• Title/Summary/Keyword: ion loss

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Optimal SOC Reference Based Active Cell Balancing on a Common Energy Bus of Battery

  • Bae, SunHo;Park, Jung-Wook;Lee, Soo Hyoung
    • Journal of Electrical Engineering and Technology
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    • v.12 no.1
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    • pp.29-38
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    • 2017
  • This paper presents a study on the state-of-charge (SOC) reference based active cell balancing in real-time. The optimal references of SOC are determined by using the proposed active cell balancing system with the bidirectional DC/DC converters via the dual active bridge (DAB) type. Then, the energies between cells can be balanced by the power flow control of DAB based bidirectional DC/DC converters. That is, it provides the effective management of battery by transferring energy from the strong cell to the weak one until the cell voltages are equalized to the same level and therefore improving the additional charging capacity of battery. In particular, the cell aging of battery and power loss caused from energy transfer are considered. The performances of proposed active cell balancing system are evaluated by an electromagnetic transient program (EMTP) simulation. Then, the experimental prototype is implemented in hardware to verify the usefulness of proposed system.

Preliminary Analysis of Several Storm Events by using the ECT data onboard Van Allen Probes

  • Choi, Eunjin;Hwang, Junga;Kim, Hang-Pyo;Kim, Kyoung-Chan;Park, Young-Deuk;Min, Kyoung-Wook
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.95.2-95.2
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    • 2013
  • The Van Allen Probes were designed to study the Earth's radiation belts on various scales of space and time. The identical two spacecrafts going nearly eccentric orbits lap each other several times over the course of the mission and each probe carries five instrument suites to address the science objectives on the radiation belt. Since Van Allen Probes launched on August 30, 2012, the probes detecte several storm events up to now. To understand the particle acceleration and loss mechanism in the radiation belt, we first focus on the energetic electrons' dynamics detected by ECT (Energetic Particle, Composition, and Thermal Plasma Suite). ECT measures near-Earth space's radiation particles covering the full electron and ion spectra from ~ eV to 10's of MeV with sufficient energy resolution. In this paper, we present the preliminary results of the recent several storm events using electron data from ECT(MagEIS and REPT).

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Role of $Mg^{2+}$ in RNA splicing of T4 td intron

  • Sung, Jung-Suk;Shin, Sook;Park, In-Kook
    • Journal of Microbiology
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    • v.33 no.2
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    • pp.160-164
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    • 1995
  • The splicing activity of T4 phage td intron RNA has been examined with various Mg$^{2+}$ ions such as MGCl$_{2}$, MgS $O_{4}$ and magnesium acetate using various splicing conditions such as different incubation time and temperature. The maximum splicing of td intron RNA occurred at the concentration of 5 mM MgCl$_{2}$. Raising the Mg$^{2+}$ concentration up to 15 mM appeared to promote P2 delection mutant to overcome the loss of some splicing activity. In both wild type and mutant, a complete hydrolysis of RNA occurred at 30 mM MgCI$_{2}$ MgS $O_{4}$ and magnesium acetate exhibited the rate and pattern of RNA splicing identical to MGCI$_{2}$. The optimal splicing conditions involve the incubation of RNA with 5 mM MgCI$_{2}$ at 58 .deg.C for 15 min. The results suggest that Mg$^{2+}$ may play a key role in the catalytic mechanism of td intron RNA.n RNA.

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Catalytic and Structural Properties of Pyridoxal Kinase

  • Cho, Jung-Jong;Kim, Se-Kwon;Kim, Young-Tae
    • BMB Reports
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    • v.30 no.2
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    • pp.125-131
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    • 1997
  • This work reports studies of the catalytic and structural properties of pyridoxal kinase (ATP: pyridoxal 5' -phosphotransferase, EC. 2.7.1.35), Pyridoxal kinase catalyzes the phosphorylation of vitamin $B_6$ (pyridoxal, pyridoxamine, pyridoxine) using ATP-Zn as a phosphoryl donor. The enzyme purified from brain tissues is made up of two identical subunits of 40 kDa each. Native enzyme was inhibited by a substrate analogue, pyridoxal-oxime. Limited chymotrypsin digestion of pyridoxal kinase yields two fragments of 24 and 16 kDa with concomitant loss of catalytic activity. These fragments were isolated by DEAE ion exchange chromatography and used for binding studies with fluorescent ATP and pyridoxal analogues. The spectroscopic properties of both fluorescent pyridoxal analogue and Anthraniloyl ATP (Ant-ATP) bound to the 24 kDa fragment are indistinguishable from those of both pyridoxal analogue and Ant-ATP bound to the native pyridoxal kinase, respectively. The small 16 kDa fragment, generated by proteolytic cleavage of the kinase, does not bind any of the substrate analogues. Binding characteristics of Ant-ATP were extensively studied by measuring the changes in fluorescence spectra at various conditions. From the results presented herein, it is postulated that the structural domain associated with catalytic activity comprises approximately one-half of the molecular mass of pyridoxal kinase (24 kDa). whereas the remaining portion (16 kDa) of the enzyme contains a regulatory binding domain.

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Characterization of Si/Mo Multilayer Anode for Microbattery (박막전지용 Si/Mo 다층박막 음극의 전기화학적 특성)

  • 이기령;정주영;문희수;이승원;이유기;박종완
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.209-209
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    • 2003
  • The adventages of Li alloys have attracted the attention of many research groups, many of which have investigated tin-based alloys [1-2], Despite interesting performances of these, the irreversible capacity loss systematically observed on the first cycle for these compounds is a main drawback for their use as anode materials in lithium ion cells. Not only Sn is efficient in forming alloys with Li, Si can also react with Li to form alloys with a high Li/Si ratio, like Li$\_$22/Si$\_$5/ at 400$^{\circ}C$. It corresponds to a capacity of 4200mAh/g. Electrochemical Li-Si reaction occurs between 0 and 0.3 V against Li/Li$\^$+/, so that high-energy density battery can be realized. Despite the high theoretical capacity of elements like Si, however, particles of the alloys crack and fragment due to the repeated alloying and do-alloying which occurs as cell are charged and discharged. The research groups of Muggins [3] and Besenhard [4] have proposed that the volume expansion due to the insertion of Li can be reduced in micro- and submicro-structured matrix alloys. For this reason, the research group of J.R. Dahn investigated Sn/Mo sequential sputter deposition to prepare nanocomposites [5]. In this study, we investigated the characterization and the electrochemical characteristics of sequentially sputtered Si/Mo multilayer for microbattery anode.

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Effect of Mechanical Restraint due to Steel Microfibers on Alkali-Silica Reaction in Mortars (미세 강섬유의 구속력이 모르타르의 알칼리-실리카 반응에 미치는 영향)

  • Yi, Chong-Ku
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.577-584
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    • 2007
  • The effect of steel microfibers (SMF) on alkali-silica reaction (ASR) was investigated using two types of reactive aggregates, crushed opal and a pyrex rod of constant diameter. Cracks are less visible in the SMF mortars compared with the unreinforced mortars. Due to crack growth resistance behavior in SMF mortar specimens, the strength loss is eliminated and the ASR products remained well confined within the ASR site. The expansion and the ASR products were characterized by microprobe analysis and inductively coupled plasma (ICP) spectroscopy. The confinement due to SMF resulted in a higher Na and Si ion concentration of the ASR liquid extracted from the reaction site. The higher concentration reduced the ASR rate and resulted in a lower reactivity of the reactive pyrex rods in SMF mortars.

The Protective Effect of Herbal Medicine on PC12 Cell Induced by $MPP^+$ and 6-OHDA Neurotoxicity ($MPP^+$와 6-OHDA에 대한 한약탕제의 보호효과 연구)

  • Kang, Bong-Joo;Hong, Seoung-Gil;Cho, Dong-Wuk
    • Korean Journal of Oriental Medicine
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    • v.5 no.1
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    • pp.119-131
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    • 1999
  • The effect of herbal medicine on 1-methyl-4-phenylpyridinium ion $(MPP^+)$ and 6-hydroxydopamine (6-OHDA) mediated neurotoxicity was studied in the rat phaeochromocytoma cell line PC12. The present study was designed to test the hypothesis that herbal medicine can protect cells from neurotoxiciy caused by $MPP^+$ and 6-OHDA. Exposure of PC12 cells to 0.2 mM $MPP^+$ and $50\;{\mu}M$ 6-OHDA for 24h resulted in a 50% cell death with respect to the control cells. $MPP^+$ induced cell death was reduced by Yollyounggobondan (延齡固本丹), Sagunjatang (四君子湯), Palmihwan (八味丸), and Palmultang (八物湯)(P<0.05). However, herbal medicines did not protect cells from degeneration caused by the 6-OHDA. Yollyounggobondan, Yungmijihwangwon (六味地黃元), Palmihwan, and Samultang (四物湯) were effective in protecting against $MPP^+$-induced ATP loss in PC12 cells (P<0.05). Yollyounggobondan and Palmultang were effect in neurite protection against 6-OHDA treatment in differentiated PC12 cells with NGF.

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Expression and Characterization of Recombinant Human Cu,Zn-Superoxide Dismutase in Escherichia coli

  • Kang, Jung-Hoon;Choi, Bong-Jin;Kim, Sung-Moon
    • BMB Reports
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    • v.30 no.1
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    • pp.60-65
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    • 1997
  • Expression of human Cu.Zn-superoxide dismutase (SOD) with activity comparable to human erythrocyte enzyme was achieved in E. coli B21(DE3) by using the pET-17b expression vector containing a T7 promoter. Recombinant human SOD was found in the cytosol of disrupted bacterial cells and represented > 25% of the total bacterial proteins. The protein produced by the E. coli cells was purified using a combination of ammonium sulfate precipitation, Sephacryl S-100 gel filtration and DEAE-Sephacel ion exchange chromatography. The recombinant Cu,Zn-SOD and human erythrocyte enzyme were compared using dismutation activity, SDS-PAGE and immunoblotting analysis. The mass of the subunits was determined to be 15,809 by using a electrospray mass spectrometer. The copper specific chelator. diethyldithiocarbamate (DOC) reacted with the recombinant Cu,Zn-SOD. At $50{\mu}M$ and $100{\mu}M$ concentrations of DOC, the dismutation activity was not inhibited for one hour but gradually reduced after one hour. This result suggests that the reaction of DOC with the enzyme occurred in two distinct phases (phase I and phase II). During phase I of this reaction, one DOC reacted with the copper center, with retention of the dismutation activity while the second DOC displaced the copper, with a loss of activity in phase II.

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A Case of Congenital Chloride Diarrhea in Premature Infant (Congenital Chloride Diarrhea 1례)

  • Yoon, Sung Kwan;Kim, Eun Young;Moon, Kyung Rye;Park, Sang Kee
    • Clinical and Experimental Pediatrics
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    • v.46 no.3
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    • pp.308-311
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    • 2003
  • Congenital chloride diarrhea is a serious autosomal recessive disease, and defect of intestinal electrolyte absorption that involves, specifically, $Cl^-/{HCO_3}^-$ exchange in the distal part of the ileum and colon. The clinical feature is dominated by profuse, watery diarrhea containing high concentrations of chloride(>90 mmol/L) and sodium. The chloride loss results in severe dehydration with a hypochloremic alkalosis. The molecular pathology involves an epithelial $Cl^-/{HCO_3}^-$ exchanger protein. Mucosal ion transport is affected to differing degrees and the severity of the disease may thus vary. Recently, a gene defect on chromosome 7 has been identified. However, there was a deficit in replacement of fluid and electrolyte, abdominal distension remained and the character of stools was watery. We report a case of congenital chloride diarrhea in a premature female who presented with watery diarrhea containing high concentrations of chloride and abdominal distension.

A Study for the Improvement of Torn Oxide Defects in Shallow Trench Isolation-Chemical Mechanical Polishing (STI-CMP) Process (STI--CMP 공정에서 Torn oxide 결함 해결에 관한 연구)

  • 서용진;정헌상;김상용;이우선;이강현;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.1-5
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    • 2001
  • STI(shallow trench isolation)-CMP(chemical mechanical polishing) process have been substituted for LOCOS(local oxidation of silicon) process to obtain global planarization in the below sub-0.5㎛ technology. However TI-CMP process, especially TI-CMP with RIE(reactive ion etching) etch back process, has some kinds of defect like nitride residue, torn oxide defect, etc. In this paper, we studied how to reduced torn oxide defects after STI-CMP with RIE etch back processed. Although torn oxide defects which can occur on trench area is not deep and not severe, torn oxide defects on moat area is not deep and not severe, torn oxide defects on moat area is sometimes very deep and makes the yield loss. Thus, we did test on pattern wafers which go through trench process, APECVD process, and RIE etch back process by using an IPEC 472 polisher, IC1000/SUVA4 PAD and KOH base slurry to reduce the number of torn defects and to study what is the origin of torn oxide defects.

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