• Nuclear Engineering and Technology
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• v.28 no.1
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• pp.44-55
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• 1996

For the purpose of controlling the release of radioiodine to the environment in nuclear power plants, adsorption characteristics of elemental iodine and methyl iodide on the base carbon and 2%, 5% TEDA impregnated carbons were studied. The amounts of adsorption of elemental iodine and methyl iodide on the carbons were compared with Langmuir, Freundlich, Sips and Dubinin-Astakhov(DA) isotherm equations. Adsorption data were well correlated by the DA equation based on the potential theory. Adsorption energy distributions were obtained from the parameters of the DA equation derived from the condensation approach method. For the adsorption of methyl iodide and elemental iodine-carbon system, the DA equation can be well expressed by the degree of heterogeneity of the micropore system because the surface is nonuniform when its potential energy is unequal. The adsorption energy distribution wes investigated to find a surface heterogeneity on the carbon. The surface heterogeneity for iodine-carbon system is highly affected by the adsorbate-adsorbent interaction as well as the pore structure. The surface heterogeneity increases as a content of TEDA impregnated increases. The adsorption nature of methyl iodide on carbon turned out to be more heterogeneous than that of elemental iodine.

• Journal of Environmental Science International
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• v.24 no.9
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• pp.1123-1129
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• 2015

This research was performed by means of several different virgin granular activated carbons (GAC) made of each coal, coconut and wood, and the GACs were investigated for an adsorption performance of iodine-131 in a continuous adsorption column. Breakthrough behavior was investigated that the breakthrough points of the virgin two coals-, coconut- and wood-based GACs were observed as bed volume (BV) 7080, BV 5640, BV 5064 and BV 3192, respectively. The experimental results of adsorption capacity (X/M) for iodine-127 showed that two coal- based GACs were highest (208.6 and $139.1{\mu}g/g$), the coconut-based GAC was intermediate ($86.5{\mu}g/g$) and the wood-based GAC was lowest ($54.5{\mu}g/g$). The X/M of the coal-based GACs was 2~4 times higher than the X/M of the coconut-based and wood-based GACs.

• Carbon letters
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• v.8 no.1
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• pp.30-36
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• 2007

Oxidized PAN (OXI-PAN) fibers were used for the precursors of activated carbon fiber in study. How drying temperature affected the properties of carbon fibers on activating process of carbon fibers was investigated. The specific surface areas of activated carbon fibers have been determined on a series of chemically activated carbons with KOH and NaOH. The experimental data showed variations in specific surface area, iodine and silver adsorptions by the activated carbon fibers. The amount of iodine adsorption increases with increasing specific surface areas in both activation methods. This was because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers. Silver adsorbed well in NaOH activated carbon fibers rather than KOH activated carbon fibers in this study.

• Journal of the Korean Wood Science and Technology
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• v.52 no.2
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• pp.118-133
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• 2024

The sapwood portion of fast-growing teak is mostly ignored due to its inferior quality. One of the possibilities for utilizing sapwood waste is to convert it into activated carbon that has good adsorption capabilities. The raw materials used in this research were sapwood of 14-year-old fast-growing teak sapwood (FTS) waste, which was taken from three trees from community forests in Wonosari, Gunungkidul, Yogyakarta Special Region. FTS waste was taken from the bottom of the tree up to a height of 1.3 m. The activation process is conducted with an activation temperature of 750℃, 850℃, and 950℃. The heating duration consists of three variations: 30 min, 60 min, and 90 min. The quality evaluation parameters of activated carbon include yield, moisture content, volatile matter content, ash content, fixed carbon content, adsorption capacity of benzene, adsorption capacity of methylene blue, and adsorption capacity of iodine. The results showed that the activated carbon produced had the following quality parameters: yield of 75.61%; moisture content of 1.27%; volatile matter content of 9.98%; ash content of 5.43%; fixed carbon content of 84.58%; benzene absorption capacity of 8.58%; methylene blue absorption capacity of 87.73 mg/g; and iodine adsorption capacity of 948.19 mg/g. It can be concluded that activated carbon from FTS waste has good iodine adsorption, which fulfilled the SNI 06-3730-1995 quality standard. Due to the iodine adsorption ability of FTS waste activated carbon, the conversion of FTS waste to activated carbon is categorized as a potential method to increase the value of this material.

• Carbon letters
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• v.10 no.4
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• pp.293-299
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• 2009

Potassium hydroxide activated carbons were prepared from Egyptian petroleum cokes with different KOH/coke ratios and at different activation temperatures and times. The textural properties were determined by adsorption of nitrogen at $-196^{\circ}C$. The adsorption of iodine and methylene blue was also investigated at $30^{\circ}C$. The surface area and the non-micropore volume increased whereas the micropore volume decreased with the increase of the ratio KOH/coke. Also the surface area and porosity increased with the rise of activation temperature from 500 to $800^{\circ}C$. Textural parameter considerably increased with the increase of activation time from 1 to 3 h. Further increasing of activation time from 3 to 4 h was associated with a less pronounced increase in textural parameters. The adsorption of iodine shows the same trend of surface area and porosity change exhibited by nitrogen adsorption, with KOH/coke ratio and temperature of activation. Adsorption of methylene blue follows pseudo-first-order kinetics and its equilibrium adsorption follows Langmuir and D-R models.

• Journal of the Korean Ceramic Society
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• v.36 no.6
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• pp.577-582
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• 1999

Activated carbon fibers were prepared from stabilized PAN fibers by chemical activation using hydroxide. The variations in specific surface area amount of iodine adsorption micro-structure and pore size distribution in the activated carbon fibers after the activation process were discussed. In the chemical activation using potassium hydroxide specific surface area of about 2545m2/g and amount of iodine adsorption of 2049 mg/g were obtained at the condition of KOH/fiber ratio of 1 and 800$^{\circ}C$ Nitrogen adsorption isotherms for PAN based activated carbon fibers showed the type I in the Brunauer-Deming-Deming-Teller classification indicating the micro-pores consisting the activated fibers.

• Archives of Pharmacal Research
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• v.14 no.3
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• pp.249-254
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• 1991

Activated carbons from rice-straw can be used as an adsorbents for the purification of water were prepared and evaluated. The adsorptive capacities of activated carbons were measured by iodine, potassium permangante, phenol and metals. It was observed by electron microscope (SEM) and IR spectrum that organic components in the rice-straw and its carbonization product were disappeared. Slit-shaped and porousstructures were formed by activation. There was no relationship between temperature and adsorption of iodine but adsorption of potassium permanganate increased as temperature rose. The adsorption of the phenol was greater than 99%. The adsorption data of phenol at $25^\circ{C}$ obeyed the Freundlich's isotherm. Various metals except sodium were not removed by activated carbon.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.3
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• pp.323-329
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• 2007

There is no certain definition about advanced drinking water treatment but it is generally known as activated carbon process, membrane process or ozone process which can remove non-conventional pollutants such as taste and odor compounds, and micro-pollutants. There are more than 20 processes related to activated carbon as adsorber or biological activated carbon in Korea. The saturated carbon by pollutants can be reused by reactivation. However, the effect of reactivation on activated carbon is not well-understood in terms of changing physical properties of carbon to adsorption capacity of natural organic matter (NOM). In this study, the effects of reactivation on physical properties of activated carbon were investigated by isotherm and breakthrough of NOM. Ash content was increased from 8% to 13.3%. Iodine number is commonly used as an indicator for performance of reactivation. The iodine number was decreased about 20% after reactivating twice. The degree of reactivation can be evaluated by not only iodine number but also apparent density.

• Carbon letters
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• v.8 no.4
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• pp.274-279
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• 2007

In order to understand the breakthrough behaviour of iodine vapours on impregnated carbon systems, an active carbon, 80 CTC grade, $12{\times}30$ BSS particle size and $1104\;m^2/g$ surface area, was impregnated with metal salts such Cu, Cr, Ag, Mo and Zn, and an organic compound Triethylene diamine (TEDA) to prepare different carbon systems such as whetlerite, whetlerite/TEDA, whetlerite/KI/KOH and ASZMT. The prepared adsorbents along with active carbon were characterized for surface area and pore volume by $N_2$ adsorption at liquid nitrogen temperature. These carbon systems were compared for their CT (concentration X time) values at 12.73 to 53.05 cm/sec space velocities and 2 to 5 cm carbon column bed heights. The carbon column of 5.0 cm bed height and 1.0 cm diameter was found to be providing protection against iodine vapours up to 5.5 h at 3.712 mg/L iodine vapour concentration and 12.73 cm/sec space velocity. The study clearly indicated the adsorption capacities of carbon systems to be directly proportional to their surface area values. Dead layer with all the prepared carbon systems was found to be less than 2.0 cm indicating it to be minimum bed height to have protection against $I_2$ vapours. Effect of carbon bed height and flow rate was also studied. The active carbon showed maximum protection at all bed heights and flow rates in comparison to all other impregnated carbon systems, showing that only physical adsorption is responsible for the removal of iodine vapours.

• Polymer(Korea)
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• v.25 no.1
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• pp.115-121
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• 2001

High molecular weight syndiotactic poly(vinyl alcohol)(HMW s-PVA) with number-average degree of polymerization of 10000 and syndiotactic diad content of 61.5%/iodine complex film was prepared. Its adsorption and desorption behaviors of iodine in hot water were investigated. In comparison with atactic PVA film or low molecular weight s-PVA film, the degree of solubility of s-PVA film and the iodine desorption of HMW s-PVA/iodine film in hot water were limited to an extremely lower level. As the soaking time increased, the iodine desorption in hot water was increased. This reason might be explained by the fact that as the soaking time increased, so the iodine adsorption increased not by the stable molecular complex between PVA and iodine but by the simple physical adsorption of iodine.