• Title/Summary/Keyword: ion absorption

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Response-Improved Electrochromic Display Device Based on Organic Materials (고응답성 유기계 전기변색성 소자의 제작과 특성)

  • 권태선
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.81.1-91
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    • 1994
  • Irradiation of aromatic diazonium salts resulted in an effcient elimination of nitrogen, yielding substitution products. This paper was not only studies about photolysis of aromatic diazonium with double salts but also coexistence of ion and radical when they was photolysis. Photolysis of aromatic diazonium was depend on excite wave length therefore photolysis products out put different absorption intensity such other. We also confirmed coexistence of ion and radical when they was accomplished photolysis. In case of BD, there are ion decomposition process about 90 percentage, decreased ion decomposition process the other side radical`s it was becomeing increased according to excite of short-wave length.

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Medium Effect on the Formation of Ion-Pair between Methylene Blue and Tetraphenylborate in Dilute Solutions

  • Moon, Eui-Wha;Lee, Beom-Gyu;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.9 no.4
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    • pp.209-212
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    • 1988
  • The hydrophobic interaction leading to the formation of ion-pair between $MB^+$ and $TPB^-$ was investigated spectroscopically by varying the medium with the addition of 1,A-dioxane or urea. Beyond 0.01 mole fraction of 1,A-dioxane in water or above 2.0M urea the ion-pair appeared to be completely dissociated into individual ions. The ion-pair was not observed in common organic solvents and the absorption maxima of $MB^+$ were correlated relatively well with the ${\pi}^{\ast}$-scale.

Numerical studied on consequenses of the ion pumping effect in helicon plasmas (헬리콘 플라즈마에서 이온 펌핑 효과의 영향에 대한 수치적 해석 연구)

  • 조수원;박인호;최성을;권명회
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.353-360
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    • 1999
  • The global balance model is applied to investigate the transient behavior of the electron density and temperature in helicon plasmas. The power absorption calculated from the solutions of the Maxwell equations is used in solving the power balance equation. A balance model for the neutral gas is also considered to fins its density self-consistently. It is turned out that the numerical results reasonably explain consequences of the ion pumping effect including the occurrence of two distinct modes of pulsed helicon discharge which have been observed experimentally. The behavior of the discharge parameters are fond to be primarily dependent on the power absorption and the gas flow rate, but the pressure controls the electron density and temperature of the final steady state as well as the transient state even with the same flow rate. Finally, it is shown that the electron density virtually the linear relationship between the density and the magnetic field is retained for a higher pressure when the effect of the ion pumping is negligible.

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A Study on the Physical Properties of Sappan Wood Dyeing Fabrics Treated by Rice Straw Ash Solution (잿물로 매염처리된 소방염포의 물성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.6
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    • pp.609-609
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    • 1998
  • This paper surveys the effect of rice straw ash solution to the physical properties of Sappan Wood dyeing fabrics. In the quantitative analysis of rice straw ash solution, the quantities of absorbed ingredients in fabrics were increased by bath pull treatment but the amount of absorption(K/S value) was increased by bath pH4.5 treatment. This is related to the metal ion. Among the metal ion, effect of Fe iou and Al ion were related. In case added extracted dye solution to mordants, the color dye solution became dark and increased reddish. The changes of mechanical properties of fabrics tensile resilience, bending rigidity(B), compressional resilience(RC) were increased. Generally mechanical properties were increased by rice straw ash solution treatment, specially bath pH9 treatment. Rice straw ash solution treatment of dyeing fabrics made the improvement in tensile strength and elongation and in the amount of absorption, dye ability, color fastness, mechanical properties, tensile strength, elongation.

A Study on the Physical Properties of Sappan Wood Dyeing Fabrics Treated by Rice Straw Ash Solution (잿물로 매염처리된 소방염포의 물성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.6
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    • pp.699-705
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    • 1998
  • This paper surveys the effect of rice straw ash solution to the physical properties of Sappan Wood dyeing fabrics. In the quantitative analysis of rice straw ash solution, the quantities of absorbed ingredients in fabrics were increased by bath pull treatment but the amount of absorption(K/S value) was increased by bath pH4.5 treatment. This is related to the metal ion. Among the metal ion, effect of Fe iou and Al ion were related. In case added extracted dye solution to mordants, the color dye solution became dark and increased reddish. The changes of mechanical properties of fabrics tensile resilience, bending rigidity(B), compressional resilience(RC) were increased. Generally mechanical properties were increased by rice straw ash solution treatment, specially bath pH9 treatment. Rice straw ash solution treatment of dyeing fabrics made the improvement in tensile strength and elongation and in the amount of absorption, dye ability, color fastness, mechanical properties, tensile strength, elongation.

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Solvent Effect on the Dynamics of Radical Ion Pair Separation

  • Han, Chul-Hee
    • Journal of Photoscience
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    • v.8 no.1
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    • pp.33-37
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    • 2001
  • Picosecond absorption spectroscopy has been employed in the study of the solvent dynamics of 1, 2, 4, 5-tetracyanobenzene/biphenyl derivative radical ion pairs, and the resulting rates of radical ion pair separation are faster in acetonitrile than in dichloromethane. In an effort to account quantitatively for such solvent effect on the rate of radical ion pair separation, an equation for the rate of radical ion pair separation is introduced, in which the rate depends exponentially on the electrostatic interaction energy in the radical ion pair. In our analysis of the types of electrostatic interaction energy based on the conducting spheres in dielectric continuum was chosen, and the rate equation employing this electrostatic energy provided information on the distance on the distance of radical ion pair separation and solvation energy of the radical ion pair, thereby providing quantitative explanation for the observed solvent effect on the rate of radical ion pair sepaaration.

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Matrix-Assisted Variable Wavelength Laser Desorption Ionization of Peptides; Influence of the Matrix Absorption Coefficient on Expansion Cooling

  • Ahn, Sung-Hee;Bae, Yong-Jin;Kim, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2955-2960
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    • 2012
  • Product ion yields in the in- and post-source decays of three peptide ions, $[Y_5X+H]^+$ (X = Y (tyrosine), K (lysine), and R (arginine)), generated by matrix-assisted laser desorption ionization (MALDI) were measured at six wavelengths, 307, 317, 327, 337, 347, and 357 nm, using ${\alpha}$-cyano-4-hydroxycinnamic acid (CHCA) and 2,5-dihydroxybenzoic acid (DHB) as the matrices. The temperatures of the early and late plumes generated by MALDI were estimated via kinetic analysis of the product ion yield data. For both matrices, the temperature drop (${\Delta}T$), i.e. the difference in the temperature between the early and late plumes, displayed negative correlation with the absorption coefficient. This was in agreement with the previous reasoning that deeper laser penetration and larger amount of material ablation arising from smaller absorption coefficient would result in larger extent of expansion cooling. The results support the postulation of the expansion cooling occurring in the plume presented previously.

The Color Analysis and The Optical Absorption Properties of Yellow(x)-Blue(1-x) Color Lens (Yellow(x)-Blue(1-x) 칼라렌즈의 광흡수 특성과 color 분석)

  • Park, Sang An;Kim, Yong Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.2
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    • pp.201-205
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    • 2000
  • The colors of a tinted lens for a mixed color could be applied to a subtractive mixture's law, and the estimation of a tinted lens used the properties of optical absorptions and the color analysis. The optical absorption properties of Yellow(x)-Blue(1-x) depended on the yellow color in short wavelength below 500 nm, the absorption in the 550~650 nm wavelength regions depended on the blue color. The absorption band in the 550~650 nm wavelength regions was a peak for an ion of transition metal. The color properties of Yellow(x)-Blue(1-x) analysing by the $L^*a^*b^*$ of CIE system shifted to toward $+a^*$ decreasing x, it was formed of a pure color because of a low saturation existing in +0.6.

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The Effects of Bleaching or Washing on the Absorption of Softener (DSDMAC) (part 1) (직물의 표백과 세척이 유연제 (DSDMAC) 흡착에 미치는 영향(제1보))

  • 박선경;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.2
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    • pp.270-281
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    • 1996
  • This study was carried to figure out the effect of bleaching on the cationic surfactant (DSDMAC) absorption by cotton fabrics. And physico-chemical change, static electricity, and fabric stiffness of bleached cotton fabrics were measured. Cotton fabrics bleached with sodium hypochlorite soluton and with sodium percarbonate solution were used to analyze the DADMAC absorption. The results were as follows: 1. As the number of bleaching cycles were increased, the degree of oxidation on cotton fabrics was increased. So their carboxyl content was increased and their tensile strength was decreased. 2. DSDMAC absorption by cotton fabrics was increased by bleaching and was in propor- tion to carboxyl content. Therefore, it was groved that DSDMAC absorption by cotton fabrics was motivated by ion exchange mechanism. 3. The static electricity of cotton fabrics almost no change when bleached and unbleached absorption had no effect on the static electricity of cotton fabrics. 4. DSDMAC which was absorbed by cotton fabrics acted as a lubricant. DSDMAC absorption reduced the friction coefficient of yarn, so stiffness of cotton fabric was decreased.

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