• Title/Summary/Keyword: ion concentration

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Antimicrobial Activity of Silver Ion against Salmonella typhimurium, Staphylococcus aureus and Vibrio parahaemolyticus (Salmonella typhimurium, Staphylococcus aureus, Vibrio parahaemolyticus에 대한 은 이온의 항균효과)

  • 김현진;이승철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.6
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    • pp.1163-1166
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    • 2002
  • Antimicrobial activity of silver ion was tested against 3 kinds of food-borne microorganisms-Salmonella typhimurium, Staphylococcus aureus and Vibrio parahaemolyticus-using paper disk and broth medium methods. In paper disk method, silver ion showed antimicrobial activity against S. typhimurium and V. parahaemolyticus at the concentration above 2 ppm and 10 ppm, respectively, where as it was not detected in S. aureus with 20 ppm of silver ion concentration. In broth medium, the growth of S. typhimurium and V. Porahaemolyticus could be retarded at 0.3 ppm and 0.5 ppm of silver ion concentration respectively. In the presence of 1.0 ppm of silver ion, the growth of S. typhimurium was inhibited completely. In S. aureus, the growth was retarded at 5 ppm and was inhibited at l5 ppm completely.

Investigation of Mechanical Behavior and Hydrates of Concrete Exposed to Chloride Ion Penetration (염해를 받은 콘크리트의 역학적 거동 및 수화 생성물 조사)

  • Yunsuk Kang;Gwihwan Lim;Byoungsun Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.381-390
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    • 2023
  • In this study, the mechanical performance of concrete exposed to chloride ion penetration was investigated. And a compressive stress-strain model was presented. CaCl2 solution was added when mixing concrete to simulate long-term chloride ion penetration, and the concentration of chlorine ions was set to 0, 1, 2, and 4 % based on the weight of the binder. To investigate the compressive stress-strain curve after the peak stress of concrete, the compressive strength was measured by displacement control. When the chlorine ion concentration was 1 %, peak stress increased, but when the chlorine ion concentration was 2 % or more, peak stress decreased. In the case of peak strain, no trend according to chloride ion concentration was observed at 7 days. At 28 days, peak strain decreased as the chloride ion concentration increased. A compressive stress-strain curve model based on the Popovics model was presented using changes in peak stress and peak strain at 28 days. Microstructure analyses were performed to investigate the cause of the decrease in mechanical performance as the concentration of chlorine ions increased. It was confirmed that as the concentration of chlorine ion increased, Friedel's salt increased and portlandite decreased.

Treatment Features of Ni Wastewater by using Coffee Grounds as the Adsorbent (커피 찌꺼기를 흡착제로 한 니켈 폐수 처리 특성)

  • Seo, Myung-Soon;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.14-20
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    • 2005
  • A feasibility study has been conducted regarding the application of waste coffee grounds as an adsorbent for the treatment of nickel ion containing wastewater. The major variables which considered to influence the adsorbability of nickel ion were its initial concentration, reaction temperature, pH, and coexisting ion. The specific surface area of coffee grounds used in the experiment was found to be ca. $39.67m^2/g$, which suggesting its potential applicability as an adsorbent due to its relatively high surface area. In the experimental conditions, more than 90% of the initial amount of nickel ion was shown to adsorb within 15 minutes and equilibrium in adsorption was attained after 3 hours. The adsorption behavior of nickel ion was well explained by Freundlich model and kinetics study showed that the adsorption reaction was second-order. Adsorption was reduced with temperature and its change of enthalpy in standard state was estimated to be -807.05 kJ/mol. Arrhenius equation was employed for the calculation of the activation energy of adsorption and nickel ion was observed to adsorb on coffee grounds exoentropically based on thermodynamic estimations. As pH rose, the adsorption of nickel ion was diminished presumably due to the formation of cuboidal complex with hydroxide ion and the coexistence of cadmium ion was found to decrease the amount of nickel ion adsorption, which was proportional to the concentration of cadmium ion.

Evaluation of Chloride Ion Binding Capacity of Hardened Portland Cement Paste Containing Hydrotalcite (경화된 하이드로탈사이트 혼입 포틀랜드 시멘트 페이스트의 염소이온 고정능력 평가)

  • Han, Jae-Do;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.27-28
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    • 2018
  • Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

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Effect of Ni/Fe Ion Concentration Ratio on Fuel Cladding Crud Deposition (핵연료 피복관 부식생성물 부착에 관한 Ni/Fe 이온 농도비의 영향)

  • Baek, S.H.;Kim, U.C.;Shim, H.S.;Lim, K.S.;Hur, D.H.
    • Corrosion Science and Technology
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    • v.13 no.4
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    • pp.145-151
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    • 2014
  • The objectives of this study are to investigate the effect of the concentration ratios of Ni and Fe ions on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the Ni and Fe concentration ratios of 20:20 ppm, 39:1 ppm and 1:39 ppm at $325^{\circ}C$ for 14 days. In the case of the same Ni and Fe ion ratio (20:20), nickel ferrite with a polyhedral shape was formed. Nickel oxide deposits with a needle shape were formed in the condition of high Ni to Fe ion ratio (39:1), While polyhedral iron oxide and needle-like nickel oxide formed in the condition of low Ni to Fe ion ratio (1:39). The amount of deposits increased, when Fe oxides were formed. This indicates that Fe rich oxides stimulated Ni oxide deposition.

A new approach for predicting sulfate ion concentration in concrete

  • Mohammad Ghanooni-Bagha;Mohsen Ali Shayanfar;Sajad Momen
    • Computers and Concrete
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    • v.33 no.1
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    • pp.1-11
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    • 2024
  • Aggressive environmental conditions, and especially the acidic effects of sulfate ion penetration, have reduced the lifetime of concrete structures in some areas, especially coastal and marine areas. In this research, at first, samples made of type II and V cement were kept in a solution of magnesium sulfate (MgSO4) for a period of 90 and 180 days, the change of appearance. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD), were used to analyze the microstructure and the complex mineral composition of the concrete after exposure to corrosive environments. Then solving the differential equation governing the sulfate ion penetration, which is based on the second Fick law, it has been tried to determine the concentration of sulfate ions inside the concrete. In the following, an attempt has been made to improve the prediction of sulfate ion concentration in concrete by using Crank's penetration equation. At the same time, the coefficient in the Crank's solution have been optimized by using the Particle Swarm Optimization (PSO algorithm). The comparison between the results shows that the values obtained from Crank's relation are closer to the experimental results than the equation obtained from Fick's second law and shows a more accurate prediction.

A Study of the Adsorption Behavior of Organic Acids by Polymeric Adsorbents (고분자 흡착제에 대한 유기산의 흡착성에 관한 연구)

  • Dai Woon Lee;In Ho Lee;Dal Ho Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.483-494
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    • 1988
  • The adsorption behavior of aromatic acids on Amberlite XAD-4 resin was investigated by measuring the distribution coefficient by batch method. The adsorption of solutes on XAD-4 was affected by the several factors such as, analyte concentration, the pH of solution and concentration of pairing ion. The enhanced adsorption of solutes on XAD-4 in the presence of tetraalkylammonium salt as an ion pairing reagent, referred to as ion interaction, was suggested to follow a double layer model where the pairing ion occupies a primary layer at the adsorbent while the solute anion and other anions in the system comlpete for the secondary layer. Therefore, the ability of an ion pairing reagent to enhance solute adsorption depended significantly on the type and concentration of counter-ion and co-anion accompanying the ion pairing reagent or salt used for ionic strength control. In addition, a good linear relationship between the logarithm of capacity factors measured by batch and elution method as a function of the concentration of ion pairing reagent and methanol can be used to predict the retention in elution method on the basis of capacity factors measured by batch method.

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Sorption Kinetics of $Sr_{2+}$in Citric Acid-Water systems (Citric acid-water 혼합시스템에서 $Sr_{2+}$의 흡착특성)

  • 김계남;김진완;한운우;원휘준;오원진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.133-136
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    • 2000
  • Soil decontamination process was conducted to study adsorption and modeling characteristic of Sr$^{2+}$ ion using citric acid and water system with TRIGA soil. When the concentration of citric acid was increased, the BTC of Sr$^{2+}$ ion was to be closed to the BTC of $^3$$H_2O$ at experiments of soil adsorption. Beside, when the concentration of citric acid was under 0.01M Sr$^{2+}$ ion, BTLs was asymmetry. It was characteristic of nonequilibrium adsorption. R and $K_{p}$ , were decreased to be increased the concentration of citric acid. Asymmetry modeling was nearly the same to be compare with symmetry modeling in decontamination process, when the concentration of citric acid was decreased. Result of experiment was agree with asymmetry and symmetry model, when the concentration of citric acid was increased.eased.

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Boron Detection Technique in Silicon Thin Film Using Dynamic Time of Flight Secondary Ion Mass Spectrometry

  • Hossion, M. Abul;Arora, Brij M.
    • Mass Spectrometry Letters
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    • v.12 no.1
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    • pp.26-30
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    • 2021
  • The impurity concentration is a crucial parameter for semiconductor thin films. Evaluating the impurity distribution in silicon thin film is another challenge. In this study, we have investigated the doping concentration of boron in silicon thin film using time of flight secondary ion mass spectrometry in dynamic mode of operation. Boron doped silicon film was grown on i) p-type silicon wafer and ii) borosilicate glass using hot wire chemical vapor deposition technique for possible applications in optoelectronic devices. Using well-tuned SIMS measurement recipe, we have detected the boron counts 101~104 along with the silicon matrix element. The secondary ion beam sputtering area, sputtering duration and mass analyser analysing duration were used as key variables for the tuning of the recipe. The quantitative analysis of counts to concentration conversion was done following standard relative sensitivity factor. The concentration of boron in silicon was determined 1017~1021 atoms/㎤. The technique will be useful for evaluating distributions of various dopants (arsenic, phosphorous, bismuth etc.) in silicon thin film efficiently.

The Effect of Turbidity and Alkalinity on the Regidual Aluminum Concentration (탁도(濁度) 및 알카리도(度)가 잔류(殘留)알루미늄 농도(濃度)에 미치는 영향(影響))

  • Choi, Suingil;Lee, Changsook
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.88-98
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    • 1995
  • Several kinds of coagulants such as aluminum sulfate, PAC, PASS are being used to treat drinking water resulting in residual aluminum ions in the water. Recently, it has been reported that high intake of aluminum ion may cause neurological dieseases such as Alzheimer's diesease and presenile dementia. Because of the possible adverse effect, WHO and EEC recommand to regulate residual aluminum. The autorities in Korea also has plan of regulating residual alunimum from 1995. But there is not enough information about the range of residual aluminum ion concentration when the aluminum sulfate, PAC or PASS has been used as a coagulant. Therefore the study has been conducted to find out the range of residual aluminum ion concentration after using aluminum sulfate, PAC, and PASS. Furthermore the effect of turbidity and alkalinity have been investigated. The experimental results are summarized as; 1. Most of the residual aluminum ion concentrations were within $10^{-6}$ and $10^{-5}mole/l$. Three coagulants have not showed any considerable difference in the residual aluminum concentration up to 50 NTU. However PAC has showed the least residual aluminum in high turbidity water over 100 NTU. 2. The low alkalinity water having 25mg/l as $CaCO_3$ has showed less residual aluminum than the water having 50mg/l alkalinity. However, the difference was not significcant. 3. Even the lowest residual aluminum concentration was over 0.05mg/l. Therefore the process to reduce residual aluminum would be necessary in water treatment plants.

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