• Journal of the Korean Wood Science and Technology
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• v.33 no.3 s.131
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• pp.45-52
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• 2005

This research was performed to evaluate adsorption behavior of woody charcoals obtained from wood powder, fiber and bark of spruce (Abies sibirica Ledeb). The wood materials were carbonized at various temperatures for 1 hour using experimental rotary kiln without any inert gas. The adsorption capacity of iodine and toluene, specific surface area and removal efficiency of acetic acid and ammonia gas of those charcoals were measured. The higher was the temperature for carbonization, the lower yields of charcoals were. Ash content of bark charcoal was higher than that of wood powder charcoal or fiber charcoal. Elemental analysis of woody charcoal revealed that the content of carbon was gradually lincreased as carbonization temperature was higher. When carbonization temperature was higher, adsorption capacity of woody charcoals for iodine was much improved. Wood powder charcoal and fiber charcoal were more effective for iodine adsorption rather than bark charcoal. Capacity of toluene adsorption was the highest in the charcoal of $600^{\circ}C$. Charcoals produced at high temperature efficiently removed acetic acid gas, while charcoals carbonized at low temperature such as $400^{\circ}C$ were proper to remove ammonia gas. This difference may be explained that the acidity of charcoals depends on the carbonization temperature: charcoals of low temperature indicate acidic property, while those of high temperature turned to alkaline.

• Journal of Energy Engineering
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• v.13 no.2
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• pp.166-172
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• 2004

The activated carbon was produced from Sancheong bamboo by steam and carbon dioxide gas activation methods. The carbonization of raw material was conducted at 90$0^{\circ}C$ and gas activation reactions were conducted with respect to various conditions. -activation temperature 750-90$0^{\circ}C$, the flow rate of steam 0.5-2g-$H_2O$/g-char$.$hr, the flow rate of carbon dioxide 5-30$m\ell$-$CO_2$/g-char-min and activation time 1-5 hr. The prepared activated carbons were measured yield, the adsorption capacity of iodine and methylene blue, BET specific surface area and pore size distribution. The adsorption capacity of iodine (680.5-1526.1 mg/g) and methylene blue (18.3-221.5 mg/g) increased with creasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the activation gas quantity in the range of 0.5-1.5g-$H_2O$/g-charㆍhr, 5-18.9$m\ell$-Co$_2$/g-charㆍmin. But those decreased over those range due to the pore shrinkage. The steam activation method was superior in efficiency to carbon dioxide activation method.

• Journal of the Korean Ceramic Society
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• v.46 no.6
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• pp.568-573
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• 2009

In this study, we used coal based activated carbons as starting material and phenolic resin (PR) as a bonding agent to prepare spherical shaped activated carbons. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity and pressure drop. According to the results, the spherical activated carbon prepared with activated carbon and PR at a ratio of 60:40 was found to have the best formation of spherical shape, which was found in sample SAC40. After activation, SAC40 has high BET surface area, iodine adsorption capability and strength value, and lowest pressure drop.

• YAKHAK HOEJI
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• v.32 no.3
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• pp.187-193
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• 1988

An activated carbon which showed big adsorption capacities of iodine, potassium permanganate and phenol was prepared from the Korean ricechaff. By scanning electron micrographs and IR spectra, it was observed that the organic components in the rice-chaff were decomposed to carbon dioxide and vapor by the pyrolysis and the activation, that activated carbon particles had carbon-carbon structures with a lot of microporosity. The adsorption capacities of iodine, potassium permanganate and phenol were determined. The adsorption isotherm of phenol was well fitted in Freundlich's equation.

• Journal of Environmental Science International
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• v.16 no.11
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• pp.1279-1285
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• 2007

The activated carbon was prepared from waste citrus peels using NaOH. With the increase of NaOH ratio, iodine adsorptivity and specific surface area of the activated carbon prepared were increased, but activation yield was decreased. The optimal condition of activation was at 300% NaOH and $700^{\circ}C$ for 1.5 hr. For the activated carbon produced under optimal condition, iodine adsorptivity was 1,006 mg/g, specific surface area was $1,356 m^2/g$, and average pore diameter was $20{\sim}25{\AA}$. From the adsorption experiment for benzene vapor in fixed bed reactor, it was found that the adsorption capacity of activated carbon prepared from waste citrus peel was higher than that of activated carbon purchased from Calgon company. This result implied that the activated carbon prepared from waste citrus peel could be used for gas phase adsorption.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.68-74
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• 2016

In this study, the fabrication of zeolite combined activated carbon spherical samples was carried out as follows. Briefly, ZSM-5 zeolite and activated carbon were composed as main absorbent materials; by controlling the weight percentage of zeolite and binder materials, a series of spherical samples (AZP 4, 6, 8) were prepared. These spherical samples were characterized by BET, XRD, SEM, EDX, and pressure drop; benzene and iodine adsorption tests, bactericidal effect test, and ignition temperature test were also performed. The adsorption capability was found to depend on the BET surface area; the spherical samples AZP6 with high BET surface area of $1011m^2/g$ not only exhibited excellent removal effects for benzene (24.9%) and iodine (920mg/g) but also a good bactericidal effect. The enhanced ignition temperature may be attributed to the homogeneous dispersion conditions and the proper weight percentage ratio between zeolite and activated carbon.

• Journal of the Korean Ceramic Society
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• v.36 no.10
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• pp.1016-1021
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• 1999

In this study activated carbon fibers were prepared from PAN-based carbon fibers by physical activation with steam or carbon dioxide. The variations in specific surface area amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. in steam activation BET surface area of about 1019 m2/g was obtained after 77% burn-off while carbn dioxide activation produced ACF with 694m2/g of BET surface area after 52% burn-off. However carbon dioxide activation produced at a similar degree of activation higher micropore volume(0.37 cc/g) and amount of iodine adsorption (1589mg/g) than steam activation. Nitrogen adsorption isotherms for (PAN based activated carbon fibers that prepared by physical activation were of type I in the Brunauer-Deming-Deming-Teller classification

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.718-722
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• 2012

$H_2S$ adsorption characteristics of adsorbent made by sewage sludge were investigated. For analyses of the manufactured adsorbent, various methods such as Iodine adsorptivity, scanning electron microscope (SEM), and measurements of BET surface area and pore volume were adopted. As the major adsorption characteristic, breakthrough curve was measured by using a continuous fixed bed adsorption column for operating variables such as adsorption temperature ($25{\sim}45^{\circ}C$), aspect ratio (L/D)(3~9), gas flow rate (0.1~2.0 liter/min) and $H_2S$ gas concentration (50~200 ppm). The experimental result showed that the carbonization and activation of sewage sludge are very important for the improvement in $H_2S$ adsorption capacity.

• Polymer(Korea)
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• v.24 no.5
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• pp.713-720
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• 2000

A polymer/iodine complex film was prepared using syndiotactic poly(vinyl alcohol) (s-PVA) with number-average degree of polymerization of 900 and syndiotactic diad content of 63.1%. In comparison with atactic-PVA/iodine films, degree of polarization of the s-PVA/iodine film was improved up to over 99% although a lower transmittance was obtained. By soaking in iodine/potassium iodide aqueous solution of a lower iodine concentration and subsequent drawing by 4 times, s-PVA/iodine film of a higher transmittance and degree of polarization was produced. The degree of iodine desorption of the s-PVA/iodine film in water were very low. The crystallinity and the d-spacing and crystal size of (100) plane increased at the early stage of soaking time, however, remained constant or decreased slightly with increasing soaking time. In consequence, s-PVA/iodine complex formation took place mainly inside crystal region at the initial stage of soaking time, whereas it occurred outside crystal region or physical adsorption of iodine dominated after sufficient soaking.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.2
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• pp.205-224
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• 2023

The emission of off-gas streams from used fuel recycling is a concern in nuclear energy usage as they contain radioactive compounds, such as, ³H, ¹⁴C, ⁸⁵Kr, ¹³¹I, and ¹²⁹I that can be harmful to human health and environment. Radioactive iodine, ¹²⁹I, is particularly troublesome as it has a half-life of more than 15 million years and is prone to accumulate in human thyroid glands. Organic iodides are hazardous even at very low concentrations, and hence the capture of ¹²⁹I is extremely important. Dynamic adsorption experiments were conducted to determine the efficiency of sodium mordenite, partially exchanged silver mordenite, and fully exchanged silver mordenite for the removal of methyl iodide present at parts per billion concentrations in a simulated off-gas stream. Kinetic analysis of the system was conducted incorporating the effects of diffusion and mass transfer. The possible reaction mechanism is postulated and the order of the reaction and the values of the rate constants were determined from the experimental data. Adsorbent characterization is performed to investigate the nature of the adsorbent before and after iodine loading. This paper will offer a comprehensive understanding of the methyl iodide behavior when in contact with the mordenites.