• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.160-165
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• 1999

Osmotic pressure induced by semi-permeability of hardened cement pasts and cement mortar was studied, which was considered to be a cause of failure such as separation and blistering of floor coatings or wall coatings from the concrete substrate. The specimens with a water cement ratio of 45, 60 and 75% were installed between the solution of sodium chloride and distilled water. First, we measured water flux from distilled water to sodium chloride and the ion flux of Na+ and Cl- through the specimens. Then, we measured osmotic pressure induced by semi-permeability of the specimens using an apparatus which was specially developed for this study. It was made clear that hardened cement paste and cement mortar have properties of semipermeability, and the osmotic pressure is closely related to their water cement ratio. Finally, we calculated the osmotic pressure according to Staverman's equation, which was obtained for organic membranes, and tried to explain quantitatively the observed pressure.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.259-262
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• 1999

In underground reinforced concrete structures, such as drainage structure, water and chloride ion penetrated into concrete through the cracks of concrete and its permeable property, cause the corrosion of reinforcing steel bar, which accelerates the expansive cracks and deterioration of concrete. It is necessary to control those deterioration of underground structure by improving its permeability and durability through the reasonable solutions in design, construction and materials. In the present study, fly ash concrete, which has good material properties in long-term period, was compared and studied with plain concrete using ordinary portland cement in terms of fundamental mechanical properties, permeability, drying shrinkage and durability. Also, the mix design and field test of low permeable concrete using fly ash were performed. From this study, fly ash concrete can control the penetration of water and chloride ion effectively by forming dense micro-structure of concrete. Therefore, fly ash concrete may increase the long-term function, performance and serviceability of underground structures.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2002.05a
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• pp.81-84
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• 2002

Recently Bentonite mat is applied various structure : External waterproofing for underground structure, A reclaimed land, Artificial lake, Large-scaled civil structure, etc. With these various structure environment, water quality for application of Bentonite Mat affects watertightness. Specially spot with a large quantity of Chloride ion like salt water, degree of watertightness revelation is evaluated and applied. In this study, it is a main goal to investigate watertightness of Bentonite Mat with distilled water and salt water dissolved chloride ion Contents 0.88%. The result of this paper is as follows. 1) Water permeability coefficient of Bentonite Mat : distilled water(1.21$\times$10$^{-9}$cm/sec), salt water(3.12$\times$10$^{-7}$cm/sec). 2) Variation of thickness : distilled water(187%), salt water(108%). 3) Swelling ratio : distilled water(1500%), salt water(350%).

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.1
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• pp.133-137
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• 2006

Ion permeability characteristics in nano-polymer membrane structures are performed to investigate the chemical composition and characteristics of MEA(Membrane Electrolyte Assembly) which is one of the most important parts to decide the performance in PEMFC(Polymer Electrolyte Membrane Fuel Cell) system. Subsequently, the MEA manufacturing process is presented for the uniformed MEA product. In the meantime, the analysis of SEM(Scanning Electron Microscope) is carried out in order to investigate the joint aspect and chemical composition of MEA. As a result of SEM analysis, it is found that the bonded catalyst and carbon composition contain the reasonable amount to get unit cell output. It is also found that the humidification gives the better performance result slightly.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.375-380
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• 1997

The purpose of this study is to examine the properties of polymer-modified mortars using asphalt emulsion. The polymer-modified mortars using asphalt emulsion with various asphalt-cement ratios are prepared, and tested for flexural and compressive strengths, water absorption and permeability, carbonation, Cl ion penetration and chemical resistance. From the test results, the flexural and compressive strengths, water absorption and permeability, carbonation and Cl ion penetration depths of polymer-modified mortars using asphalt emulsion tend to be decreased with increasing asphalt-cement ratio, and chemical resistance is improved. It is evident that polymer-modified mortars using asphalt emulsion having an excellent properties as a waterproof and finish materials can be produced.

• Corrosion Science and Technology
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• v.15 no.1
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• pp.28-37
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• 2016

Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

• Geomechanics and Engineering
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• v.10 no.6
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• pp.807-826
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• 2016

In this study, aiming to investigate the effects of sulfate attack on cement stabilized highly plastic clay; an experimental study was carried out considering the effects of cement type, sulfate type and its concentration, cement content and curing period. Unconfined compressive strength and chloride-ion penetration tests were performed to obtain strength and permeability characteristics of specimens cured under different conditions. Test results were evaluated along with microstructural investigations including SEM and EDS analyses. Results revealed that use of sulfate resistance cement instead of normal portland cement is more plausible for soils under the threat of sulfate attack. Besides, it was verified that sulfate concentration is responsible for strength loss and permeability increase in cement stabilized montmorillonite. Finally, empirical equations were proposed to estimate the unconfined compressive strength of cement stabilized montmorillonite, which was exposed to sulfate attack for 28 days.

• Membrane Journal
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• v.12 no.4
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• pp.247-254
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• 2002

In order to develop the ion exchange membranes which would be used in direct methanol fuel cell (DMFC), the polysulfone polymer was sulfonated using chlorosulfonic acid (CSA) and trimethylchlorosilane(TMCS). It has been characterized in terms of ion conductivities, methanol crossover, swelling degree and ion exchange capacities for the heat untreated and treated membranes at $150^{\circ}C.$ Typically, the methanol permeability and ion conductivity at the mole ratio of 1.4 between polysulfone repeating unit and sulfonating agents showed $2.87{\times}10^{-7}\; cm^2/s$(without heat treatment), $1.52{\times}10^{-7}\; cm^2/s$(with heat treatment) and $1.10{\times}10^{-2}\; S/cm$(without heat treatment), $0.87{\times}10^{-2}\;$ S/cm(with heat treatment), respectively. After the mole ration of 1.4 both values indicated mild increase.

• Proceedings of the Korean Fiber Society Conference
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• 1986.06a
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• pp.32-32
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• 1986

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.74-79
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• 2003

Many marine wastes such as seaweeds are casted aside at the seasides. So, the objective of this study is to apply the marine wastes to the concrete. To this end, mortar and concrete tests with the marine wastes have been conducted. The results of the present mortar and concrete tests indicate that the mortar and concrete with marine wastes admixtures exhibits very low permeability. The present study provides a firm base for the use of very low permeable concrete and the application of the marine structures and the submerged structures.