• Title/Summary/Keyword: iodine crystal deposition

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Iodine Deposition onto the Chinese Cabbage (요오드의 배추에 대한 침적)

  • Lee, Han-Soo;Choi, Heui-Joo;Kang, Hee-Suk;Yu, Dong-Han;Keum, Dong-Kwon;Lim, Kwang-Mook;Park, Hyo-Kook;Choi, Yong-Ho;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
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    • v.29 no.3
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    • pp.173-177
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    • 2004
  • The Chinese cabbage, being one of the principal foodstuffs in Asian countries, is tested for iodine exposure. As a radioactive source, iodine-125 of which the radiological half life is 60 days was used to measure the concentration change. Experiments were carried out four times with different times of exposure. The iodine source was prepared by the chemical reaction of NaI in order to avoid producing relatively large iodine which might be generated In the case of crystal evaporation. The deposition velocity was obtained from the integrated air concentration and surface concentration of the Chinese cabbage. The environmental half life was also calculated.

Synthesis of iron disilicide single crystal by chemical vapour transport (기상성장법(CVT)에 의한 Iron disilicide단결정의 합성)

  • 이충효;홍대석;이상진;최종건;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.2
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    • pp.68-72
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    • 2002
  • The $\beta$-$FeSi_2$ and $\alpha$-$FeSi_2$ single crystals were synthesized by chemical vapour transport (CVT) using iodine as a transporting agent from the commercially available $FeSi_2$ powder. The $FeSi_2$ powder together with iodine were sealed in an evacuated quartz ampoule and the ampoule then being placed in two-zone electrical furnace for growing crystal. The CVT of $FeSi_2$ with iodine yielded $\beta$-$FeSi_2$ and $\alpha$-FeSi$_2$ single crystals at deposition temperature of 750 and $950^{\circ}C$ respectively. The source temperature was $1050^{\circ}C$ in both cases. The crystals of the $\alpha$-FeSi$_2$ phase were typically plate shaped with dimensions of about $10\times 10 \textrm{mm}^2$, whereas the crystals of orthorhombic $\beta$-$FeSi_2$ phase grew predominantly in the fonts of thin needle of about 10 mm in length. The composition of$\alpha$-FeSicrystal determined by electron probe microanalysis (EPMA) resulted in Si-rich $FeSi_{2.58}$ . 57. Furthermore, the CVT $\beta$-$FeSi_2$ crystal was found to be transformed to the high temperature $\alpha$-$FeSi_2$phase above $930^{\circ}C$.

Variation of Microfibril Angle Within Stems of Three Commercial Softwoods Grown in Korea (국내산 주요 침엽수 3종의 수간 내 마이크로피브릴 경사각의 변이)

  • Eun, Dong-Jin;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.77-83
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    • 2008
  • Radial and axial variations of microfibril angle (MFA) within stems of three commercial softwoods (Pinus densiflora, Pinus koraiensis and Pinus rigida) grown in Korea were examined by iodine crystal deposition method. The average MFA were $16.4^{\circ}$ in Pinus densiflora, 14.4, in Pinus koraiensis, and $26.2^{\circ}$ in Pinus rigida, respectively. The MFA in earlywood and latewood decreased with age to about 15~20 years, and then remained almost constant. The MFA of latewood was slightly smaller than that of earlywood. The MFA in the three species was a little smaller at the base of stem and decreased slightly with increasing tree height, but no significant difference by height was identified only in earlywood of Pinus rigida. Consequently, it was considered that the MFA could be an useful index for identifying juvenile wood and adult wood of Pinus densiflora, Pinus. koraiensis and Pinus rigida.

Active Materials for Energy Conversion and Storage Applications of ALD

  • Sin, Hyeon-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.75.2-75.2
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    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

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