrodialysis and fuel-cell system. But the phenomenon is not fully understood because hydrodynamics, electrokinetics and electrochemistry are coupled with each other. Here, we report that there occurs a change of pH value of buffer solution in concentration polarization phenomenon. To visualize the change of pH, the litmus solution which is one of the pH indicators was used. It is conjectured that the pH of solution changes because hydrogen ions were concentrated in cathodic side and hydroxide ions were concentrated in anodic side. We anticipate that this work may contribute to the fundamental understanding on the ion concentration polarization phenomenon.

Visualization of Unsteady DC Electro-osmotic flow by using Methods of Coupling Fortran and CFX Codes (포트란-CFX 연동해석 기법을 이용한 비정상 DC 전기삼투 유동 가시화)

  • Heo, Young-Gun;Jeong, Jong-Hyeon;Suh, Yong-Kweon
    • Journal of the Korean Society of Visualization
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    • v.9 no.4
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    • pp.22-27
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    • 2011
  • In this study, we present methods of coupling a commercial code, ANSYS CFX, and the user Fortran codes for solving an unsteady electro-osmotic flow around a pair of electrodes, receiving DC, attached to the top and the bottom walls of a two-dimensional cavity. We developed a module of Fortran programs for solving the ion-transport equations as well as the Poisson equations for the potential to be used in coupling with the CFX. We present how the developed codes are applied to solving the transient DC electro-osmotic flow problem within a simple cavity. We also address various problems encountered during the development process and explain why such problems are raised.

Field-effect Ion-transport Devices with Carbon Nanotube Channels: Schematics and Simulations

  • Kwon Oh Kuen;Kwon Jun Sik;Hwang Ho Jung;Kang Jeong Won
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.787-791
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    • 2004
  • We investigated field-effect ion-transport devices based on carbon nanotubes by using classical molecular dynamics simulations under applied external force fields, and we present model schematics that car be applied to the nanoscale data storage devices and unipolar ionic field-effect transistors. As the applied external force field is increased, potassium ions rapidly flow through the nanochannel. Under low external force fields, ther nal fluctuations of the nanochannels affect tunneling of the potassium ions whereas the effects of thermal fluctuations are negligible under high external force fields. Since the electric current conductivity increases when potassium ions are inserted into fullerenes or carbon nanotubes, the field effect due to the gate, which can modify the position of the potassium ions, changes the tunneling current between the drain and the source.

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Ion Transport and High Frequency Dielectric of the Hollandite $Nax(Ti_8-_xCr_x)O_{16}$ (Hollandite $Nax(Ti_8-_xCr_x)O_{16}$의 이온 전송과 고유전율)

  • Shin, Hyun-Mahn;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.243-244
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    • 2008
  • The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6{\times}10^{12}Hz$ that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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Numerical Analysis of Impurity Transport Along Magnetic Field Lines in Tokamak Scrape-011 Layer

  • Chung, Tae-Kyun;Hong, Sang-Hee
    • Nuclear Engineering and Technology
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    • v.30 no.1
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    • pp.17-25
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    • 1998
  • Transport of carbon and boron impurity ions parallel to magnetic field lines in the tokamak SOL (scrape-off layer) is numerically investigated for a one-dimensional steady state. The spatial distributions of density and velocity of the impurity ions in a steady state are calculated by finite difference method for a single-fluid model. The calculated results show that among forces acting on SOL particles thermal force produced tv plasma temperature gradient is a principal force determining the feature of impurity distribution profiles in the tokamak edge. However, strong collisional friction forces appearing dominant in front of the diverter plate restrain impurity ion flows due to temperature gradients from moving toward the midplane. Consequently, the stagnation point develops in the impurity flow by these two forces near the diverter region, in which ion flows change their directions. Impurity ions turn out to be accumulated at the stagnation points, where peaked profiles of highly-ionized state ions are relatively predominant over those of low-ionized state ions.

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Metabolic Components of Energy Expenditure in Growing Beef Cattle - Review -

  • Caton, J.S.;Bauer, M.L.;Hidari, H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.5
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    • pp.702-710
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    • 2000
  • A large portion of total energy expenditure associated with ruminant livestock production goes towards maintenance. Approximately 55% of whole body energy use is consumed by visceral tissues (including internal organs) with the majority of this going to the liver and gastrointestinal tract. Muscle and adipose tissues consume about 27% of total body energy expenditure. Metabolic components within the viscera responsible for the majority of energy consumption include ion transport, protein turnover, substrate cycling, and urea synthesis (liver). Within muscle tissue of growing animals ion transport and protein turnover account for most of the energy expenditure. Protein synthesis consumes approximately 23% of whole body energy use and visceral tissues account for proportionally more of whole body protein synthesis than skeletal muscle. Research efforts focused on improving energetic efficiency of the tissues and metabolic mechanisms responsible for the majority of whole animal energy expenditure should provide information leading to more efficient production of an edible product.

A study on heavy metal migration in fly ash/bentonite using a reactive transport model

  • Jung, Yoo-Jin;Cho, Hee-Chan
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.629-636
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    • 2003
  • The retardation of heavy metals in a mixture of fly ash and bentonite was studied as a potential barrier material for a landfill. Column tests were conducted using synthetic leachate having 100 mg/L and 50 mg/L of lead (Pb) and cadmium (Cd), respectively. Results indicated that the mixture had obvious retardation ability for heavy metals. To investigate the retardation factor caused by adsorption, batch adsorption tests were conducted at various concentrations. Test results were correlated with both Langmuir and Freundlich isotherms. The adsorption of the lead ion was applicable to the Langmuir isotherm and the adsorption of the cadmium ion was applicable to the Freundlich isotherm. In addition, based on experimental results, the migration characteristics of heavy metals through the bed of fly ash and bentonite mixture were investigated using the PHREEQC, a reactive transport model, under the real conditions of the landfill liner.

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Electrogravimetric and Electrochemical Ac Response of Polypyrrole Films

  • Yang, Haesik;Lee, Hochun;Kwak, Juhyoun
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.663-668
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    • 1995
  • Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

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Investigation of Oxygen Functional Group Movement in Graphene Oxide Devices (그래핀 산화물 소자에서의 산소 작용기 이동 연구)

  • Eun Hee Kee;Mohd Musaib Haidari;Ji Hoon Jeon;Jin Sik Choi;Bae Ho Park
    • Journal of Sensor Science and Technology
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    • v.32 no.2
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    • pp.100-104
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    • 2023
  • In this study, a device was fabricated to check the possibility of a memory device by controlling the oxygen functional groups in graphene oxide formed with a 45-second exposure time. We discovered that graphene oxide can be formed using the ultraviolet (UV) light treatment method with different exposure times. Moreover, Raman spectroscopy measurement revealed that the oxygen functional groups can be moved by controlling the voltage. We further studied the change in the local graphene oxide region, which was found to be related to the modulation of the electrical properties of the device. Therefore, the fabricated graphene oxide device can be used as a wettability switching membrane and graphene-based ion transport device.

Regulation of depth and composition of airway surface liquid

  • J. H. Widdicombe;S. J. Bastacky;D. X.Y. Wu;Lee, C. Y.
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1996.04a
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    • pp.119-130
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    • 1996
  • We review the factors which regulate the depth and composition of the human airway surface liquid (ASL). These include secretion from airway submucosal glands, ion and fluid transport across the surface epithelium, goblet cell discharge, surface tension and transepithelial gradients in osmotic and hydrostatic pressure. We describe recent experiments in which we have used low temperature scanning electron microscopy of rapidly frozen specimens to detect changes in depth of ASL in response to submucosal gland stimulation. We also present preliminary data in which X-ray microanalysis of frozen specimens has been used to determine the elemental composition of ASL.

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